公开(公告)号：US4283479A

公开(公告)日：1981-08-11

申请号：US123611

申请日：1980-02-22

Applicant: Tsutomu Hamaoka ,  Yasuo Kasama

Inventor： Tsutomu Hamaoka ,  Yasuo Kasama

IPC: G03C1/42 ,  G03C5/30 ,  G03C5/315 ,  G03F7/06 ,  G03C1/48 ,  G03C5/00

CPC classification number: G03C5/315 ,  G03C5/3021

Abstract: Silver halide photographic materials providing wash-off relief images and having excellent shelf life comprising a support having formed thereon at least a silver halide photosensitive emulsion layer and said silver halide emulsion layer or another hydrophilic colloid layer containing a polyhydroxy-spiro-bis-chroman tanning developing agent and a gallic acid alkyl ester is disclosed with a process forming relief images.

Abstract translation: 卤化银照相材料提供洗脱浮雕图像并且具有优异的保存期限，其中包括至少在其上形成有卤化银感光乳剂层和所述卤化银乳剂层或含有多羟基 - 双 - 苯并二氮唑鞣制剂的另一亲水胶体层的载体 公开了显影剂和没食子酸烷基酯与形成浮雕图像的工艺。

公开(公告)号：US4542086A

公开(公告)日：1985-09-17

申请号：US266781

申请日：1981-05-26

Applicant: Nobutaka Ohki ,  Motohiko Tsubota ,  Masakazu Morigaki ,  Tsutomu Hamaoka

Inventor： Nobutaka Ohki ,  Motohiko Tsubota ,  Masakazu Morigaki ,  Tsutomu Hamaoka

IPC: G03C8/36 ,  G03C8/00 ,  G03C1/40 ,  G03C5/54

CPC classification number: G03C8/00

Abstract: A color diffusion transfer photographic element comprising (a) a light sensitive component containing at least one light sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b) and (c) containing a diffusible hydroquinone type compound having the half wave potential of polarography in the range of from -300 mV to -380 mV measured using a saturated calomel electrode as a reference electrode in a buffer solution having a pH of 13.0.degree. at 25.degree. C. The diffusible hydroquinone type compound has excellent gradation control properties and is particularly suitable for controlling gradation of the toe part in a photographic characteristic curve of a color diffusion transfer photograph. A typical example of a diffusible hydroquinone compound of the invention is: ##STR1##

Abstract translation: 一种彩色扩散转印照相材料，包括（a）含有至少一种与释放染料的氧化还原化合物相关的感光卤化银乳剂层的光敏组分，（b）染料影像接收组分和（c）碱性处理组合物组分， 其中所述改进包括至少一种所述组分（a），（b）和（c）中的至少一种，其含有具有-300mV至-380mV范围内极谱半波电位的可扩散氢醌型化合物，其使用饱和 甘汞电极作为参考电极，在25℃下pH为13.0的缓冲溶液中。可扩散氢醌型化合物具有优异的灰度控制性能，特别适用于控制颜色的照相特征曲线中的脚趾部分的灰度 扩散转印照片。 本发明的可扩散氢醌化合物的典型实例是：

公开(公告)号：US4429031A

公开(公告)日：1984-01-31

申请号：US193495

申请日：1980-10-03

Applicant: Motohiko Tsubota ,  Masakazu Morigaki ,  Tsutomu Hamaoka ,  Nobutaka Ohki

Inventor： Motohiko Tsubota ,  Masakazu Morigaki ,  Tsutomu Hamaoka ,  Nobutaka Ohki

IPC: G03C5/29 ,  G03C5/30 ,  G03C7/00 ,  G03C8/36 ,  G03C5/54

CPC classification number: G03C5/3021 ,  G03C8/36

Abstract: A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.

