ESTERIFICATION UNIT FOR PRODUCING CRUDE METHYL METHACRYLATE, ESTERIFICATION PROCESS USING SAID UNIT AND PLANT COMPRISING SAID UNIT
    1.
    发明申请
    ESTERIFICATION UNIT FOR PRODUCING CRUDE METHYL METHACRYLATE, ESTERIFICATION PROCESS USING SAID UNIT AND PLANT COMPRISING SAID UNIT 审中-公开
    用于生产甲基丙烯酸甲酯的制备单元,使用上述单元和包含所述单元的设备的确定过程

    公开(公告)号:US20160257639A1

    公开(公告)日:2016-09-08

    申请号:US15028745

    申请日:2014-10-17

    申请人: ARKEMA FRANCE

    IPC分类号: C07C67/20 B01J10/00

    摘要: The invention relates to an esterification unit (150) and esterification process for producing crude methyl methacrylate (MMA) from methacrylamide (MAM), which enable particularly to improve the yield, meaning that the organics spent acids are low; and at the same time, providing crude MMA with rather good quality, meaning that MMA concentration in crude MMA is rather high and preferably from 50 wt % to 80 wt %. According to the invention, the esterification unit comprises esterification reactors (1, . . . , 5 (or 6) set up in a serial way so that there is a counter current flow between gaseous phase and liquid phase, the liquid phase flowing from first reactor (1) of the series to last reactor (5 (or 6)), and the gaseous phase flowing from reactor to first reactor (1).

    摘要翻译: 本发明涉及由甲基丙烯酰胺(MAM)制备粗甲基丙烯酸甲酯(MMA)的酯化单元(150)和酯化方法,其特别能够提高产率,意味着有机废酸为低; 同时提供质量较好的粗MMA,这意味着粗MMA中的MMA浓度相当高,优选为50wt%至80wt%。 根据本发明,酯化单元包括以串联方式设置的酯化反应器(1,...,5(或6)),使得在气相和液相之间存在逆流,液相从第一 (5(或6))和从反应器流向第一反应器(1)的气相的反应器(1)。

    INSTALLATION AND PROCESS FOR THE PREPARATION OF HYDROGEN CYANIDE
    3.
    发明申请
    INSTALLATION AND PROCESS FOR THE PREPARATION OF HYDROGEN CYANIDE 有权
    氢化氰化物的制备安装和工艺

    公开(公告)号:US20160194212A1

    公开(公告)日:2016-07-07

    申请号:US14905435

    申请日:2014-07-18

    申请人: ARKEMA FRANCE

    摘要: Present invention relates to a process and an installation (100) for the preparation of hydrogen cyanide by the Andrussow process, and more precisely for improving the conditions of mixing the reactant gases before feeding the Andrussow type reactor (60), in order to improve safety, to avoid any risk of explosion and to produce HCN in safe and efficient manner. The installation is configured in such a manner that oxygen is pre-mixed with air with a ratio comprised between 20.95% and 32.5% by volume, preferably between 25% and 30.5% by volume; methane containing gas and ammonia are simultaneously added in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80° C. and 120° C., preferably between 95° C. and 115° C. for feeding the Andrussow type reactor (60).

    摘要翻译: 本发明涉及一种用于通过Andrussow方法制备氰化氢的方法和装置(100),更准确地说,涉及在提供安德鲁梭型反应器(60)之前改进混合反应气体的条件,以提高安全性 ,以避免任何爆炸的危险,并以安全有效的方式生产HCN。 该装置以这样一种方式配置,使氧与空气预混合,其比例为20.95至32.5%(体积),优选为25%至30.5%(体积); 含甲烷的气体和氨同时加入到富氧空气的预混合物中,使得甲烷与氨的体积比在1.35和1.02之间,这取决于氧气进入空气的含量; 所述获得的反应气体混合物的温度为80℃至120℃,优选为95℃至115℃,用于供给安德鲁苏型反应器(60)。

