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公开(公告)号:US06262275B1
公开(公告)日:2001-07-17
申请号:US09368475
申请日:1999-08-04
申请人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
发明人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
IPC分类号: C07D41306
CPC分类号: C07D257/04 , A01N47/38
摘要: Novel 1-substituted methyltetrazolinones of the formula (I) wherein R1 represents a 5-membered heterocyclic radical which has 1 to 3 heteroatoms selected arbitrarily from the group consisting of N, O and S and which is optionally substituted by halogen and/or C1-4 alkyl, or represents oxiran-2-yl, optionally chloro-substituted pyridyl or C1-4 alkyl-S(O)m— wherein m represents 0, 1 or 2, or represents a C3-6 alicyclic hydrocarbon radical; R2 and R3 represent, independently of one another, C1-6 alkyl, C3-7 cycloalkyl or optionally substituted phenyl, or R2 and R3 may form, together with the N-atom to which they are bonded, an optionally substituted ring; R4 represents a hydrogen atom or methyl; and n represents 0 or 1; as well as for their preparation processes and novel intermediates in their production. The inventive compounds of formula (I) are used as herbicides.
摘要翻译: 式(I)的新的1-取代的甲基四唑啉酮,其中R 1表示具有1至3个杂原子的5元杂环基,其任选地由N,O和S组成,并且任选被卤素和/或C 1-4取代 烷基,或表示环氧乙烷-2-基,任选氯取代的吡啶基或C 1-4烷基-S(O)m - ,其中m表示0,1或2,或表示C 3-6脂族烃基; R 2和R 3彼此独立地表示C 1-6烷基,C 3-7环烷基或任选取代的苯基,或者R 2和R 3可以与它们所键合的N-原子一起形成任选取代的环; R4表示氢原子或甲基; n表示0或1; 以及它们的制备过程和新型中间体的生产。 本发明式(I)化合物用作除草剂。
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公开(公告)号:US6017853A
公开(公告)日:2000-01-25
申请号:US890432
申请日:1997-07-09
申请人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
发明人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Chieko Ueno , Yoshiko Kyo
IPC分类号: A01N47/38 , C07D257/04 , A01N43/72 , C07D413/12
CPC分类号: C07D257/04 , A01N47/38
摘要: Novel 1-substituted methyltetrazolinones of the formula (I) ##STR1## wherein R.sup.1 represents a 5-membered heterocyclic radical which has 1 to 3 heteroatoms selected arbitrarily from the group consisting of N, O and S and which is optionally substituted by halogen and/or C.sub.1-4 alkyl, or represents oxiran-2-yl, optionally chloro-substituted pyridyl or C.sub.1-4 alkyl-S(O).sub.m --wherein m represents 0, 1 or 2, or represents a C.sub.3-6 alicyclic hydrocarbon radical; R.sup.2 and R.sup.3 represent, independently of one another, C.sub.1-4 alkyl, C.sub.3-7 cycloalkyl or optionally substituted phenyl, or R.sup.2 and R.sup.3 may form, together with the N-atom to which they are bonded, an optionally substituted ring; R.sup.4 represents a hydrogen atom or methyl; and n represents 0 or 1; as well as for their preparation processes and novel intermediates in their production. The inventive compounds of formula (I) are used as herbicides.
