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公开(公告)号:US10293370B2
公开(公告)日:2019-05-21
申请号:US13501304
申请日:2010-10-22
申请人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
摘要: A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating. An apparatus for the process is also described, and includes a web line, a coating section, a partial polymerization section, and a solvent removal section.
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公开(公告)号:US20120201977A1
公开(公告)日:2012-08-09
申请号:US13501304
申请日:2010-10-22
申请人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
CPC分类号: B05D3/101 , B05D3/0209 , B05D3/0254 , B05D3/067 , B05D3/10 , B05D3/107 , B05D5/00 , B05D7/04 , B82Y20/00 , G02B2207/101 , G02B2207/107
摘要: A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating. An apparatus for the process is also described, and includes a web line, a coating section, a partial polymerization section, and a solvent removal section.
摘要翻译: 描述了用于生产梯度纳米组分制品,梯度纳米复合涂层和梯度低折射率涂层的方法和设备。 该方法包括在溶剂中提供可聚合材料的第一溶液,以及在涂层的第一区域附近提供第一环境以及邻近涂层的相邻区域的不同的第二环境。 该方法还包括至少部分聚合可聚合材料以形成包含不溶性聚合物基质和第二溶液的组合物。 不溶性聚合物基质包括填充有第二溶液的多个纳米泡,并且除去来自第二溶液的大部分溶剂。 靠近涂层的第一区域的多个纳米空心的第一体积分数小于邻近涂层的多个纳米空间的第二体积分数。 还描述了一种用于该方法的装置,并且包括幅材线,涂布部分,部分聚合部分和溶剂去除部分。
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公开(公告)号:US09279918B2
公开(公告)日:2016-03-08
申请号:US13501295
申请日:2010-10-22
申请人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
IPC分类号: G02B5/02
CPC分类号: G02B5/0242 , G02B5/0231 , G02B5/0247 , G02B5/0263 , G02B5/0278 , G02B2207/107 , Y10T428/249961
摘要: A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.
摘要翻译: 描述了包括梯度光学膜的梯度光学膜和光学结构。 梯度光学膜包括粘合剂,多个颗粒和具有局部体积分数的多个互连的空隙。 多个相互连接的空隙的局部体积分数沿梯度光学膜的厚度方向变化。 梯度光学膜的折射率也可以沿着梯度光学膜的厚度方向变化,因为折射率也可以取决于多个互连空隙的局部体积分数。
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公开(公告)号:US20120200931A1
公开(公告)日:2012-08-09
申请号:US13501295
申请日:2010-10-22
申请人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
发明人: Adam D. Haag , William F. Edmonds , Jason S. Petaja , Eric W. Nelson , William Blake Kolb , Encai Hao , Fei Lu , Michael Benton Free
CPC分类号: G02B5/0242 , G02B5/0231 , G02B5/0247 , G02B5/0263 , G02B5/0278 , G02B2207/107 , Y10T428/249961
摘要: A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.
摘要翻译: 描述了包括梯度光学膜的梯度光学膜和光学结构。 梯度光学膜包括粘合剂,多个颗粒和具有局部体积分数的多个互连的空隙。 多个相互连接的空隙的局部体积分数沿梯度光学膜的厚度方向变化。 梯度光学膜的折射率也可以沿着梯度光学膜的厚度方向变化,因为折射率也可以取决于多个互连空隙的局部体积分数。
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公开(公告)号:US20120200919A1
公开(公告)日:2012-08-09
申请号:US13501310
申请日:2010-10-22
申请人: Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
发明人: Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
CPC分类号: G02B5/0247 , G02B5/0242 , Y10T428/249986
摘要: A voided diffuser and an optical construction incorporating the voided diffuser are provided. The voided diffuser includes a plurality of beads and a binder composition in contact with the plurality of beads. The binder composition includes a binder and a plurality of interconnected voids. The optical construction includes the voided diffuser disposed on a substrate.
摘要翻译: 提供了一种排空的扩散器和结合有空隙扩散器的光学结构。 空隙扩散器包括多个珠粒和与多个珠粒接触的粘合剂组合物。 粘合剂组合物包括粘合剂和多个相互连接的空隙。 光学结构包括设置在基板上的空隙扩散器。
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公开(公告)号:US08982468B2
公开(公告)日:2015-03-17
申请号:US13501310
申请日:2010-10-22
申请人: Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
发明人: Jason S. Petaja , William F. Edmonds , Adam D. Haag , Eric W. Nelson , Encai Hao , William Blake Kolb , Fei Lu , Richard J. Pokorny
IPC分类号: G02B5/02
CPC分类号: G02B5/0247 , G02B5/0242 , Y10T428/249986
摘要: A voided diffuser and an optical construction incorporating the voided diffuser are provided. The voided diffuser includes a plurality of beads and a binder composition in contact with the plurality of beads. The binder composition includes a binder and a plurality of interconnected voids. The optical construction includes the voided diffuser disposed on a substrate.
