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    CATIONIC POLYMERS FOR ANTIMICROBIAL APPLICATIONS AND DELIVERY OF BIOACTIVE MATERIALS
    2.
    发明申请
    CATIONIC POLYMERS FOR ANTIMICROBIAL APPLICATIONS AND DELIVERY OF BIOACTIVE MATERIALS 有权
    用于抗生素应用和递送生物材料的阳离子聚合物

    公开(公告)号：US20140220093A1

    公开(公告)日：2014-08-07

    申请号：US14246045

    申请日：2014-04-05

    申请人： AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH ,  INTERNATIONAL BUSINESS MACHINES CORPORATION

    发明人： Daniel J. Coady ,  Amanda C. Engler ,  Kazuki Fukushima ,  James L. Hedrick ,  Jeremy P. K. Tan ,  Yi Yan Yang

    IPC分类号： A01N37/44

    CPC分类号： A01N37/44 ,  A01N33/12 ,  A61K48/0041 ,  C08G83/004 ,  C12N15/88 ,  A01N25/10 ,  A01N2300/00

    摘要： A cationic star polymer is disclosed of the general formula (1): wherein w′ is a positive number greater than or equal to 3, I′ is a dendritic polyester core covalently linked to w′ independent peripheral linear cationic polymer chains P′. Each of the chains P′ comprises a cationic repeat unit comprising i) a backbone functional group selected from the group consisting of aliphatic carbonates, aliphatic esters, aliphatic carbamates, aliphatic ureas, aliphatic thiocarbamates, aliphatic dithiocarbonates, and combinations thereof, and ii) a side chain comprising a quaternary amine group. The quaternary amine group comprises a divalent methylene group directly covalently linked to i) a positive charged nitrogen and ii) an aromatic ring.

    摘要翻译： 公开了通式（1）的阳离子星形聚合物：其中w'是大于或等于3的正数，I'是与w'独立的外部线性阳离子聚合物链P'共价连接的树枝状聚酯芯。 每个链P'包含阳离子重复单元，其包含i）选自脂族碳酸酯，脂族酯，脂族氨基甲酸酯，脂族脲，脂族硫代氨基甲酸酯，脂族二硫代碳酸酯及其组合的骨架官能团，和ii） 侧链包含季胺基。 季胺基包括与i）正电荷氮和ii）芳环直接共价连接的二价亚甲基。

    Methods of ring opening polymerization and catalysts therefor
    7.
    发明授权
    Methods of ring opening polymerization and catalysts therefor 有权
    开环聚合方法及其催化剂

    公开(公告)号：US08846851B2

    公开(公告)日：2014-09-30

    申请号：US13771552

    申请日：2013-02-20

    申请人： International Business Machines Corporation

    发明人： Daniel J. Coady ,  Kazuki Fukushima ,  James L. Hedrick ,  Hans W. Horn ,  Julia E. Rice

    IPC分类号： C08G63/00 ,  C08G64/38 ,  C08G63/82 ,  C08G75/28

    CPC分类号： C08G63/823 ,  C08G64/38 ,  C08G75/28

    摘要： A salt catalyst comprises an ionic complex of i) a nitrogen base comprising one or more guanidine and/or amidine functional groups, and ii) an oxoacid comprising one or more active acid groups, the active acid groups independently comprising a carbonyl group (C═O), sulfoxide group (S═O), and/or a phosphonyl group (P═O) bonded to one or more active hydroxy groups; wherein a ratio of moles of the active hydroxy groups to moles of the guanidine and/or amidine functional groups is greater than 0 and less than 2.0. The salt catalysts are capable of catalyzing ring opening polymerization of cyclic carbonyl compounds.

    摘要翻译： 盐催化剂包含i）包含一个或多个胍和/或脒官能团的氮碱的离子络合物，和ii）包含一个或多个活性酸基团的含氧酸，所述活性酸基团独立地包含羰基（C = O），亚砜基（S = O）和/或与一个或多个活性羟基键合的膦酰基（P = O）; 其中所述活性羟基的摩尔数与所述胍和/或脒官能团的摩尔数之比大于0且小于2.0。 盐催化剂能够催化环羰基化合物的开环聚合。

    METHODS OF RING OPENING POLYMERIZATION AND CATALYSTS THEREFOR
    8.
    发明申请
    METHODS OF RING OPENING POLYMERIZATION AND CATALYSTS THEREFOR 有权
    环形聚合方法及其催化剂

    公开(公告)号：US20130158226A1

    公开(公告)日：2013-06-20

    申请号：US13771552

    申请日：2013-02-20

    申请人： International Business Machines Corporation

    发明人： Daniel J. Coady ,  Kazuki Fukushima ,  James L. Hedrick ,  Hans W. Horn ,  Julia E. Rice

    IPC分类号： C08G63/82

    CPC分类号： C08G63/823 ,  C08G64/38 ,  C08G75/28

    摘要： A salt catalyst comprises an ionic complex of i) a nitrogen base comprising one or more guanidine and/or amidine functional groups, and ii) an oxoacid comprising one or more active acid groups, the active acid groups independently comprising a carbonyl group (C═O), sulfoxide group (S═O), and/or a phosphonyl group (P═O) bonded to one or more active hydroxy groups; wherein a ratio of moles of the active hydroxy groups to moles of the guanidine and/or amidine functional groups is greater than 0 and less than 2.0. The salt catalysts are capable of catalyzing ring opening polymerization of cyclic carbonyl compounds.

    摘要翻译： 盐催化剂包括i）包含一个或多个胍和/或脒官能团的氮碱的离子络合物，和ii）包含一个或多个活性酸基团的含氧酸，所述活性酸基团独立地包含羰基（C = O），亚砜基（S = O）和/或与一个或多个活性羟基键合的膦酰基（P = O）; 其中所述活性羟基的摩尔数与所述胍和/或脒官能团的摩尔数之比大于0且小于2.0。 盐催化剂能够催化环羰基化合物的开环聚合。