In-situ process for the monitoring of localized pitting corrosion
    1.
    发明授权
    In-situ process for the monitoring of localized pitting corrosion 失效
    用于局部点腐蚀的监测的现场处理

    公开(公告)号:US5888374A

    公开(公告)日:1999-03-30

    申请号:US855707

    申请日:1997-05-08

    IPC分类号: G01N17/02 G01N27/26

    CPC分类号: G01N17/02

    摘要: A method and apparatus are provided for monitoring localized pitting corrosion in metal pipes or storage vessels. Electrochemical probes are used for sensing electrochemical noise voltage values and electrochemical noise current values. The root-mean-square electrochemical noise current and voltage values are calculated and stored for the sensed electrochemical noise voltage values and the electrochemical noise current values. The stored electrochemical noise current and voltage values are processed by transforming the stored electrochemical noise current and voltage values into power spectral density data utilizing a fast Fourier transform. A slope of the power spectral density data relative to frequency is calculated. The electrochemical probes include a pair of working electrodes formed of the same material of the monitored metal pipes or storage vessels and a reference electrode formed of a corrosion resistant material. A linear slope of a low-frequency portion of the power spectral density data is calculated by using a least-square method.

    摘要翻译: 提供了一种用于监测金属管或储存容器中局部点腐蚀的方法和装置。 电化学探针用于检测电化学噪声电压值和电化学噪声电流值。 计算并存储均方根电化学噪声电流和电压值,用于感测的电化学噪声电压值和电化学噪声电流值。 通过使用快速傅里叶变换将存储的电化学噪声电流和电压值转换成功率谱密度数据来处理存储的电化学噪声电流和电压值。 计算相对于频率的功率谱密度数据的斜率。 电化学探针包括由监测的金属管或储存容器的相同材料形成的一对工作电极和由耐腐蚀材料形成的参比电极。 利用最小二乘法计算功率谱密度数据的低频部分的线性斜率。

    Devices using resin wafers and applications thereof
    3.
    发明授权
    Devices using resin wafers and applications thereof 有权
    使用树脂晶片的设备及其应用

    公开(公告)号:US07507318B2

    公开(公告)日:2009-03-24

    申请号:US11082469

    申请日:2005-03-17

    IPC分类号: C25C3/00

    摘要: Devices incorporating a thin wafer of electrically and ionically conductive porous material made by the method of introducing a mixture of a thermoplastic binder and one or more of anion exchange moieties or cation exchange moieties or mixtures thereof and/or one or more of a protein capture resin and an electrically conductive material into a mold. The mixture is subjected to temperatures in the range of from about 60° C. to about 170° C. at pressures in the range of from about 0 to about 500 psig for a time in the range of from about 1 to about 240 minutes to form thin wafers. Devices include electrodeionization and separative bioreactors in the production of organic and amino acids, alcohols or esters for regenerating cofactors in enzymes and microbial cells.

    摘要翻译: 通过引入热塑性粘合剂和一种或多种阴离子交换部分或阳离子交换部分或其混合物和/或一种或多种蛋白质捕获树脂的混合物的方法制成的电离离子导电多孔材料薄片的装置 并将导电材料导入模具中。 将混合物在约0℃至约500psig的压力范围内经受约60℃至约170℃的温度,时间范围为约1至约240分钟至 形成薄晶圆。 器件包括在生产有机和氨基酸中的电去离子和分离生物反应器,用于在酶和微生物细胞中再生辅因子的醇或酯。

    Retention of counterions in the separative bioreactor
    5.
    发明授权
    Retention of counterions in the separative bioreactor 有权
    在分离生物反应器中保留抗衡离子

    公开(公告)号:US08007647B2

    公开(公告)日:2011-08-30

    申请号:US12005586

    申请日:2007-12-27

    IPC分类号: B01D61/48

    摘要: A bioreactor with an anode and a cathode, and a plurality of reaction chambers each having an inlet and an outlet and each including a porous solid ion exchange wafer having ion-exchange resins. Each of the reaction chambers is interleaved between a cation exchange membrane and an anion exchange membrane or between either a cation or an anion exchange membrane and a bipolar exchange membrane. A product chamber is separated from one of the reaction chambers by either a cation or an anion exchange membrane. Recirculation mechanism is provided for transporting material between the reaction chamber inlets and outlets. A method of producing organic acids, amino acids, or amines using the separative bioreactor is disclosed.

