公开(公告)号：US06423452B1

公开(公告)日：2002-07-23

申请号：US09215459

申请日：1998-12-17

申请人： Akinori Kita ,  Naoko Inagaki ,  Atsuo Omaru ,  Akio Takahashi

发明人： Akinori Kita ,  Naoko Inagaki ,  Atsuo Omaru ,  Akio Takahashi

IPC分类号： H01M614

CPC分类号： H01M10/0567 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/4235 ,  H01M10/446 ,  Y10T29/49108

摘要： A nonaqueous electrolytic secondary battery includes a negative electrode, a positive electrode, and a nonaqueous electrolytic solution including an electrolytic salt dissolved in a nonaqueous solvent. A polymer is added to the nonaqueous electrolytic solution. Also, a method of making a nonaqueous electrolytic secondary battery includes the steps of placing a negative electrode, a positive electrode, and a nonaqueous electrolytic solution including an electrolytic salt dissolved in a nonaqueous solvent, in a battery housing to assemble a battery; and charging and discharging the battery under overcharge conditions or applying a pulse voltage to the battery.

摘要翻译： 非水电解质二次电池包括负极，正极和包含溶解在非水溶剂中的电解质盐的非水电解液。 向非水电解液中加入聚合物。 此外，制造非水电解二次电池的方法包括将负极，正极和包含溶解在非水溶剂中的电解质盐的非水电解液放置在电池壳体中以组装电池的步骤; 并在过充电条件下对电池充电和放电，或向电池施加脉冲电压。

公开(公告)号：US07037623B2

公开(公告)日：2006-05-02

申请号：US10310562

申请日：2002-12-04

申请人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

发明人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

IPC分类号： C01B31/04

CPC分类号： H01M4/623 ,  H01M2/022 ,  H01M4/0404 ,  H01M4/0433 ,  H01M4/366 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T428/30

摘要： A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.

公开(公告)号：US20050202317A1

公开(公告)日：2005-09-15

申请号：US11127461

申请日：2005-05-12

申请人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

发明人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

IPC分类号： G01N21/65 ,  C01B31/00 ,  C01B31/02 ,  C01B31/04 ,  G01N23/207 ,  H01M2/02 ,  H01M4/36 ,  H01M4/587 ,  H01M4/62 ,  H01M6/10 ,  H01M10/05 ,  H01M10/0525 ,  H01M4/58

CPC分类号： H01M4/623 ,  H01M2/022 ,  H01M4/0404 ,  H01M4/0433 ,  H01M4/366 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T428/30

摘要： A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.

摘要翻译： 非水二次电池的负极由碳质材料形成。 通过由表面增强拉曼光谱确定的碳质材料的石墨化度Gs与通过使用氩激光测得的拉曼光谱确定的石墨化度Gb的比率RG = Gs / Gb至少为4.5。 或者，碳质材料在通过相同的表面增强拉曼光谱测量的表面增强拉曼光谱中具有在1,360cm -1以上的波长范围内的峰。 在高温环境下使用时，非水系二次电池的劣化被抑制，长时间保持高容量。

公开(公告)号：US20050202318A1

公开(公告)日：2005-09-15

申请号：US11127741

申请日：2005-05-12

申请人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

发明人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

IPC分类号： G01N21/65 ,  C01B31/00 ,  C01B31/02 ,  C01B31/04 ,  G01N23/207 ,  H01M2/02 ,  H01M4/36 ,  H01M4/587 ,  H01M4/62 ,  H01M6/10 ,  H01M10/05 ,  H01M10/0525 ,  H01M4/58

CPC分类号： H01M4/623 ,  H01M2/022 ,  H01M4/0404 ,  H01M4/0433 ,  H01M4/366 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T428/30

摘要： A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by-the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.

摘要翻译： 非水二次电池的负极由碳质材料形成。 通过由表面增强拉曼光谱确定的碳质材料的石墨化度Gs与通过使用氩激光测得的拉曼光谱确定的石墨化度Gb的比率RG = Gs / Gb至少为4.5。 或者，碳质材料在通过相同的表面增强拉曼光谱测量的表面增强拉曼光谱中具有在1,360cm -1以上的波长范围内的峰。 在高温环境下使用时，非水系二次电池的劣化被抑制，长时间保持高容量。

公开(公告)号：US07658775B2

公开(公告)日：2010-02-09

申请号：US11127741

申请日：2005-05-12

申请人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

发明人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

IPC分类号： H01M6/00

CPC分类号： H01M4/623 ,  H01M2/022 ,  H01M4/0404 ,  H01M4/0433 ,  H01M4/366 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T428/30

摘要： A method for making a negative electrode component used in a nonaqueous secondary battery that includes the steps of polishing the surface of the negative electrode component by irradiating the surface with light to produce a negative electrode that includes a carbonaceous material in which the ratio RG=Gs/Gb is at least 4.5, where Gs is the degree of graphitization the carbonaceous material as determined by a surface-enhanced Raman spectrum and Gb is degree of graphitization of the carbonaceous material as determined by a Raman spectrum measured using argon laser light and both Gs and Gb are measured under set parameters.