摘要翻译: 式(I)的新型1-取代的甲基四唑啉酮,其中R 1表示具有1至3个杂原子的5元杂环基,其任选地由N,O和S组成的组中选择,并且其任选被卤素和/或C1- 或烷基,或表示环氧乙烷-2-基,任选氯取代的吡啶基或C 1-4烷基-S(O)m - ,其中m表示0,1或2,或表示C 3-6脂环族烃基; R 2和R 3彼此独立地表示C 1-4烷基,C 3-7环烷基或任选取代的苯基,或者R 2和R 3可以与它们所键合的N-原子一起形成任选取代的环; R4表示氢原子或甲基; n表示0或1; 以及它们的制备过程和新型中间体的生产。 本发明式(I)化合物用作除草剂。
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公开(公告)号:US5605920A
公开(公告)日:1997-02-25
申请号:US618954
申请日:1996-03-20
申请人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
发明人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
IPC分类号: C07D401/06 , A01N47/38 , C07D257/04 , C07D401/12 , C07D403/06 , C07D403/12 , A01N43/713 , A61K31/41
CPC分类号: C07D257/04 , A01N47/38 , C07D401/12 , C07D403/12
摘要: Disclosed are herbicidal tetrazolinone derivatives, selective in paddy fields of the formula ##STR1## wherein X represents C.sub.1-4 alkyl,n represents 1, 2, 3 or 4,R.sup.1 and R.sup.2 each independently represents C.sub.1-6 alkyl, C.sub.2-4 alkenyl, C.sub.2-6 alkynyl, C.sub.3-8 cycloalkyl, aryl which may optionally be substituted (wherein the substituent is at least one radical selected from the group consisting of halogen, C.sub.1-4 alkyl, C.sub.1-2 haloalkyl, C.sub.1-2 haloalkoxy, C.sub.1-2 haloalkylthio, acyl, nitro and cyano) or aralkyl optionally substituted by halogen orR.sup.1 and R.sup.2 form, together with the N-atom to which they are bonded, a cyclic ring which may be substituted. Also, disclosed are novel intermediates useful in the preparation of the compounds of formula (I).
摘要翻译: 公开了除草性四唑啉酮衍生物,其在式(I)的水田中是选择性的,其中X表示C1-4烷基,n表示1,2,3或4,R1和R2各自独立地表示C1-6烷基,C2- 4链烯基,C 2-6炔基,C 3-8环烷基,可任选取代的芳基(其中取代基是至少一个选自卤素,C 1-4烷基,C 1-2卤代烷基,C 1-2卤代烷氧基 ,C 1-2卤代烷硫基,酰基,硝基和氰基)或任选被卤素或R 1和R 2形式取代的芳烷基与它们所键合的N-原子一起可以被取代的环状基团。 还公开了可用于制备式(I)化合物的新型中间体。
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公开(公告)号:US6077866A
公开(公告)日:2000-06-20
申请号:US644139
申请日:1996-05-10
申请人: Yoshinori Kitagawa , Katsuaki Wada , Yoshiko Kyo , Yuichi Otsu , Yumi Hattori , Toru Obinata , Takahisa Abe , Katsuhiko Shibuya , Wolfram Andersch
发明人: Yoshinori Kitagawa , Katsuaki Wada , Yoshiko Kyo , Yuichi Otsu , Yumi Hattori , Toru Obinata , Takahisa Abe , Katsuhiko Shibuya , Wolfram Andersch
IPC分类号: C07C317/28 , A01N33/26 , A01N35/10 , A01N37/28 , A01N41/10 , A01N47/24 , A01N47/34 , C07C317/24 , C07C323/08 , C07C323/22 , C07C323/45 , C07C323/48 , C07C323/60 , C07C327/22 , C07C329/16 , C07C331/04 , C07C335/32 , C07F7/08 , A01N47/12
CPC分类号: C07C335/32 , A01N35/10 , A01N37/28 , A01N47/24 , A01N47/34 , C07C317/24 , C07C317/28 , C07C323/08 , C07C323/22 , C07C323/48 , C07C323/60 , C07C327/22 , C07C329/16 , C07C331/04 , C07F7/0818