Abstract translation: 公开了一种彩色扩散转印照相材料，其包含（a）含有至少一种与DRR化合物组合的感光卤化银乳剂层的感光组分，（b）染料影像接收组分和（c）碱性处理组合物组分，其中 改进包括含有式（I）表示的化合物的所述组分（a），（b）和（c）中的至少一种：其中R表示取代或未取代的烷基，其具有1至 18个碳原子。

公开(公告)号：US4360589A

公开(公告)日：1982-11-23

申请号：US263805

申请日：1981-05-14

Applicant: Tetsuro Kojima ,  Masakazu Morigaki ,  Tsutomu Hamaoka ,  Satoru Sawada

Inventor： Tetsuro Kojima ,  Masakazu Morigaki ,  Tsutomu Hamaoka ,  Satoru Sawada

IPC: G03C7/26 ,  C07C205/38 ,  C07C271/44 ,  G03C7/392 ,  G03C8/24 ,  G03C1/40

CPC classification number: C07C271/44 ,  C07C205/38 ,  G03C7/3928 ,  G03C8/246

Abstract: A compound represented by the structural formula: ##STR1## is representative of the compounds disclosed which are utilized within the silver halide layer of photographic light-sensitive materials. The compounds aid in preventing the fading of dye images which are formed by development of color photographic light-sensitive materials as well as aiding in the prevention of discoloration of non-developed areas. The effects of the compounds are particularly noticeable when utilized in combination with magenta couplers or cyan couplers, and other antifading agents in an amount of 2 to 150% by weight based on the weight of the couplers.

Abstract translation: 由结构式表示的化合物：是在照相感光材料的卤化银层内使用的化合物的代表。 这些化合物有助于防止通过彩色摄影感光材料的显影形成的染料图像的褪色以及有助于防止非显影区域的变色。 当与品红成色剂或青色成色剂组合使用时，化合物的效果特别明显，其它抗褪色剂的量为基于成色剂重量的2至150重量％。

公开(公告)号：US4157915A

公开(公告)日：1979-06-12

申请号：US902139

申请日：1978-05-02

Applicant: Tsutomu Hamaoka ,  Junkichi Ogawa ,  Isao Shimamura

Inventor： Tsutomu Hamaoka ,  Junkichi Ogawa ,  Isao Shimamura

IPC: G03C7/00 ,  C07C67/00 ,  C07C313/00 ,  C07C317/18 ,  G03C1/42 ,  G03C7/30 ,  G03C7/392 ,  G03C7/413 ,  G03C1/06

CPC classification number: G03C1/42 ,  G03C7/39236 ,  G03C7/4136 ,  Y10S430/16

Abstract: A color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, a non-diffusible color coupler present in at least one layer on the support and a layer containing at least one compound represented by the following general formula (I) ##STR1## wherein R.sub.1 represents an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group or an alkylsulfonamidoalkyl group; R.sub.2 represents an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group or an alkylsulfonamidoalkyl group, R.sub.3 represents a hydrogen atom, an alkyl group or an alkoxyalkyl group, and R.sub.4 and R.sub.5, which may be the same or different, each represents a hydrogen atom, a halogen atom, a carboxyl group, a sulfo group, a nitro group, a carboxylic acid ester group, an alkyl group or an alkoxyalkyl group.

Abstract translation: 一种彩色摄影感光材料，其包括其上具有至少一个卤化银乳剂层的支撑体，在载体上至少一层中存在的不可扩散颜色成色剂和含有至少一种由以下通式表示的化合物 I）其中R 1表示烷基，羟烷基，烷氧基烷基或烷基磺酰胺基烷基; R 2表示烷基，羟烷基，烷氧基烷基或烷基磺酰氨基烷基，R 3表示氢原子，烷基或烷氧基烷基，R 4和R 5可以相同或不同，表示氢原子 卤素原子，羧基，磺基，硝基，羧酸酯基，烷基或烷氧基烷基。

公开(公告)号：US4155763A

公开(公告)日：1979-05-22

申请号：US831209

申请日：1977-09-07

Applicant: Kazunori Hasebe ,  Shinzo Kishimoto ,  Tsutomu Hamaoka ,  Masakazu Morigaki ,  Yosuke Nakajima

Inventor： Kazunori Hasebe ,  Shinzo Kishimoto ,  Tsutomu Hamaoka ,  Masakazu Morigaki ,  Yosuke Nakajima

IPC: G03C7/30 ,  G03C7/413 ,  G03C7/00

CPC classification number: G03C7/413

Abstract: A method for processing a silver halide color photographic light-sensitive material which comprises developing an image-wise exposed silver halide color light-sensitive material in the presence of (a) an aromatic primary amine color developing agent, (b) hydroxylamine or a hydroxylamine derivative, and (c) a 1-aryl-3-pyrazolidone derivative containing two substituent groups at the 4-position thereof.

