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公开(公告)号:US10927235B2
公开(公告)日:2021-02-23
申请号:US15741785
申请日:2016-07-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tatsuo Fukushi , Larry A. Last , Michael H. Mitchell
IPC: C08F214/26 , C08K5/3492 , C08K5/00 , C08K5/14 , C08F214/22
Abstract: Described herein is a composition comprising: a fluorinated thermosetting plastic comprising repeating divalent monomeric units derived from TFE, HFP and VDF and further comprising a least 0.1-1% by weight iodine endgroups, wherein the fluorinated thermosetting plastic has an MFI greater than 5 g/10 min at 265° C. and 5 kg; and a curing agent.
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公开(公告)号:US10590224B2
公开(公告)日:2020-03-17
申请号:US15742202
申请日:2016-07-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael H. Mitchell , Denis Duchesne , Tatsuo Fukushi , Werner M. A. Grootaert , Larry A. Last , Peter J. Scott , Karl D. Weilandt
IPC: C08F299/02 , C08F293/00 , C08F16/24 , C08F214/22 , C08F214/26 , C08F214/28 , C08K5/14
Abstract: Described herein is a millable fluorinated block copolymer having at least one A block and at least one B block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from TFE, HFP and VDF; and the B block is a segment comprising repeating dilvalent monomeric units derived from HFP and VDF; and wherein the millable fluorinated block copolymer has a modulus of 0.1 to 2.5 MPa at 100° C.
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公开(公告)号:US20190352444A1
公开(公告)日:2019-11-21
申请号:US16477006
申请日:2018-01-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael H. Mitchell , Denis Duchesne , Tatsuo Fukushi , Larry A. Last , Peter J. Scott , Karl D. Weilandt
IPC: C08F293/00
Abstract: There is provided a curable composition comprising a fluorinated block copolymer having (a) at least one A block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from at least a fluorinated monomer; and (b) at least one B block, wherein the B block is a segment comprising repeating divalent monomeric units that comprises at least a fluorinated monomer and a nitrile-containing cure-site monomer.
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公开(公告)号:US11267922B2
公开(公告)日:2022-03-08
申请号:US16477006
申请日:2018-01-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael H. Mitchell , Denis Duchesne , Tatsuo Fukushi , Larry A. Last , Peter J. Scott , Karl D. Weilandt
IPC: C08F293/00 , C08F214/22 , C08F214/26 , C08F214/28 , C08F216/14
Abstract: There is provided a curable composition comprising a fluorinated block copolymer having (a) at least one A block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from at least a fluorinated monomer; and (b) at least one B block, wherein the B block is a segment comprising repeating divalent monomeric units that comprises at least a fluorinated monomer and a nitrile-containing cure-site monomer.
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公开(公告)号:US11261280B2
公开(公告)日:2022-03-01
申请号:US16477019
申请日:2018-01-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael H. Mitchell , Denis Duchesne , Tatsuo Fukushi , Larry A. Last , Peter J. Scott , Karl D. Weilandt
IPC: C08F293/00 , C08F2/22 , C08F214/16 , C08F214/22 , C08F214/26 , C08F214/28 , C08K5/14
Abstract: Described herein is a millable fluorinated block copolymer having (a) at least one A block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from at least TFE, HFP and VDF; (b) at least one B block, wherein the B block is a segment comprising repeating divalent monomeric units derived from at least HFP and VDF; and (c) a bisolefin monomer, wherein at least (i) the semi-crystalline segment of the A block comprises repeating divalent monomeric units derived from TFE, HFP, VDF, and the bisolefin monomer, (ii) the segment of the B block comprises repeating divalent monomeric units derived from HFP, VDF, and the bisolefin monomer, or (iii) a combination thereof; and wherein the millable fluorinated block copolymer has a modulus of 0.1 to 2.5 MPa at 100° C.