摘要: Novel benzophenonehydrazone derivatives represented by the formula (I): ##STR1## wherein, R.sup.1 is halogen; R.sup.2 is hydrogen or C.sub.1-4 alkyl; R.sup.3 is cyano, optically substituted C.sub.1-4 alkyl, C.sub.2-4 alkenyl, C.sub.3-4 alkynyl, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl; R.sup.4 is hydrogen, phenyl, optionally substituted C.sub.1-6 alkyl, optionally substituted C.sub.2-8 alkenyl, --CO--R.sup.8, --CO--O--R.sup.9 or ##STR2## R.sup.5 is hydrogen, formyl, phenyl, optionally substituted C.sub.1-8 alkyl, optionally substituted C.sub.2-8 alkenyl, optionally substituted C.sub.3-8 alkynyl, optionally substituted C.sub.1-8 alkyl-arbonyl, optionally substituted C.sub.1-6 alkyl-oxalyl, optionally substituted C.sub.1-8 alkoxy-carbonyl, optionally substituted C.sub.1-8 alkoxy-oxalyl, optionally substituted C.sub.3-8 cycloalkyl-carbonyl, optionally substituted C.sub.2-8 alkenyl-carbonyl or optionally substituted benzoyl; R.sup.6 is hydrogen or halogen; R.sup.7 is hydrogen, halogen or C.sub.1-2 alkyl, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl; n is 0, 1 or 2, provided that n is 0 when R.sup.3 is cyano, C.sub.1-4 alkyl-carbonyl or C.sub.1-4 alkoxy-thiocarbonyl, is a single bond of Anti form or of Syn form.The benzophenonehydrazone derivatives of the formula (I) have excellent insecticidal activities.
摘要翻译: 由式(I)表示的新型二苯甲酮腙衍生物:其中,R1为卤素; R2是氢或C1-4烷基; R3是氰基,光学取代的C1-4烷基,C2-4烯基,C3-4炔基,C1-4烷基羰基或C1-4烷氧基 - 硫代羰基; R4是氢,苯基,任选取代的C 1-6烷基,任选取代的C 2-8烯基,-CO-R 8,-CO-O-R 9或R 5是氢,甲酰基,苯基,任选取代的C 1-8烷基,任选取代的C 2 -8-烯基,任选取代的C 3-8炔基,任选取代的C 1-8烷基 - 羰基,任选取代的C 1-6烷基 - 草酰基,任选取代的C 1-8烷氧羰基,任选取代的C 1-8烷氧基 - 草酰基,任选取代的C 3 -8环烷基 - 羰基,任选取代的C 2-8烯基 - 羰基或任选取代的苯甲酰基; R6是氢或卤素; R7是氢,卤素或C1-2烷基,C1-4烷基羰基或C1-4烷氧基 - 硫代羰基; n为0,1或2,条件是当R 3为氰基时,n为0,C 1-4烷基 - 羰基或C 1-4烷氧基 - 硫代羰基,+ Z为抗式或Syn形式的单键。 式(I)的二苯甲酮腙衍生物具有优异的杀虫活性。
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公开(公告)号:US5650374A
公开(公告)日:1997-07-22
申请号:US553160
申请日:1995-11-07
申请人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo
发明人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo
IPC分类号: C07D401/06 , A01N47/38 , C07D257/04 , C07D403/06 , C07D405/12 , A01N43/713 , A01N43/72
CPC分类号: C07D257/04 , A01N47/38
摘要: Herbicidal 1-cyclopropyl tetrazolinones of the formula ##STR1## wherein X represents C.sub.1-3 alkyl, C.sub.2-4 alkenyl or halogen,n represents 0 to 5,R.sup.1 and R.sup.2 each independently represents C.sub.1-6 alkyl, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl, C.sub.3-7 cycloalkyl which may optionally be substituted by C.sub.1-3 alkyl, epoxy-C.sub.3-5 alkan-1-yl, phenyl which may optionally be substituted, or aralkyl which may optionally be substituted, orR.sup.1 and R.sup.2 together with the N-atom to which they are attached, represent a cyclic ring which may be substituted, and some novel intermediates therefor.
