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公开(公告)号:US20200316926A1
公开(公告)日:2020-10-08
申请号:US16905966
申请日:2020-06-19
Applicant: AGC Inc.
Inventor: Shuhei OCHI , Tomoaki GOMI , Shun SAITO
Abstract: To provide a decorative film, whereby formation of wrinkles is suppressed when bonded to a three dimensional molded product in a stretched state, a method for producing a decorative film, a method for producing a decorative film-attached three dimensional molded product, and a fluorinated polymer composition. The decorative film of the present invention is a decorative film having at least a base film layer and a fluorinated layer containing a crosslinked fluorinated polymer, wherein the crosslinked fluorinated polymer is a crosslinked product of a crosslinkable polymer comprising units based on a fluoroolefin and units having a crosslinkable group, and the average molecular weight between crosslinking groups of the crosslinked fluorinated polymer is from 500 to 50,000.
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公开(公告)号:US20230399549A1
公开(公告)日:2023-12-14
申请号:US18234982
申请日:2023-08-17
Applicant: AGC INC.
Inventor: Takashi YOSHIDA , Shuhei OCHI , Takashi TAKAYANAGI
CPC classification number: C09J7/385 , C09J7/25 , C09J11/08 , C09J2301/414 , C09J2301/408 , C09J2427/00 , C09J2433/00 , C09J2475/006 , C09J2483/00
Abstract: To provide a laminate excellent in stretchability and solvent resistance. A laminate comprising a base film and a clear layer, wherein the clear layer is a layer formed by curing a composition containing a fluorinated polymer having hydroxy or carboxy groups, a non-fluorinated polymer, and a curing agent having functional groups that react with the hydroxy or carboxy groups, and the hydroxy value or acid value of the fluorinated polymer is at least 20 mgKOH/g, and the content of the fluorinated polymer is at most 30 mass % to the total content of the fluorinated polymer and the non-fluorinated polymer.
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公开(公告)号:US20210101376A1
公开(公告)日:2021-04-08
申请号:US17117567
申请日:2020-12-10
Applicant: AGC Inc.
Inventor: Shuhei OCHI , Shiori YOSHIGAMI , Shun SAITO , Takashi YOSHIDA , Yoshiya MATSUDA
Abstract: To provide a decorative film in which swelling of a layer containing a fluorinated polymer is suppressed and adhesion of the layer containing the fluorinated polymer is excellent; and a method for producing a three-dimensional molded product provided with a decorative film. The decorative film is characterized by comprising a base film containing a plasticizer; a first layer containing at least one member selected from the group consisting of a polyvinylidene fluoride, a polymethyl methacrylate and a polyurethane; and a second layer containing a fluorinated polymer comprising units based on a fluoroolefin and units based on at least one type of non-fluorinated monomer selected from the group consisting of a vinyl ether, a vinyl ester, an allyl ether and an allyl ester, in this order; wherein the water contact angle of the surface on the first layer side of the second layer is larger than the water contact angle on the second layer side of the first layer, and the difference between the water contact angle of the surface on the first layer side of the second layer and the water contact angle of the surface on the second layer side of the first layer is more than 0° and at most 50°.
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公开(公告)号:US20200317835A1
公开(公告)日:2020-10-08
申请号:US16905972
申请日:2020-06-19
Applicant: AGC Inc.
Inventor: Shuhei OCHI , Tomoaki GOMI , Shun SAITO
Abstract: To provide a decorative film whereby formation of wrinkles is suppressed when attached to a three dimensional molded product in a stretched state, and a method for producing a decorative film-attached three dimensional molded product. The decorative film of the present invention is a decorative film having at least a base film and a top layer containing a fluorinated polymer, the top layer being disposed on one surface, wherein the surface reflection intensity Wa at a wavelength of from 0.1 to 0.3 mm and the surface reflection intensity Wb at a wavelength of from 0.3 to 1.0 mm, of the top layer as measured by using a wave scan apparatus in such a state that the decorative film is stretched by 1.5 times, are both at most 30.0.
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公开(公告)号:US20210095084A1
公开(公告)日:2021-04-01
申请号:US17117896
申请日:2020-12-10
Applicant: AGC Inc.
Inventor: Shuhei OCHI , Shiori YOSHIGAMI , Shun SAITO
IPC: C08J5/18 , C08L27/12 , B29C65/00 , B29C51/10 , B29C51/12 , B29C51/14 , B32B27/08 , B32B27/26 , B32B27/30 , B32B7/12
Abstract: To provide a decorative film whereby cracking is suppressed when the decorative film is adhered to a three-dimensional molded product while it is being stretched or in a stretched state. To further provide a composition, a method for producing the decorative film, and a method for producing a three-dimensional molded product provided with the decorative film. The decorative film has at least a base film and a fluororesin layer containing a fluororesin having a crosslinked structure, characterized in that the fluororesin layer contains a urethane bond and an allophanate bond, and the average molecular weight between crosslinking-points of the fluororesin layer is more than 50,000 and at most 100,000.
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6.
公开(公告)号:US20200231836A1
公开(公告)日:2020-07-23
申请号:US16836994
申请日:2020-04-01
Applicant: AGC Inc.
Inventor: Shun SAITO , Shuhei OCHI , Shiori YOSHIGAMI
IPC: C09D127/12 , C09D7/63 , C09D7/65
Abstract: To provide an aqueous coating material which is capable of forming a coating film excellent in stain resistance; a coating film; and a method for producing a substrate with a coating film. An aqueous coating material of the present invention comprises a fluorinated non-block copolymer which comprises units based on a fluoroolefin and units having a hydrophilic group, a fluorinated block copolymer which has a fluorinated segment comprising units based on a monomer having a perfluoroalkyl group and a non-fluorinated segment containing no fluorine atom, an anionic surfactant, of which the HLB value is at least 17.5, and water.
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