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公开(公告)号：US20140004447A1
公开(公告)日：2014-01-02
申请号：US13717255
申请日：2012-12-17
IPC分类号： H01M12/04
CPC分类号： H01M12/04 , H01M2/1646 , H01M4/40 , H01M12/08 , H01M16/003 , Y02E60/128 , Y02P90/40
摘要： Active metal fuel cells are provided. An active metal fuel cell has a renewable active metal (e.g., lithium) anode and a cathode structure that includes an electronically conductive component (e.g., a porous metal or alloy), an ionically conductive component (e.g., an electrolyte), and a fluid oxidant (e.g., air, water or a peroxide or other aqueous solution). The pairing of an active metal anode with a cathode oxidant in a fuel cell is enabled by an ionically conductive protective membrane on the surface of the anode facing the cathode.
摘要翻译： 提供了活性金属燃料电池。 活性金属燃料电池具有可再生活性金属（例如锂）阳极和阴极结构，其包括电子导电组分（例如，多孔金属或合金），离子导电组分（例如电解质）和流体 氧化剂（例如空气，水或过氧化物或其它水溶液）。 活性金属阳极与燃料电池中的阴极氧化剂的配对通过面向阴极的阳极表面上的离子导电保护膜来实现。
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公开(公告)号：US20130224593A1
公开(公告)日：2013-08-29
申请号：US13765522
申请日：2013-02-12
IPC分类号： H01M4/00
CPC分类号： H01M2/08 , H01B1/122 , H01M2/16 , H01M2/1686 , H01M2/18 , H01M4/00 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/366 , H01M4/667 , H01M4/668 , H01M4/70 , H01M6/30 , H01M6/34 , H01M6/42 , H01M10/052 , H01M10/34 , H01M12/06 , H01M12/08 , H01M2004/021 , H01M2004/027 , Y02E60/122 , Y02E60/128 , Y02P70/54
摘要： Protected anode architectures have ionically conductive protective membrane architectures that, in conjunction with compliant seal structures and anode backplanes, effectively enclose an active metal anode inside the interior of an anode compartment. This enclosure prevents the active metal from deleterious reaction with the environment external to the anode compartment, which may include aqueous, ambient moisture, and/or other materials corrosive to the active metal. The compliant seal structures are substantially impervious to anolytes, catholyes, dissolved species in electrolytes, and moisture and compliant to changes in anode volume such that physical continuity between the anode protective architecture and backplane are maintained. The protected anode architectures can be used in arrays of protected anode architectures and battery cells of various configurations incorporating the protected anode architectures or arrays.
摘要翻译： 受保护的阳极结构具有离子导电保护膜结构，其结合顺应性密封结构和阳极背板，有效地将活性金属阳极包围在阳极室的内部。 该外壳防止活性金属与阳极室外部的环境有害的反应，阳极室可包括水性环境水分和/或对活性金属具有腐蚀性的其它材料。 顺应性密封结构基本上不透过阳极电解液，阴极电解质，电解质中的溶解物质和水分，并且符合阳极体积的变化，从而维持阳极保护结构和背板之间的物理连续性。 受保护的阳极结构可用于保护阳极结构的阵列和包含受保护的阳极结构或阵列的各种配置的电池单元。
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公开(公告)号：US20130164628A1
公开(公告)日：2013-06-27
申请号：US13708540
申请日：2012-12-07
IPC分类号： H01M2/16
CPC分类号： H01M2/145 , H01M2/16 , H01M2/1673 , H01M6/18 , H01M6/181 , H01M6/182 , H01M6/185 , H01M6/187 , H01M6/188 , H01M10/0525 , H01M10/056 , H01M10/0562 , H01M10/0565 , H01M2300/0065 , H01M2300/0071 , H01M2300/008 , H01M2300/0094 , Y02E60/122 , Y02P70/54 , Y10T29/49108 , Y10T29/49115
摘要： Disclosed are ionically conductive membranes for protection of active metal anodes and methods for their fabrication. The membranes may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the membrane has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The membrane is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the membrane is incorporated.
