Coating compositions containing crosslinked spherical fine particles
    2.
    发明授权
    Coating compositions containing crosslinked spherical fine particles 失效
    含有交联球形微粒的涂料组合物

    公开(公告)号:US5498670A

    公开(公告)日:1996-03-12

    申请号:US325105

    申请日:1994-10-17

    摘要: Disclosed herein are crosslinked spherical fine particles having good toughness, elastic properties, and chemical properties, and a process for producing the same, said fine particles being obtained by radical polymerization in the suspended state of a component [M] capable of radical polymerization containing a vinyl group-containing compound (V) capable of radical polymerization which is obtained by reaction of (a) a selected polyol, (b) an isocyanate group-containing compound, and (c) an active hydrogen-containing vinyl monomer capable of radical polymerization. Also disclosed herein are the secondary products of the crosslinked spherical fine particles, which include a coating composition and its derivatives (such as filmlike article, sheetlike article, adhesive filmlike article, and adhesive sheetlike article) and a peelable pressure-sensitive adhesive and peelable pressure-sensitive adhesive article.

    摘要翻译: 本发明公开了具有良好的韧性,弹性和化学性质的交联球形微粒及其制备方法,所述微粒是通过在能够自由基聚合的组分[M]的悬浮状态下自由基聚合而得到的, 通过(a)所选择的多元醇,(b)含异氰酸酯基的化合物和(c)能够自由基聚合的含活性氢的乙烯基单体的反应获得的能够进行自由基聚合的含乙烯基的化合物(V) 。 本文还公开了交联球形微粒的二次产物,其包括涂料组合物及其衍生物(例如薄膜状制品,片状制品,粘合膜状制品和粘合片状制品)和可剥离压敏粘合剂以及可剥离压力 敏感性粘合剂制品。

    Aqueous crosslinkable resin dispersions, method of their production and
use thereof
    3.
    发明授权
    Aqueous crosslinkable resin dispersions, method of their production and use thereof 失效
    水性交联树脂分散体,其制备方法和用途

    公开(公告)号:US5284900A

    公开(公告)日:1994-02-08

    申请号:US708368

    申请日:1991-05-31

    摘要: The present invention yields a coating film excellent in adhesion, water resistance, solvent resistance and durability. A compound having a carboxyl group and a long-chain alkylthio group or a salt thereof is used as an emulsifier and emulsion polymerization is carried out using a polymerizable monomer or monomers having, within their molecule, a group reactive with a carboxyl group as raw materials for emulsion polymerization, whereby the resin produced by emulsion polymerization and the emulsifier react with each other efficiently on the occasion of film formation and form a crosslinked structure. When a compound having a polymerizable unsaturated group in addition to the carboxyl group and long-chain alkylthio group or a salt thereof is used as the emulsifier, not only the above-mentioned crosslinked structure is formed but also the polymerizable unsaturated group in the emulsifier will react with the unsaturated group in the polymerizable monomer or monomers in the manner of grafting. As a result, the compatibility between the emulsifier and the emulsion-polymerized resin is improved.

    摘要翻译: 本发明产生粘附性,耐水性,耐溶剂性和耐久性优异的涂膜。 使用具有羧基和长链烷硫基的化合物或其盐作为乳化剂,并使用其分子内具有与羧基反应的基团作为原料的可聚合单体或单体进行乳液聚合 用于乳液聚合,由此通过乳液聚合制备的树脂和乳化剂在成膜时有效地相互反应并形成交联结构。 当使用除了羧基和长链烷硫基之外具有可聚合不饱和基团的化合物或其盐作为乳化剂时,不仅形成上述交联结构,而且乳化剂中的可聚合不饱和基团 以可接枝的方式与可聚合单体中的不饱和基团反应。 结果,改善了乳化剂与乳液聚合树脂的相容性。

    Process for producing polymer having hydroxyl groups at both terminals
    4.
    发明授权
    Process for producing polymer having hydroxyl groups at both terminals 失效
    制造两端具有羟基的聚合物的方法

    公开(公告)号:US5391665A

    公开(公告)日:1995-02-21

    申请号:US30368

    申请日:1993-04-02

    IPC分类号: C08F2/38 C08F2/44 C08G18/62

    摘要: There are provided a process for obtaining a polymer having hydroxyl groups at both terminals easily and with cheap cost and excellent efficiency from a wide variety of vinyl-based compounds, a composition containing said polymer and its use, and a polymer derived from said composition and its use.The polymerization reaction of a vinyl-based monomer (b) is carried out by using a radical polymerization initiator (c) in the presence of a compound (a) represented by the general formula:HO--A--(S).sub.x --B--OH (I)and, a polymer having hydroxyl groups at both terminals is obtained under conditions that, in the above reaction, any compound other than (a), (b) and (c) is not practically used and the compound (a) always exists in 50 mole times or more of the initiator (c) in the course of reaction in a reactor; and either a composition containing this polymer or a polymer derived from this composition is used.