Abstract translation: 一种用于处理卤化银彩色照相感光材料的方法，其包括在（a）芳族伯胺显色剂，（b）羟胺或羟胺存在下显影成像曝光的卤化银色光敏材料 衍生物，和（c）在其4-位含有两个取代基的1-芳基-3-吡唑烷酮衍生物。

公开(公告)号：US4367272A

公开(公告)日：1983-01-04

申请号：US258491

申请日：1981-04-28

Applicant: Hiroshi Hayashi ,  Tsutomu Hamaoka ,  Masakazu Morigaki

Inventor： Hiroshi Hayashi ,  Tsutomu Hamaoka ,  Masakazu Morigaki

IPC: G03C8/50 ,  G03C8/24 ,  G03C8/52 ,  G03C1/40

CPC classification number: G03C8/246 ,  G03C8/52 ,  Y10S430/142

Abstract: A photographic print prepared by a color diffusion transfer process comprising at least a support, a mordant layer containing therein a diffusion transfer dye image, and a white reflection layer constituting the background of the dye image and containing therein at least one compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an aralkyloxy group, an alkenyl group, an alkenyloxy group, an alkylthio group, an arylthio group, an acyl group, an acylamino group, a diacylamino group, an alkylamino group, a sulfonamido group, an acyloxy group, an alkoxycarbonyl group, or an aryloxycarbonyl group, and A represents a non-metallic atom group necessary for forming a 5- or 6-membered ring.

Abstract translation: 通过颜色扩散转移方法制备的照相印刷品，其包含至少一种载体，含有扩散转印染料图像的媒染剂层和构成染料图像背景的白色反射层，并含有至少一种由式（ I）：其中R 1，R 2和R 3可以相同或不同，表示氢原子，卤素原子，烷基，芳基，芳烷基，烷氧基，芳氧基 基团，芳烷氧基，烯基，烯氧基，烷硫基，芳硫基，酰基，酰氨基，二酰氨基，烷氨基，亚磺酰氨基，酰氧基，烷氧基羰基， 或芳氧基羰基，A表示形成5-或6-元环所必需的非金属原子团。

公开(公告)号：US4346167A

公开(公告)日：1982-08-24

申请号：US287850

申请日：1981-07-29

Applicant: Eiji Imatomi ,  Tsuyoshi Ogawa ,  Tsutomu Hamaoka

Inventor： Eiji Imatomi ,  Tsuyoshi Ogawa ,  Tsutomu Hamaoka

IPC: G03C1/06 ,  G03C1/09 ,  G03C1/10 ,  G03C1/34 ,  G03C1/02 ,  G03C1/28

CPC classification number: G03C1/10 ,  G03C1/067 ,  G03C1/09 ,  G03C1/34 ,  Y10S430/15

Abstract: A silver halide photographic light-sensitive material is described comprising a support having thereon at least one light-sensitive silver halide emulsion layer, said silver halide emulsion layer containing a rhodium salt in an amount sufficient to increase a contrast thereof, and said silver halide emulsion layer or a layer adjacent thereto containing a compound represented by the following formula (I) or (II), and a process for producing a silver halide photographic emulsion containing rhodium salts is also described which comprises adding a rhodium salt into a silver halide photographic emulsion in an amount sufficient to increase a contrast before the conclusion of first ripening and adding a compound represented by the following formula (I) or (II) into the resulting emulsion after washing to remove useless salts ##STR1## wherein R.sub.1 represents hydrogen or a substituted or unsubstituted alkyl group.The silver halide photographic light-sensitive material and a silver halide photographic emulsion each is capable of providing high contrast images and stabilized photographic properties; particularly, gradation properties remain stable during storage.

