Use of amide or imide co-catalysts for nitroxide mediated oxidation
    2.
    发明授权
    Use of amide or imide co-catalysts for nitroxide mediated oxidation 失效
    酰胺或酰亚胺助催化剂用于硝基氧介导的氧化

    公开(公告)号:US06540876B1

    公开(公告)日:2003-04-01

    申请号:US09575303

    申请日:2000-05-19

    IPC分类号: D21H1120

    CPC分类号: D21H11/20 C08B15/02 C08B31/18

    摘要: This invention pertains to the use of compounds containing amide or imide type functional groups to increase the rate of nitroxide mediated oxidation of alcohols, particularly primary and secondary alcohols. While suitable for oxidation of alcohol groups on a variety of substrates, it is particularly useful to oxidize cellulose, cellulose pulp or cellulose fiber such that it is commercially compatible with the traditional paper making process. Such co-catalysts may be used to increase the absolute amount of aldehyde groups on cellulose, cellulose pulp or cellulose fiber, thereby further increasing the inherent wet strength, temporary wet strength, and dry strength of paper made with such cellulose, cellulose pulp or cellulose fiber.

    摘要翻译: 本发明涉及使用含有酰胺或酰亚胺型官能团的化合物来提高醇,特别是伯醇和仲醇的氮氧化物介导的氧化速率。 氧化纤维素,纤维素纸浆或纤维素纤维时,它适用于各种基材上的醇基氧化,特别适用于与传统的造纸工艺相容。 这样的助催化剂可用于增加纤维素,纤维素纸浆或纤维素纤维上的醛基的绝对量,从而进一步提高用这种纤维素,纤维素纸浆或纤维素制成的纸的固有湿强度,临时湿强度和干强度 纤维。