摘要翻译: 提供了一种排空的扩散器和结合有空隙扩散器的光学结构。 空隙扩散器包括多个珠粒和与多个珠粒接触的粘合剂组合物。 粘合剂组合物包括粘合剂和多个相互连接的空隙。 光学结构包括设置在基板上的空隙扩散器。
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公开(公告)号:US09791603B2
公开(公告)日:2017-10-17
申请号:US14005912
申请日:2012-03-26
IPC分类号: G02B27/10 , G02B27/12 , B64D47/06 , G02F1/1335 , G02B5/04 , C09J133/08 , C09J7/02 , C09J151/06
CPC分类号: G02B5/045 , C08L2205/04 , C09J7/38 , C09J133/08 , C09J151/06
摘要: Presently described are optical stacks comprising a first optical film comprising a plurality of structures comprising an optically active portion designed primarily to provide optical gain and optionally an optically in-active bonding portion disposed on a first surface bonded to a second optical film with a light-transmissive adhesive layer such that a portion of the structures penetrate the adhesive layer and a separation is provided between the adhesive layer and the first surface. In one embodiment, the optical stacks exhibit a combination of high peel strength and high retained brightness, particularly after aging. The adhesive layer preferably comprises an interpenetrating network of the reaction product of a polyacrylate component and a polymerizable monomer and the adhesive layer has an elastic modulus ranging from 100 to 2000 MPa at 25° C.
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公开(公告)号:US20140016208A1
公开(公告)日:2014-01-16
申请号:US14005912
申请日:2012-03-26
IPC分类号: G02B5/04
CPC分类号: G02B5/045 , C08L2205/04 , C09J7/38 , C09J133/08 , C09J151/06
摘要: Presently described are optical stacks comprising a first optical film comprising a plurality of structures comprising an optically active portion designed primarily to provide optical gain and optionally an optically in-active bonding portion disposed on a first surface bonded to a second optical film with a light-transmissive adhesive layer such that a portion of the structures penetrate the adhesive layer and a separation is provided between the adhesive layer and the first surface. In one embodiment, the optical stacks exhibit a combination of high peel strength and high retained brightness, particularly after aging. The adhesive layer preferably comprises an interpenetrating network of the reaction product of a polyacrylate component and a polymerizable monomer and the adhesive layer has an elastic modulus ranging from 100 to 2000 MPa at 25° C.
摘要翻译: 目前描述的是包括第一光学膜的光学堆叠,该第一光学膜包括多个结构,该多个结构包括主要用于提供光学增益的光学活性部分和可选地设置在与第二光学膜结合的第一表面上的光学活性粘合部分, 透明粘合剂层,使得一部分结构穿透粘合剂层,并且在粘合剂层和第一表面之间提供分离。 在一个实施例中,光学堆叠表现出高剥离强度和高保留亮度的组合,特别是在老化之后。 粘合剂层优选包括聚丙烯酸酯组分和可聚合单体的反应产物的互穿网络,并且粘合剂层在25℃下具有100至2000MPa的弹性模量。
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公开(公告)号:US20120225301A1
公开(公告)日:2012-09-06
申请号:US13392700
申请日:2010-08-27
申请人: Bryan V. Hunt , Brandt K. Carter , Maureen C. Nelson , Thomas P. Klun , Jason S. Petaja , Yizhong Wang , Joel D. Oxman
发明人: Bryan V. Hunt , Brandt K. Carter , Maureen C. Nelson , Thomas P. Klun , Jason S. Petaja , Yizhong Wang , Joel D. Oxman
CPC分类号: C09K3/16 , C08F220/34 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663 , C08F220/22 , C08F222/1006 , C08F230/08
摘要: Optical devices comprising at least one optical layer and at least one antistatic layer disposed on at least one surface of the optical layer wherein the antistatic layer comprises the reaction product of: (a) at least one polymerizable onium salt; and (b) at least one polymerizable, non-onium, silicone or perfluoropolyether moiety-containing monomer, oligomer, or polymer.
摘要翻译: 光学器件包括至少一个光学层和至少一个设置在光学层的至少一个表面上的抗静电层,其中抗静电层包含以下物质的反应产物:(a)至少一种可聚合的鎓盐; 和(b)至少一种可聚合,非鎓,硅氧烷或全氟聚醚部分的单体,低聚物或聚合物。
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