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公开(公告)号：US06632956B2
公开(公告)日：2003-10-14
申请号：US10218558
申请日：2002-08-15
申请人： Akihito Tsukuno , Hiroyuki Kobayashi , Yukinori Satoh , Hideaki Ozeki , Yoshihiro Shirota , Susumu Ueno
发明人： Akihito Tsukuno , Hiroyuki Kobayashi , Yukinori Satoh , Hideaki Ozeki , Yoshihiro Shirota , Susumu Ueno
IPC分类号： C07F704
CPC分类号： C07F7/125
摘要： A diorganodichlorosilane is prepared by subjecting organochlorosilanes to disproportionation reaction in the co-presence of a SiH group-containing compound and in the presence of a primary catalyst of AlCl3 or AlBr3 and a co-catalyst of Mg, Al, Ca, Ti, Fe, Ni, Cu, Zn or Sn or a compound thereof. The invention enables disproportionation reaction of organochlorosilanes under atmospheric pressure and at a low temperature at which no substantial sublimation of AlCl3 or the like occurs, thus allowing the reaction equipment to be simple and improving the safety of reaction.
摘要翻译： 二有机二氯硅烷通过使有机氯硅烷在含SiH基的化合物的共存下和在AlCl 3的初级催化剂存在下进行歧化反应来制备，或者是AlBr
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公开(公告)号：US06225490B1
公开(公告)日：2001-05-01
申请号：US09084786
申请日：1998-05-27
申请人： Hiroshi Nakayama , Naoyuki Ida , Hiroyuki Kobayashi , Yukinori Satoh , Yoshihiro Shirota , Masaaki Furuya
发明人： Hiroshi Nakayama , Naoyuki Ida , Hiroyuki Kobayashi , Yukinori Satoh , Yoshihiro Shirota , Masaaki Furuya
IPC分类号： C07F704
CPC分类号： C08G77/06
摘要： For the continuous hydrolysis of organochlorosilane, a reaction system comprising at least three stages of hydrolysis is used. Each stage includes a reactor and a phase separator wherein hydrolysis is effected to form a hydrolysis mixture which is separated into a hydrolyzate and a hydrogen chloride-containing aqueous medium. The separated aqueous medium is circulated to the reactor. The hydrolyzate is conveyed to the reactor of the subsequent stage. The organochlorosilane is fed into the first stage reactor, the aqueous medium containing an amount of water corresponding to the consumption in one stage is fed into one stage reactor from the subsequent stage, and an amount of water corresponding to the consumption in the overall reaction system is fed in the last stage. Then the entire amount of hydrogen chloride generated in multiple stages of hydrolysis is recovered as anhydrous hydrogen chloride from the first stage. The entire amount of the aqueous media separated in the phase separators is retained in the reaction system.
摘要翻译： 对于有机氯硅烷的连续水解，使用包含至少三个水解阶段的反应体系。 每个阶段包括反应器和相分离器，其中进行水解以形成分离成水解产物和含氯化氢的水性介质的水解混合物。 将分离的水性介质循环至反应器。 水解产物被输送到后续阶段的反应器。 将有机氯硅烷进料到第一阶段反应器中，将含有相当于一步消耗量的水的含水介质从后续阶段进料到一级反应器中，并且一定量的水对应于整个反应体系中的消耗 在最后阶段喂养。 然后从第一阶段以多级水解产生的全部量的氯化氢作为无水氯化氢回收。 在相分离器中分离的水性介质的全部量保留在反应体系中。
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公开(公告)号：US5917099A
公开(公告)日：1999-06-29
申请号：US78714
申请日：1998-05-14
CPC分类号： C07C17/16 , Y02P20/582
摘要： Methyl chloride is prepared by effecting liquid-phase reaction between hydrogen chloride and methanol in the absence of a catalyst. The reaction is effected in divided stages including at least an early stage and a last stage. The early stage of reaction is effected in a stoichiometric excess of hydrogen chloride. The last stage of reaction is effected in a stoichiometric excess of methanol. The invention is industrially advantageous in that methyl chloride can be prepared at a high conversion of hydrogen chloride while suppressing the formation of dimethyl ether by-product.