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公开(公告)号：US20130122380A1
公开(公告)日：2013-05-16
申请号：US13663224
申请日：2012-10-29
IPC分类号： H01M12/06
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
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公开(公告)号：US08323820B2
公开(公告)日：2012-12-04
申请号：US12484063
申请日：2009-06-12
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
摘要翻译： Li /空气电池单元可配置为实现非常高的能量密度。 电池包括在阴极室中的受保护的锂金属或合金阳极和含水阴极电解液。 除了水性阴极电解液之外，阴极室的部件还包括空气阴极（例如氧气电极）和各种其它可能的元件。
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6.发明申请HIGH RATE SEAWATER ACTIVATED LITHIUM BATTERY CELLS BI-POLAR PROTECTED ELECTRODES AND MULTI-CELL STACKS 审中-公开高速海水活化锂电池双极保护电极和多层电池公开(公告)号：US20110269007A1
公开(公告)日：2011-11-03
申请号：US12973779
申请日：2010-12-20
IPC分类号： H01M10/02
CPC分类号： H01M6/34 , H01M2/1626 , H01M2/1653 , H01M4/06 , H01M4/38 , H01M4/382 , H01M4/405 , H01M4/582 , H01M12/00 , H01M2004/027 , H01M2004/029
摘要： Water activated alkali metal battery cells, protected anode bi-polar electrodes and multi-cell stacks are configurable to achieve very high energy density. The cells, bi-polar electrode and multi-cell stacks include a protected anode and a cathode having a solid phase electro-active component material that is reduced during cell discharge.
摘要翻译： 水活化的碱金属电池，受保护的阳极双极电极和多电池堆可配置以实现非常高的能量密度。 电池，双极电极和多电池堆包括受保护的阳极和具有在电池放电期间减少的固相电活性组分材料的阴极。
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公开(公告)号：US08048571B2
公开(公告)日：2011-11-01
申请号：US12649245
申请日：2009-12-29
申请人： Steven J. Visco , Yevgeniy S. Nimon
发明人： Steven J. Visco , Yevgeniy S. Nimon
IPC分类号： H01M4/36
CPC分类号： H01M4/628 , H01M2/1646 , H01M2/1653 , H01M2/1686 , H01M4/04 , H01M4/382 , H01M4/405 , H01M6/04 , H01M6/34 , H01M8/1016 , H01M10/0525 , H01M10/0562 , H01M10/058 , H01M10/24 , H01M10/36 , H01M10/38 , H01M12/06 , H01M12/08 , H01M16/00 , H01M16/003 , H01M2300/0071 , H01M2300/0094 , Y02E60/124 , Y02P70/54 , Y10T29/49108 , Y10T29/4911 , Y10T29/49115
摘要： Alkali (or other active) metal battery and other electrochemical cells incorporating active metal anodes together with aqueous cathode/electrolyte systems. The battery cells have a highly ionically conductive protective membrane adjacent to the alkali metal anode that effectively isolates (de-couples) the alkali metal electrode from solvent, electrolyte processing and/or cathode environments, and at the same time allows ion transport in and out of these environments. Isolation of the anode from other components of a battery cell or other electrochemical cell in this way allows the use of virtually any solvent, electrolyte and/or cathode material in conjunction with the anode. Also, optimization of electrolytes or cathode-side solvent systems may be done without impacting anode stability or performance. In particular, Li/water, Li/air and Li/metal hydride cells, components, configurations and fabrication techniques are provided.