    摘要翻译: PCT No.PCT / JP92 / 00992 Sec。 371日期:1993年4月2日 102(e)日期1993年4月2日PCT提交1992年8月4日PCT公布。 公开号WO93 / 03066 日本公开了1993年2月18日。提供了一种用于从各种乙烯基类化合物,含有所述聚合物的组合物及其用途容易地获得具有羟基的聚合物的方法,并且成本低廉且效率优异的方法,以及 衍生自所述组合物的聚合物及其用途。 乙烯基类单体(b)的聚合反应通过使用自由基聚合引发剂(c)在由以下通式表示的化合物(a)的存在下进行:HO-A-(S)xB-OH( (a),(b)和(c)以外的任何化合物未被实际使用且化合物(a)总是存在的条件下得到两末端具有羟基的聚合物,在上述反应中, 在反应器中反应过程中的50摩尔倍以上的引发剂(c); 并且使用含有该聚合物或由该组合物衍生的聚合物的组合物。

    Method of treating fluorine compound
    5.
    发明授权
    Method of treating fluorine compound 失效
    氟化合物的处理方法

    公开(公告)号:US06743957B2

    公开(公告)日:2004-06-01

    申请号:US10070756

    申请日:2002-06-26

    IPC分类号: C07C1738

    摘要: Divalent and trivalent metal salts are added to the solution containing the fluorine compound and the polymer containing fluorine to precipitate the layered double hydroxide containing the fluorine compound between layers. At this time, the polymer containing fluorine suspended in the solution is also coagulated to precipitate. By these processes, the fluorine compound is fixed with high rate to separate from the solution with the polymer containing fluorine, and recovered if necessary. By this treatment process, the fluorine compound and the polymer containing fluorine, contained in the wastewater etc. can be separated easily, and the burden to environment or ecosystem can be reduced.

    摘要翻译: 向含氟化合物和含氟聚合物的溶液中加入二价和三价金属盐,使层间含有氟化合物的层状双氢氧化物析出。 此时,含有悬浮在溶液中的氟的聚合物也凝结而沉淀。 通过这些方法,氟化合物以高速固定,与含氟聚合物的溶液分离,如果需要回收。 通过这种处理方法,可以容易地分离含有废水等的氟化合物和含氟聚合物,能够减轻对环境或生态系统的负担。

    Process for producing polymer having hydroxyl group at both terminals
    6.
    发明授权
    Process for producing polymer having hydroxyl group at both terminals 失效
    在两端生产具有羟基的聚合物的方法

    公开(公告)号:US5470930A

    公开(公告)日:1995-11-28

    申请号:US197177

    申请日:1994-02-16

    CPC分类号: C08F4/30

    摘要: This invention provides a production process by which a polymer having a hydroxyl group at both terminals can be easily obtained with a cheap price and good efficiency from a wide field of vinyl-based monomers including polar ones. In this process, a polymerization reaction of a vinyl-based monomer (a) is performed by using hydrogen peroxide (b) and, on this occasion, either one or both of a hydrogen peroxide-decomposing accelerator (c) and an amphiphilic compound (d) are further used and any component other than the (a), (b), (c) and (d) is not substantially used.

    摘要翻译: 本发明提供了一种制备方法,通过该方法可以从包括极性的乙烯基类单体的广泛领域以便宜的价格和良好的效率容易地获得两端具有羟基的聚合物。 在该方法中,使用过氧化氢(b)进行乙烯基类单体(a)的聚合反应,此时,过氧化氢分解促进剂(c)和两亲性化合物 d),并且基本上不使用(a),(b),(c)和(d)以外的任何成分。

    Coating for water blocking agents
    10.
    发明授权
    Coating for water blocking agents 失效
    防水涂料

    公开(公告)号:US06764538B2

    公开(公告)日:2004-07-20

    申请号:US09922839

    申请日:2001-08-07

    IPC分类号: B32B108

    摘要: The present invention relates to a coating for water blocking agents to fill empty joint spaces on continuous walls comprising a composition consisting essentially of a water-absorbing resin (a), a hydrophilic binder resin (b) and a solvent (c), wherein said hydrophilic binder resin (b) has an acid value of 40 mg KOH/g to 500 mg KOH/g. The present invention also relates to a water blocking construction method using the coating for water blocking agents.

    摘要翻译: 本发明涉及用于填充封闭剂以填充连续壁上的空关节空间,包括基本上由吸水树脂(a),亲水性粘合剂树脂(b)和溶剂(c)组成的组合物,其中所述亲水 粘合剂树脂(b)的酸值为40mg KOH / g至500mg KOH / g。 本发明还涉及一种使用该阻挡剂涂层的防水结构方法。