摘要翻译： 在不存在催化剂的情况下通过在氯化氢和甲醇之间进行液相反应制备甲基氯。 反应分为两个阶段进行，包括至少早期阶段和最后阶段。 反应的早期阶段是在化学计量过量的氯化氢中进行。 反应的最后阶段在化学计量过量的甲醇中进行。 本发明在工业上是有利的，因为氯甲烷的高转化率可以制备甲基氯，同时抑制二甲醚副产物的形成。
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4.发明授权Method for preparing monosilanes from a high-boiling fraction formed as by-products in the direct synthesis of methylchlorosilanes 失效在直接合成甲基氯硅烷中作为副产物形成的高沸点馏分制备单硅烷的方法
公开(公告)号：US5922893A
公开(公告)日：1999-07-13
申请号：US31545
申请日：1998-02-27
申请人： Akihito Tsukuno , Yukinori Satoh , Masao Maruyama , Kesaji Harada , Shoichi Tanaka , Masaaki Furuya
发明人： Akihito Tsukuno , Yukinori Satoh , Masao Maruyama , Kesaji Harada , Shoichi Tanaka , Masaaki Furuya
CPC分类号： C07F7/128
摘要： The direct synthesis of methylchlorosilanes to react metallic silicon with methyl chloride in the presence of a copper catalyst yields a high-boiling fraction of methylchlorodisilanes as by-products. The invention provides a method for preparing monosilanes from the high-boiling fraction by reacting it with hydrogen chloride in the presence of an amine or amide catalyst. The reaction is effected under the condition that the amount of iron, aluminum, zinc, tin and compounds thereof present in the reaction system is less than the equimolar amount with respect to the catalyst. This increases the conversion of disilanes into monosilanes.
摘要翻译： 甲基氯硅烷在铜催化剂存在下直接合成甲基氯与甲基氯反应产生高沸点馏分的甲基氯二硅烷作为副产物。 本发明提供了通过在胺或酰胺催化剂的存在下与氯化氢反应从高沸点馏分制备单硅烷的方法。 反应在反应体系中存在的铁，铝，锌，锡及其化合物的量相对于催化剂小于等摩尔量的条件下进行。 这增加了二硅烷转化为单硅烷的转化率。
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公开(公告)号：US5961695A
公开(公告)日：1999-10-05
申请号：US47385
申请日：1998-03-25
申请人： Masayuki Hasegawa , Kazuo Ogiwara , Hiroyuki Kobayashi , Yukinori Satoh , Yoshihiro Shirata , Masaaki Furuya
发明人： Masayuki Hasegawa , Kazuo Ogiwara , Hiroyuki Kobayashi , Yukinori Satoh , Yoshihiro Shirata , Masaaki Furuya
摘要： A silane-containing gas is treated by contacting it with a liquid containing silanes or disilanes which are higher boiling than the silanes in the silane-containing gas, thereby easily removing or reducing the amount of silanes in the gas and enabling the recovery of these silanes.
摘要翻译： 通过使含硅烷的气体与含有硅烷的气体中的硅烷沸点比沸点高的硅烷或二硅烷的液体接触来处理，从而容易地除去或减少气体中的硅烷的量并能够回收这些硅烷 。
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公开(公告)号：US5712405A
公开(公告)日：1998-01-27
申请号：US781207
申请日：1997-01-10
CPC分类号： C07F7/16
摘要： An (alkylhalo)silane is prepared by using a fluidized bed reactor equipped with a feed line for reactant gas and a delivery line for product gas, charging the reactor with a contact mass comprising metallic silicon powder and a copper catalyst, and feeding a reactant gas containing an alkyl halide through the feed line into the reactor whereby the silane is formed by direct synthesis. A dust collector is connected to the delivery line for collecting the contact mass carried over with the product gas, which is fed back to the reactor. The feed of the reactant gas is controlled such that a linear velocity multiplied by a density may range from 0.2-2 kg/m.sup.2 .multidot.sec.