摘要翻译: 式(I)的除草1-环丙基四唑啉酮其中X代表C1-3烷基,C2-4烯基或卤素,n代表0-5,R1和R2各自独立地表示C1-6烷基,C2-6烯基 C 2-6炔基,可任选被C 1-3烷基取代的C 3-7环烷基,环烷基-C 3-5烷基-1-基,可任意被取代的苯基或可任意被取代的芳烷基,或R 1和 R2与它们所连接的N-原子一起表示可以被取代的环状环,以及一些新的中间体。
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公开(公告)号:US5668087A
公开(公告)日:1997-09-16
申请号:US616674
申请日:1996-03-15
申请人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo , Natsuko Minegishi
发明人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Kazuhiro Ukawa , Yoshiko Kyo , Natsuko Minegishi
IPC分类号: C07D401/06 , A01N47/38 , C07D257/04 , C07D403/06 , A01N43/713
CPC分类号: C07D257/04 , A01N47/38
摘要: Herbicidal 1-alkenyltetrazolinones of the formula: ##STR1## wherein R.sup.1 represents the group: ##STR2## or the group: ##STR3## R.sup.2 and R.sup.3, independently of one another, represent C.sub.1-6 alkyl, C.sub.3-7 cycloalkyl which may optionally be substited by methyl, C.sub.2-4 alkenyl, C.sub.2-5 alkynyl, phenyl which may optionally be substituted or aralkyl which may optionally be substituted, orR.sup.2 and R.sup.3 may optionally form, together with the N-atom to which they are bonded, a heterocyclic ring which may optionally be substituted, and novel intermediates therefor.
摘要翻译: 下式的除草1-烯基四唑啉酮:彼此独立地表示C 1-6烷基,可以任选地被甲基,C 2-4烯基,C 2-5炔基,可任选被取代的苯基或任选被取代的芳基烷基的C 3-7环烷基 可以任选地被取代,或者R 2和R 3可以任选地与它们所键合的N-原子一起形成可以任选被取代的杂环,以及其新颖的中间体。
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公开(公告)号:US5654257A
公开(公告)日:1997-08-05
申请号:US601748
申请日:1996-02-15
申请人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
发明人: Toshio Goto , Yoshinori Kitagawa , Seishi Ito , Katsuhiko Shibuya , Tatsuya Yamaoka , Chieko Ueno , Yoshiko Kyo
IPC分类号: C07D401/06 , A01N47/38 , C07D257/04 , C07D403/06 , A01N43/713
CPC分类号: C07D257/04 , A01N47/38
摘要: 1-cycloalkenyltetrazolinone derivatives of the following herbicidal formula ##STR1## R.sup.1 is cycloalkenyl which may optionally be substituted by halogen C.sub.1-4 alkyl, or bicycloalkenyl which may optionally be substituted by halogen or C.sub.1-4 alkyl, andR.sup.2 and R.sup.3 each independently is alkyl, cycloalkyl, phenyl (optionally substituted by a member selected from the group consisting of nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and alkylthio), alkenyl and alkynyl,orR.sup.2 and R.sup.3 together with the N-atom to which they are bonded form, a 5- or 6-membered heterocyclic ring which may optionally contain a further hetero atom, said heterocyclic ring optionally being benzo-condensed, or a C-.sub.1-4 alkyl,and intermediates therefore of the formula ##STR2##
摘要翻译: 以下除草式R 1的1-环烯基四唑啉酮衍生物是可任选被卤素C 1-4烷基取代的环烯基,或可任意被卤素或C 1-4烷基取代的双环烯基,R 2和R 3各自独立地为烷基 ,环烷基,苯基(任选被选自硝基,氰基,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基和烷硫基的成员取代),烯基和炔基,或者R 2和R 3与它们的N-原子一起 键合形式,可任选地含有另外的杂原子的所述5或6元杂环,所述杂环任选地被苯并稠合,或C 1-4烷基,因此具有下式的中间体:
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