摘要:
Surface-crosslinked superabsorbents are produced using a process that comprises the steps of contacting a superabsorbent base polymer with a polyvalent metal salt solution produced by dissolving at least two different polyvalent metal salts, at least one of which comprises a chelate-forming anion, and heat-treating to produce a surface-crosslinked superabsorbent.
摘要:
Superabsorbent polymer particles having superior gel integrity, absorption capacity, and permeability are disclosed. A method of producing the superabsorbent polymer particles by applying a polyamine coating to the particles also is disclosed.
摘要:
Re-moisturised, surface-crosslinked superabsorbents are produced using a process that comprises the steps of contacting a superabsorbent base polymer with an organic crosslinker and a polyvalent metal salt solution in the presence of an alcohol, heat-treating to produce a surface-crosslinked, dry superabsorbent and re-moisturising the surface-crosslinked dry superabsorbent.
摘要:
An absorbent article can have a topsheet, a backsheet, and an absorbent core disposed between the topsheet and the backsheet. In some aspects, at least one of the topsheet, backsheet, and absorbent core is stretchable. In other aspects, the absorbent core can comprise layers, at least one of which includes substantially the superabsorbent material and at least one of which includes substantially fluff. In some aspects, the article includes superabsorbent material which has a centrifuge retention capacity of at least about 25 g/g, a free swell gel bed permeability of at least 200 Darcies, and a gel integrity of at least 2. In some aspects, the superabsorbent material is coated with a polyvinylamine.
摘要:
Superabsorbent polymer (SAP) particels containing a clay are disclosed. The clay is added to an SAP hydrogel prior to SAP neutralization to provide particles having improved fluid acquisition rates and an improved permeability of a fluid through the swollen SAP-clay particles. Diaper cores and absorbent articles containing the SAP-clay particles also are disclosed.
摘要:
A surface crosslinked superabsorbent polymer composition, a process for its preparation and articles made therefrom wherein said superabsorbent composition is prepared by surface crosslinking the polymerization product of a carboxyl or carboxylate group containing monomer with a crosslinker solution comprising water, C.sub.3 -C.sub.6 diol and a crosslinking compound having at least two functional reactive groups with the carboxyl or carboxylate groups of said polymerization product.
摘要:
Novel cationic polymers are provided by reaction of high molecular weight polymers and copolymers of acrylamide with an alkyl epoxide compound such as glycidyldialkylamine or glycidyltrialkylammonium salt to form polymer chain units containing e.g. pendant (N-2-hydroxypropyl) dialkylamine groups or their trialkylammonium salts. Processes for making the graft copolymers are provided in which the reaction is carried out while maintaining the reaction mixture in gel form by swelling the starting solid polymer with a solvent mixture.The reaction may be carried out in a homogeneous reaction environment or in a heterogeneous reaction environment by dispersing the starting solid polymer in an inert liquid that is a non-solvent for both the polymer and the salt. The polymeric products of the reaction may be hardened with a suitable liquid, such as isopropanol, to a solid particulate material.
摘要:
Superabsorbents are produced by polymerisation in a kneader equipped with at least two parallel shafts that also comprises elements on at least one shaft that transport the kneader's content parallel to the shafts from a feed section to a discharge section, the process comprising the addition of an inorganic powder to the kneader's contents prior to or during polymerisation and the addition of at least one other additive to the kneader's contents during polymerisation, wherein the inorganic powder is added no later than half the average residence time of the kneader's contents and the other additive is added no earlier than half this residence time.
摘要:
A process for producing surface postcrosslinked water-absorbing polymer particles, wherein the water-absorbing polymer particles are coated, before, during or after the surface postcrosslinking, with at least one basic salt of a trivalent metal cation and a monovalent carboxylic acid anion.