    UNIT AND PROCESS FOR PURIFICATION OF CRUDE METHYL METHACRYLATE
    4.
    发明申请
    UNIT AND PROCESS FOR PURIFICATION OF CRUDE METHYL METHACRYLATE 审中-公开
    用于纯化甲基丙烯酸甲酯的单元和方法

    公开(公告)号:US20160251297A1

    公开(公告)日:2016-09-01

    申请号:US15029300

    申请日:2014-10-17

    申请人: ARKEMA FRANCE

    摘要: The invention relates to a purification unit (200) which is able to separate crude MMA from light and heavy impurities in order to obtain high quality of MMA, suitable to produce optimal grade polymethylmethacrylate (PMMA). The unit (200) comprises two distillation columns (210, 250) in series, fed with mixture to be distilled in their median part, in order to separate each column in two upper (213, 253) and lower (212, 252) parts, the first distillation column (210) being fed with crude prewashed MMA, and the second distillation column (250) being fed with distilled liquid stream containing MMA, separated from light impurities, issued from bottom of first distillation column (210). The upper part (213) of first distillation column (210) is connected to a lateral extraction system (220), able to minimize MMA content in light impurities flowing upward said first column (210).

    摘要翻译: 本发明涉及一种净化单元(200),其能够将粗MMA与轻重杂质分离,以获得高品质的MMA,适合于生产最佳级别的聚甲基丙烯酸甲酯(PMMA)。 单元(200)包括串联的两个蒸馏塔(210,250),在其中间部分中加入要蒸馏的混合物,以便将两个上部(213,253)和下部(212,252)部分分离 ,第一蒸馏塔(210)被供给粗制的预洗的MMA,并且第二蒸馏塔(250)从第一蒸馏塔(210)的底部发出的含有从轻质杂质分离的含有MMA的蒸馏液流。 第一蒸馏塔(210)的上部(213)连接到横向提取系统(220),能够最小化在第一塔(210)上向上流动的杂质中的MMA含量。

    REACTOR FOR PREPARING HYDROGEN CYANIDE BY THE ANDRUSSOW PROCESS, EQUIPMENT COMPRISING SAID REACTOR AND PROCESS USING SUCH AN EQUIPMENT
    5.
    发明申请
    REACTOR FOR PREPARING HYDROGEN CYANIDE BY THE ANDRUSSOW PROCESS, EQUIPMENT COMPRISING SAID REACTOR AND PROCESS USING SUCH AN EQUIPMENT 审中-公开
    通过安德鲁斯过程制备氢氰化物的反应器,包含该反应器的设备和使用这种设备的方法

    公开(公告)号:US20160152484A1

    公开(公告)日:2016-06-02

    申请号:US14905462

    申请日:2014-07-18

    申请人: ARKEMA FRANCE

    IPC分类号: C01C3/02 B01J8/02

    摘要: The present invention relates to a reactor (201) for preparing hydrogen cyanide by the Andrussow process, to an equipment (200) comprising said reactor and to a process for preparing hydrogen cyanide by the Andrussow process. The reactor (201) comprising at least one gas inlet (I) for reactant gases mixture, a catalyst (203), a porous support for the catalyst (204), a porous sub support (205, 206) and at least one outlet (P8) for the reaction products. According to the invention, said reactor has a cone frustum shaped metallic casing (210) and comprises inside the metallic casing, a gas distributor (202) located between the gas inlet and the catalyst, said distributor comprising at least one cone frustum element (D1, . . . Dn) having an upper base directed towards the gas inlet (I).

    摘要翻译: 本发明涉及一种用于通过Andrussow方法制备氰化氢的反应器(201),其包括所述反应器的设备(200)和通过Andrussow方法制备氰化氢的方法。 反应器(201)包括用于反应气体混合物的至少一个气体入口(I),催化剂(203),用于催化剂(204)的多孔载体,多孔子载体(205,206)和至少一个出口 P8)作为反应产物。 根据本发明,所述反应器具有圆锥截头锥形的金属外壳(210),并且在金属外壳内部包括位于气体入口和催化剂之间的气体分配器(202),所述分配器包括至少一个锥形截头锥体元件(D1 ,... Dn),其具有朝向气体入口(I)的上部基座。