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公开(公告)号:US20210284780A1
公开(公告)日:2021-09-16
申请号:US16477019
申请日:2018-01-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Michael H. Mitchell , Denis Duchesne , Tatsuo Fukushi , Larry A. Last , Peter J. Scott , Karl D. Weilandt
IPC: C08F293/00 , C08F214/22 , C08F214/26 , C08F214/28 , C08F214/16 , C08F2/22 , C08K5/14
Abstract: Described herein is a millable fluorinated block copolymer having (a) at least one A block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from at least TFE, HFP and VDF; (b) at least one B block, wherein the B block is a segment comprising repeating dilvalent monomeric units derived from at least HFP and VDF; and (c) a bisolefin monomer, wherein at least (i) the semi-crystalline segment of the A block comprises repeating divalent monomeric units derived from TFE, HFP, VDF, and the bisolefin monomer, (ii) the segment of the B block comprises repeating divalent monomeric units derived from HFP, VDF, and the bisolefin monomer, or (iii) a combination thereof; and wherein the millable fluorinated block copolymer has a modulus of 0.1 to 2.5 MPa at 100° C.
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公开(公告)号:US10723868B2
公开(公告)日:2020-07-28
申请号:US15767893
申请日:2016-10-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Claude Lavallée , Peter J. Scott , Denis Duchesne , Dale E. Hutchens , Larry A. Last , Kirsten J. Fronek , Thomas J. Blong
Abstract: A polymer composition includes a non-fluorinated, thermoplastic polymer and a minor amount of a fluoropolymer combined with the non-fluorinated polymer. A polymer processing additive composition that includes a fluoropolymer and a polymer processing additive synergist is also disclosed. The fluoropolymer includes diads represented by formula —CF2-CF(R)—CH(R′)—CF(R″)— in a range from about 23 mole percent to about 50 mole percent. Each R is independently —CF3, —Rf, or —ORf, each R′ and R″ are independently H, F, CF3, or —Rf, and each Rf is independently a perfluoroalkyl group having from 1 to 12 carbon atoms and optionally interrupted by one or more —O— groups. A method of reducing melt defects during the extrusion of a polymer is also disclosed.
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公开(公告)号:US20180208743A1
公开(公告)日:2018-07-26
申请号:US15741785
申请日:2016-07-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tatsuo Fukushi , Larry A. Last , Michael H. Mitchell
IPC: C08K5/3492
CPC classification number: C08K5/34924 , C08F214/22 , C08F214/26 , C08K5/0025 , C08K5/14 , C08L27/12 , C08L27/16 , C08L27/18
Abstract: Described herein is a composition comprising: a fluorinated thermosetting plastic comprising repeating divalent monomeric units derived from TFE, HFP and VDF and further comprising a least 0.1-1% by weight iodine endgroups, wherein the fluorinated thermosetting plastic has an MFI greater than 5 g/10 min at 265° C. and 5 kg; and a curing agent.
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公开(公告)号:US20180312673A1
公开(公告)日:2018-11-01
申请号:US15767893
申请日:2016-10-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Claude Lavallée , Peter J. Scott , Denis Duchesne , Dale E. Hutchens , Larry A. Last , Kirsten J. Fronek , Thomas J. Blong
IPC: C08L23/06
CPC classification number: C08L23/06 , B29B7/88 , B29C48/022 , B29K2023/0625 , C08L27/06 , C08L2205/02 , C08L2205/03 , C08L2205/06 , C08L2205/08 , C08L2207/066 , C08L27/16 , C08L27/20
Abstract: A polymer composition includes a non-fluorinated, thermoplastic polymer and a minor amount of a fluoropolymer combined with the non-fluorinated polymer. A polymer processing additive composition that includes a fluoropolymer and a polymer processing additive synergist is also disclosed. The fluoropolymer includes diads represented by formula —CF2-CF(R)—CH(R′)—CF(R″)— in a range from about 23 mole percent to about 50 mole percent. Each R is independently —CF3, —Rf, or —ORf, each R′ and R″ are independently H, F, CF3, or —Rf, and each Rf is independently a perfluoroalkyl group having from 1 to 12 carbon atoms and optionally interrupted by one or more —O— groups. A method of reducing melt defects during the extrusion of a polymer is also disclosed.
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