Abstract translation: 描述了一种卤化银照相感光材料，其包括其上具有至少一个感光卤化银乳剂层的载体，所述卤化银乳剂层含有足以提高其对比度的铑盐，并且所述卤化银乳剂 层或邻近的含有下式（I）或（II）表示的化合物的层，以及制备含有铑盐的卤化银照相乳剂的方法，其包括将铑盐加入到卤化银照相乳剂中 其量足以在第一次熟化结束之前增加对比度，并且在洗涤之后将由下式（I）或（II）表示的化合物加入到所得乳液中以除去无用盐。（I）（ II）其中R 1表示氢或取代或未取代的烷基。 卤化银照相感光材料和卤化银照相乳剂各自能够提供高对比度图像和稳定的照相性能; 特别地，在储存期间灰度特性保持稳定。

公开(公告)号：US4366226A

公开(公告)日：1982-12-28

申请号：US285721

申请日：1981-07-22

Applicant: Tsutomu Hamaoka ,  Osamu Takahashi ,  Tooru Harada ,  Minoru Sakai ,  Nobutaka Ohki

Inventor： Tsutomu Hamaoka ,  Osamu Takahashi ,  Tooru Harada ,  Minoru Sakai ,  Nobutaka Ohki

IPC: G03C7/26 ,  C07C67/00 ,  C07C301/00 ,  C08F28/00 ,  G03C7/392 ,  G03C8/08 ,  G03C8/10 ,  G03C1/40 ,  G03C1/10 ,  G03C5/54

CPC classification number: G03C7/39216 ,  G03C8/10

Abstract: A color photographic silver halide light-sensitive material is described comprising a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.3 can each represent an unsubstituted or substituted alkyl group or an unsubstituted or substituted aryl group, R.sup.2 can represent an unsubstituted or substituted alkyl group, R.sup.4 and R.sup.5 can each represent a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryloxy group, an unsubstituted or substituted alkylthio group, an unsubstituted or substituted arylthio group, a halogen atom, or an acylamino group, and R.sup.1 and R.sup.2, R.sup.1 and R.sup.4, or R.sup.2 and R.sup.5 together can represent atoms forming a condensed ring structure together with the benzene ring of formula (I), provided that the total of carbon atom numbers in R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is at least 16.

Abstract translation: 描述了一种彩色照相卤化银感光材料，其包含由式（I）表示的化合物（I），其中R 1和R 3各自表示未取代或取代的烷基或未取代或取代的芳基，R 2可以表示 未取代或取代的烷基，R4和R5各自表示氢原子，未取代或取代的烷基，未取代或取代的芳氧基，未取代或取代的烷硫基，未取代或取代的芳硫基，卤素原子或 酰基氨基，R1和R2，R1和R4，或R2和R5一起可以表示与式（I）的苯环一起形成稠环结构的原子，条件是R1，R2， R3，R4和R5至少为16。

公开(公告)号：US4362795A

公开(公告)日：1982-12-07

申请号：US182545

申请日：1980-08-29

Applicant: Junkichi Ogawa ,  Minoru Yamada ,  Tsutomu Hamaoka

Inventor： Junkichi Ogawa ,  Minoru Yamada ,  Tsutomu Hamaoka

IPC: G03C1/00 ,  G03C7/305 ,  G03C7/00

CPC classification number: G03C7/30523 ,  Y10S430/167

Abstract: A process for forming photographic images comprising a silver image and a dye image, comprising development processing an imagewise exposed silver halide photographic light-sensitive material containing a 4-alkoxy-1-naphthol represented by the formula (I) ##STR1## wherein R represents an alkyl group, an alkoxyalkyl group, or a hydroxyalkyl group, and the number of carbon atoms in the substituent represented by R is from 1 to 4.The process of this invention is particularly useful in the field of X-ray photography, in order to provide an image of increased density for a given silver content. A novel silver halide photographic light-sensitive material includes the above 4-alkoxy-1-naphthol in a photographic colloid layer thereof, preferably the silver halide emulsion layer.

Abstract translation: 一种用于形成包含银图像和染料图像的照相图像的方法，包括显影处理含有由式（I）表示的4-烷氧基-1-萘酚的成像曝光的卤化银照相感光材料， 其中R表示烷基，烷氧基烷基或羟烷基，R表示的取代基中的碳原子数为1〜4。本发明的方法在X射线摄影领域中特别有用 ，以便为给定的银含量提供增加密度的图像。 一种新型的卤化银照相感光材料在其胶体胶体层中包括上述4-烷氧基-1-萘酚，优选卤化银乳剂层。