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    FLUOROPOLYMER BLEND
    3.
    发明申请
    FLUOROPOLYMER BLEND 审中-公开
    荧光增白剂混合

    公开(公告)号：US20160200907A1

    公开(公告)日：2016-07-14

    申请号：US14914364

    申请日：2014-08-28

    Applicant: ARKEMA INC.

    Inventor： Ramin AMIN-SANAYEI ,  Gregory S. O'BRIEN ,  Saeid ZERAFATI

    IPC: C08L27/16 ,  B29C47/00 ,  C08J5/18

    CPC classification number: C08L27/16 ,  B29C48/04 ,  B29K2027/12 ,  B29L2031/00 ,  C08J5/18 ,  C08J2327/16 ,  C08L2203/12 ,  C08L2203/16 ,  C08L2203/18 ,  C08L2203/30 ,  C08L2205/02 ,  C08L2205/025

    Abstract: The present invention relates to the preparation of a thermoplastic fluoropolymer blend composition exhibiting improved mechanical properties upon fabrication. The fluoropolymer blend composite on is produced by blending an emulsion latex of fluoropolymer (A) with an emulsion latex of fluorinated copolymer (B). Copolymer (B) emulsion has a small particle size, super high MW, and a low degree of crystallinity. The blending of the latex emulsions results in a morphology with small particles of copolymer (B) uniformly distributed within a matrix of fluoropolymer (A) in a manner that could not be achieved by a mere melt blending of the tow components.

    Abstract translation: 本发明涉及在制造时显示改善的机械性能的热塑性含氟聚合物共混物组合物的制备。 通过将含氟聚合物（A）的乳液胶乳与含氟共聚物（B）的乳液胶乳混合，制备含氟聚合物共混物复合物。 共聚物（B）乳液具有小的粒度，超高的MW和低的结晶度。 乳胶乳液的混合导致形态，其中共聚物（B）的小颗粒均匀地分布在含氟聚合物（A）的基质内，其方式不能仅通过熔融共混丝束组分来实现。

    FLUORO-THERMOPLASTIC ELASTOMER BLENDS
    4.
    发明申请
    FLUORO-THERMOPLASTIC ELASTOMER BLENDS 有权

    公开(公告)号：US20220025166A1

    公开(公告)日：2022-01-27

    申请号：US17299802

    申请日：2019-12-05

    Applicant: Arkema Inc.

    Inventor： Adam W. HAUSER ,  Mathieu Y. CAPELOT ,  Florence MEHLMANN ,  Gregory S. O'BRIEN

    IPC: C08L27/16

    Abstract: Disclosed is a thermoplastic elastomer composition comprising a blend of at least two fluoropolymers. The first fluoropolymer has from 0 to 30 weight percent of a monomer J selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof. The second fluoropolymer has at least 30 weight percent, preferably at least 35 weight percent, of monomer T selected from the group consisting of hexafluoropropene (HFP), fluorinated or perfluorinated vinyl ethers, 2,3,3,3-tetrafluoropropene, trifluoropropene, 1-chloro-3,3,3-trifluoro propene or combinations thereof.

    3-D PRINTED FLUOROPOLYMER STRUCTURES
    6.
    发明申请
    3-D PRINTED FLUOROPOLYMER STRUCTURES 审中-公开

    公开(公告)号：US20190127500A1

    公开(公告)日：2019-05-02

    申请号：US15635525

    申请日：2017-03-31

    Applicant: Arkema Inc.

    Inventor： David Shin-Ren LIU ,  Gregory S. O'BRIEN ,  David A. SEILER

    IPC: C08F14/22 ,  B33Y70/00 ,  B33Y80/00 ,  B33Y10/00 ,  B29C64/118 ,  C08L27/16 ,  C08K3/013

    Abstract: The invention relates to fluoropolymer filament for use in 3-D printing, and 3-D printed fluoropolymer articles having low warpage, excellent chemical resistance, excellent water resistance, flame resistance, and good mechanical integrity. Additionally, the articles of the invention have good shelf life without the need for special packaging. In particular, the invention relates to filament, 3-D printed polyvinylidene fluoride (PVDF) articles, and in particular material extrusion 3-D printing. The articles may be formed from PVDF homopolymers, copolymers, such as KYNAR® resins from Arkema, as well as polymer blends with appropriately defined low shear melt viscosity. The PVDF may optionally be a filled PVDF formulation. The physical properties of the 3-D printed articles can be maximized and warpage minimized by optimizing processing parameters.

    HIGH IMPACT BLENDS OF VINYLIDENE FLUORIDE-CONTAINING POLYMERS
    7.
    发明申请
    HIGH IMPACT BLENDS OF VINYLIDENE FLUORIDE-CONTAINING POLYMERS 审中-公开

    公开(公告)号：US20180044515A1

    公开(公告)日：2018-02-15

    申请号：US15557147

    申请日：2016-03-10

    Applicant: Arkema Inc.

    Inventor： Saeid ZERAFATI ,  Ramin AMIN-SANAYEI ,  James J. HENRY ,  Gregory S. O'BRIEN

    IPC: C08L27/16

    Abstract: The invention relates to blends containing polymers of vinylidene fluoride, having low ductile-brittle transition temperatures and having excellent low temperature impact properties while maintaining the positive aspects of unmodified vinylidene fluoride-containing polymers. The blends of this invention are produced by adding a core-shell impact modifier (CSIM) comprised of a polysiloxane core and a shell compatible with vinylidene fluoride-containing polymer. The blends are further characterized by the presence of a heterogeneous copolymer composition comprised of two or more distinct phases and/or at least one flame and smoke suppressant. The preparation of these new blends can be done by conventional thermoplastic compounding techniques such as twin screw compounding; alternatively, the CSIM can be introduced earlier, such as in the latex. The unique properties of the new blends make them useful in end-use applications where those properties provide performance advantages, such as in wires & cables and in oil and gas applications.

    3-D PRINTED FLUOROPOLYMER STRUCTURES
    8.
    发明申请
    3-D PRINTED FLUOROPOLYMER STRUCTURES 审中-公开

    公开(公告)号：US20200247923A1

    公开(公告)日：2020-08-06

    申请号：US16856254

    申请日：2020-04-23

    Applicant: Arkema Inc.

    Inventor： DAVID SHIN-REN LIU ,  Gregory S. O'BRIEN ,  David A. SEILER

    IPC: C08F14/22 ,  C08L27/16 ,  C08K3/30 ,  C08K3/26 ,  B33Y80/00 ,  B33Y70/00 ,  B33Y10/00 ,  B29C64/118 ,  B29C64/112

    Abstract: A lubricant composition includes a base oil present in an amount of greater than 70 parts by weight per 100 parts by weight of the lubricant composition and an antioxidant. The antioxidant has the structure: wherein each X is independently C-A or N, so long as at least one X is N but no more than two of X are N. Moreover, A is H, cyano or an electron donating group that: (1) has an atom having at least one lone pair of electrons that is bonded directly to the aromatic ring; or (2) is an aryl group or alkyl group. Further, each R is independently H, an alkyl group, or aryl group and each R′ is independently an alkyl group or an aryl group.

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