摘要翻译： 通过使用配备有反应气体的进料管线和产物气体的输送管线的流化床反应器制备（烷基卤代）硅烷，用包括金属硅粉末和铜催化剂的接触物料装入反应器，并将反应气体 含有通过进料管线的烷基卤化物进入反应器，由此通过直接合成形成硅烷。 集尘器连接到输送管线，用于收集被反馈到反应器的产物气体携带的接触物质。 控制反应气体的进料使得乘以密度的线速度可以在0.2-2kg / m2×sec的范围内。
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7.发明授权Preparation of contract mass for alkylhalosilane production and process for producing alkylhalosilanes 失效制备烷基卤硅烷生产的合同质量和制备烷基卤代硅烷的方法
公开(公告)号：US6090966A
公开(公告)日：2000-07-18
申请号：US76153
申请日：1998-05-12
摘要： Alkylhalosilanes are produced by first fluidizing a metallic silicon powder with an inert gas, preheating the silicon powder at a temperature between 200.degree. C. and a steady reaction temperature while keeping the silicon powder fluidized, adding a copper catalyst to the preheated silicon powder to form a contact mass, and feeding an alkyl halide into the contact mass whereby the alkylhalosilanes are formed by direct synthesis. This process prevents the copper catalyst from being sintered by thermal hysteresis and activates a high catalysis on the contact mass at the start of reaction. The desired dialkyldihalosilane can be produced at a high selectivity.
摘要翻译： 烷基卤代硅烷首先用惰性气体流化金属硅粉末，在保持硅粉末流动的同时在200℃和稳定的反应温度之间预热硅粉末，向预热的硅粉末中加入铜催化剂以形成 接触物质，并将烷基卤化物进料到接触物质中，由此通过直接合成形成烷基卤代硅烷。 该过程防止铜催化剂通过热滞后烧结，并且在反应开始时对接触质量起到高催化作用。 所需的二烷基二卤硅烷可以高选择性制备。
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公开(公告)号：US6025513A
公开(公告)日：2000-02-15
申请号：US106145
申请日：1998-06-29
IPC分类号： C07F7/16
CPC分类号： C07F7/16
摘要： An alkylhalosilane is prepared by charging a reactor with a contact mass comprising a metallic silicon powder and a copper catalyst, and feeding an alkyl halide into the reactor whereby the silane is formed by direct synthesis. The contact mass contains 1-10,000 ppm of elemental boron. The addition of boron to the contact mass is effective for increasing the throughput of dialkyldihalosilane at desired STY in an inexpensive manner while suppressing formation of unnecessary hydrosilanes and disilanes.
摘要翻译： 通过向反应器中加入包含金属硅粉末和铜催化剂的接触物质，并将烷基卤化物进料到反应器中制备烷基卤硅烷，由此通过直接合成形成硅烷。 接触质量含有1-10,000 ppm的元素硼。 向接触物质中加入硼对于以便宜的方式在期望的STY下提高二烷基二卤代硅烷的通量是有效的，同时抑制不必要的氢硅烷和二硅烷的形成。
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公开(公告)号：US5986123A
公开(公告)日：1999-11-16
申请号：US053059
申请日：1998-04-01
CPC分类号： C07F7/16
摘要： An alkylhalosilane is prepared by charging a reactor with a contact mass comprising a metallic silicon powder and a copper catalyst, and feeding an alkyl halide into the reactor whereby the silane is formed by direct synthesis. The use of a metallic silicon powder having a specific particle size distribution ensures effective fluidization whereby the alkylhalosilane of quality is formed at a high selectivity and in high yields.
摘要翻译： 通过向反应器中加入包含金属硅粉末和铜催化剂的接触物质，并将烷基卤化物进料到反应器中制备烷基卤硅烷，由此通过直接合成形成硅烷。 使用具有特定粒度分布的金属硅粉末确保有效的流化，从而以高选择性和高产率形成质量的烷基卤代硅烷。
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公开(公告)号：US5847181A
公开(公告)日：1998-12-08
申请号：US812942
申请日：1997-03-04
CPC分类号： C07F7/16
摘要： An alkylhalosilane is prepared by charging a reactor with a contact mass comprising metallic silicon powder and a copper catalyst and feeding a reactant gas containing an alkyl halide into the reactor whereby the silane is formed by direct synthesis. A phosphorus compound is added to the contact mass in an amount of 3,000-10,000 ppm calculated as phosphorus. The invention produces a more amount of dialkyldihalosilane in a desirable STY while minimizing the amount of unnecessary disilanes.
摘要翻译： 通过将包含金属硅粉末和铜催化剂的接触物质装入反应器并将含有烷基卤化物的反应气体进料到反应器中制备烷基卤硅烷，由此通过直接合成形成硅烷。 按磷计算，磷化合物的量为3,000〜10000ppm。 本发明在所需的STY中产生更多量的二烷基二卤硅烷，同时使不需要的二硅烷的量最小化。
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