    摘要翻译: 具有阳极和阴极的生物反应器和多个具有入口和出口的反应室,每个反应室均包含具有离子交换树脂的多孔固体离子交换晶片。 每个反应室在阳离子交换膜和阴离子交换膜之间或阳离子或阴离子交换膜和双极交换膜之间交错。 通过阳离子或阴离子交换膜将产物室与一个反应室分离。 提供循环机构用于在反应室入口和出口之间输送材料。 公开了使用分离式生物反应器生产有机酸,氨基酸或胺的方法。

    Electronically and ionically conductive porous material and method for manufacture of resin wafers therefrom
    6.
    发明授权
    Electronically and ionically conductive porous material and method for manufacture of resin wafers therefrom 有权
    电子和离子导电多孔材料及其制造树脂晶片的方法

    公开(公告)号:US07977395B2

    公开(公告)日:2011-07-12

    申请号:US12288554

    申请日:2008-10-21

    IPC分类号: H01B1/24 C08J5/22

    CPC分类号: H01B1/122 H01B1/24

    摘要: An electrically and ionically conductive porous material including a thermoplastic binder and one or more of anion exchange moieties or cation exchange moieties or mixtures thereof and/or one or more of a protein capture resin and an electrically conductive material. The thermoplastic binder immobilizes the moieties with respect to each other but does not substantially coat the moieties and forms the electrically conductive porous material. A wafer of the material and a method of making the material and wafer are disclosed.

    摘要翻译: 包括热塑性粘合剂和一种或多种阴离子交换部分或阳离子交换部分或其混合物和/或蛋白质捕获树脂和导电材料中的一种或多种的电离离子导电多孔材料。 热塑性粘合剂相对于彼此固定部分,但基本上不涂布部分并形成导电多孔材料。 公开了材料的晶片和制造材料和晶片的方法。

    Retention of counterions in the separative bioreactor
    8.
    发明申请
    Retention of counterions in the separative bioreactor 有权
    在分离生物反应器中保留抗衡离子

    公开(公告)号:US20080187902A1

    公开(公告)日:2008-08-07

    申请号:US12005586

    申请日:2007-12-27

    摘要: A bioreactor with an anode and a cathode, and a plurality of reaction chambers each having an inlet and an outlet and each including a porous solid ion exchange wafer having ion-exchange resins. Each of the reaction chambers is interleaved between a cation exchange membrane and an anion exchange membrane or between either a cation or an anion exchange membrane and a bipolar exchange membrane. A product chamber is separated from one of the reaction chambers by either a cation or an anion exchange membrane. Recirculation mechanism is provided for transporting material between the reaction chamber inlets and outlets. A method of producing organic acids, amino acids, or amines using the separative bioreactor is disclosed.

    摘要翻译: 具有阳极和阴极的生物反应器和多个具有入口和出口的反应室,每个反应室均包括具有离子交换树脂的多孔固体离子交换晶片。 每个反应室在阳离子交换膜和阴离子交换膜之间或阳离子或阴离子交换膜和双极交换膜之间交错。 通过阳离子或阴离子交换膜将产物室与一个反应室分离。 提供循环机构用于在反应室入口和出口之间输送材料。 公开了使用分离式生物反应器生产有机酸,氨基酸或胺的方法。

    Bioprocess utilizing carbon dioxide and electrodeionization
    9.
    发明授权
    Bioprocess utilizing carbon dioxide and electrodeionization 有权
    生物处理利用二氧化碳和电去离子

    公开(公告)号:US08580096B2

    公开(公告)日:2013-11-12

    申请号:US13248231

    申请日:2011-09-29

    IPC分类号: B01D61/48

    摘要: A method for producing succinic acid is provided, which comprises circulating a fermentation broth containing succinate ion through an electrodeionization apparatus. The apparatus comprises an anode; a cathode; a stacked ion-exchange assembly comprising a one or more oriented ion-exchange units between the anode and the cathode. Each ion-exchange unit comprises a porous ion-exchange resin wafer including an inlet and an outlet together are adapted to circulate a liquid reaction stream containing a carboxylate anion from a fermentor through the resin wafer; a flow-distributing gasket for circulating a product stream through a product reservoir; an anion exchange membrane for transporting at least a portion of the carboxylate anion to the product stream; and a bipolar ion-exchange membrane to direct protons toward the cathode and into the product stream and to direct hydroxyl ions toward the anode and into the reaction stream in the resin wafer of an adjacent ion-exchange unit.

    摘要翻译: 提供了一种生产琥珀酸的方法,其包括使含有琥珀酸离子的发酵液循环通过电去离子装置。 该装置包括阳极; 阴极 包括在阳极和阴极之间的一个或多个取向离子交换单元的层叠离子交换组件。 每个离子交换单元包括多孔离子交换树脂晶片,其包括入口和出口,一起适于使含有羧酸根阴离子的液体反应物流从发酵罐循环通过树脂晶片; 用于使产品流循环通过产品储存器的流量分配垫圈; 用于将至少一部分羧酸根阴离子输送到产物流的阴离子交换膜; 和双极离子交换膜,以将质子引向阴极并进入产物流,并将羟基离子引向阳极并进入相邻离子交换单元的树脂晶片中的反应流中。