摘要翻译： 碱（或其他活性）金属电池和其他电化学电池，其中加入活性金属阳极以及含水阴极/电解质体系。 电池单元具有与碱金属阳极相邻的高离子导电保护膜，其有效地将碱金属电极与溶剂，电解质处理和/或阴极环境隔离（去耦合），并且同时允许离子输入和输出 的这些环境。 以这种方式将阳极与电池单元或其它电化学电池的其它组件隔离允许使用与阳极结合的实际上任何溶剂，电解质和/或阴极材料。 此外，电解质或阴极侧溶剂体系的优化可以在不影响阳极稳定性或性能的情况下进行。 特别地，提供了Li /水，Li /空气和Li /金属氢化物电池，组件，构造和制造技术。
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8.发明申请PROTECTED ACTIVE METAL ELECTRODE AND BATTERY CELL WITH IONICALLY CONDUCTIVE PREOTECTIVE ARCHITECTURE 有权受保护的活性金属电极和具有导电预防性结构的电池公开(公告)号：US20110014522A1
公开(公告)日：2011-01-20
申请号：US12888154
申请日：2010-09-22
IPC分类号： H01M4/40 , H01M2/14 , H01M4/38 , H01M4/46 , H01M4/42 , H01M4/44 , H01M4/583 , H01M2/16 , H01M4/06
CPC分类号： H01M2/1673 , H01G11/06 , H01G11/52 , H01G11/58 , H01M2/1686 , H01M4/13 , H01M4/366 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2300/0002 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02P70/54 , Y10T29/49108
摘要： Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
摘要翻译： 活性金属和活性金属插入电极结构以及具有离子导电保护结构的电池单元，其包括通过浸渍有非水电解质（阳极电解液）的多孔隔离物与电极（阳极）分离的活性金属（例如锂）导电不渗透层。 这种保护结构防止活性金属与不透水层的另一（阴极）侧的环境有害的反应，其可以包括水性或非水性液体电解质（阴极电解液）和/或各种电化学活性材料，包括液体， 固体和气体氧化剂。 还提供了便于制造的安全性添加剂和设计。
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公开(公告)号：US20100112454A1
公开(公告)日：2010-05-06
申请号：US12607360
申请日：2009-10-28
IPC分类号： H01M2/00
CPC分类号： H01M2/08 , H01B1/122 , H01M2/16 , H01M2/1686 , H01M2/18 , H01M4/00 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/366 , H01M4/667 , H01M4/668 , H01M4/70 , H01M6/30 , H01M6/34 , H01M6/42 , H01M10/052 , H01M10/34 , H01M12/06 , H01M12/08 , H01M2004/021 , H01M2004/027 , Y02E60/122 , Y02E60/128 , Y02P70/54
摘要： Protected anode architectures have ionically conductive protective membrane architectures that, in conjunction with compliant seal structures and anode backplanes, effectively enclose an active metal anode inside the interior of an anode compartment. This enclosure prevents the active metal from deleterious reaction with the environment external to the anode compartment, which may include aqueous, ambient moisture, and/or other materials corrosive to the active metal. The compliant seal structures are substantially impervious to anolytes, catholyes, dissolved species in electrolytes, and moisture and compliant to changes in anode volume such that physical continuity between the anode protective architecture and backplane are maintained. The protected anode architectures can be used in arrays of protected anode architectures and battery cells of various configurations incorporating the protected anode architectures or arrays.
摘要翻译： 受保护的阳极结构具有离子导电保护膜结构，其结合顺应性密封结构和阳极背板，有效地将活性金属阳极包围在阳极室的内部。 该外壳防止活性金属与阳极室外部的环境有害的反应，阳极室可包括水性环境水分和/或对活性金属具有腐蚀性的其它材料。 顺应性密封结构基本上不透过阳极电解液，阴极电解质，电解质中的溶解物质和水分，并且符合阳极体积的变化，从而维持阳极保护结构和背板之间的物理连续性。 受保护的阳极结构可用于保护阳极结构的阵列和包含受保护的阳极结构或阵列的各种配置的电池单元。
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公开(公告)号：US20090311605A1
公开(公告)日：2009-12-17
申请号：US12484079
申请日：2009-06-12
IPC分类号： H01M4/58
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
摘要翻译： Li /空气电池单元可配置为实现非常高的能量密度。 电池包括在阴极室中的受保护的锂金属或合金阳极和含水阴极电解液。 除了水性阴极电解液之外，阴极室的部件还包括空气阴极（例如氧气电极）和各种其它可能的元件。
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