摘要翻译： 一种制造在非水二次电池中使用的负极组分的方法，包括以下步骤：通过用光照射该表面来抛光负极组件的表面，以产生包含比例为RG = Gs的碳质材料的负极 / Gb至少为4.5，其中Gs是通过表面增强拉曼光谱确定的碳质材料的石墨化程度，并且Gb是通过使用氩激光测量的拉曼光谱和两个Gs测定的碳质材料的石墨化程度 和Gb在设定参数下测量。

公开(公告)号：US07041415B2

公开(公告)日：2006-05-09

申请号：US11127461

申请日：2005-05-12

申请人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

发明人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

IPC分类号： C01B31/04

CPC分类号： H01M4/623 ,  H01M2/022 ,  H01M4/0404 ,  H01M4/0433 ,  H01M4/366 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T428/30

摘要： A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.

摘要翻译： 非水二次电池的负极由碳质材料形成。 通过由表面增强拉曼光谱确定的碳质材料的石墨化度Gs与通过使用氩激光测得的拉曼光谱确定的石墨化度Gb的比率RG = Gs / Gb至少为4.5。 或者，碳质材料在通过相同的表面增强拉曼光谱测量的表面增强拉曼光谱中具有在1,360cm -1以上的波长范围内的峰。 在高温环境下使用时，非水系二次电池的劣化被抑制，长时间保持高容量。

公开(公告)号：US06506519B1

公开(公告)日：2003-01-14

申请号：US09514590

申请日：2000-02-28

申请人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

发明人： Kotaro Satori ,  Akinori Kita ,  Atsuo Omaru

IPC分类号： H01M458

CPC分类号： H01M4/623 ,  H01M2/022 ,  H01M4/0404 ,  H01M4/0433 ,  H01M4/366 ,  H01M4/587 ,  H01M6/10 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T428/30

摘要： A negative electrode of a nonaqueous secondary battery is formed of a carbonaceous material. The ratio RG=Gs/Gb of the degree of graphitization Gs of the carbonaceous material, determined by a surface-enhanced Raman spectrum, to the degree of graphitization Gb, determined by a Raman spectrum measured using argon laser light, is at least 4.5. Alternatively, the carbonaceous material has a peak in a wavelength range above 1,360 cm−1 in a surface-enhanced Raman spectrum which is measured by the same surface-enhanced Raman spectrum. The deterioration of the nonaqueous secondary battery is suppressed during use in high-temperature environments and high capacity is maintained for long periods.

摘要翻译： 非水二次电池的负极由碳质材料形成。 通过由表面增强拉曼光谱确定的碳质材料的石墨化度Gs与通过使用氩激光测得的拉曼光谱确定的石墨化度Gb的比率RG = Gs / Gb至少为4.5。 或者，碳质材料在通过相同的表面增强拉曼光谱测量的表面增强拉曼光谱中具有在1,360cm -1以上的波长范围内的峰。 在高温环境下使用时，非水系二次电池的劣化被抑制，长时间保持高容量。

公开(公告)号：US10069168B2

公开(公告)日：2018-09-04

申请号：US12123840

申请日：2008-05-20

申请人： Masayuki Ihara ,  Kiyohiko Suzuki ,  Akinori Kita ,  Tadahiko Kubota

发明人： Masayuki Ihara ,  Kiyohiko Suzuki ,  Akinori Kita ,  Tadahiko Kubota

IPC分类号： H01M10/0569 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M4/133 ,  H01M4/134 ,  H01M10/0587

CPC分类号： H01M10/0569 ,  H01M4/133 ,  H01M4/134 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0587 ,  H01M2300/0037

摘要： A battery capable of improving high-temperature characteristics is provided. The battery includes a cathode, an anode and an electrolytic solution. A separator provided between the cathode and the anode is impregnated with the electrolytic solution. A solvent of the electrolytic solution includes a main solvent such as a cyclic carbonate which includes halogen and a sub solvent such as carbonate dimer.

公开(公告)号：US08993166B2

公开(公告)日：2015-03-31

申请号：US12026594

申请日：2008-02-06

申请人： Satoshi Mizutani ,  Hiroshi Inoue ,  Akinori Kita ,  Akira Yamaguchi

发明人： Satoshi Mizutani ,  Hiroshi Inoue ,  Akinori Kita ,  Akira Yamaguchi

IPC分类号： H01M4/38 ,  H01M10/0569 ,  H01M4/134 ,  H01M4/36 ,  H01M4/58 ,  H01M10/0587 ,  H01M4/52 ,  H01M4/46 ,  H01M4/587 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/42 ,  H01M4/02

CPC分类号： H01M10/0569 ,  H01M4/134 ,  H01M4/364 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M4/463 ,  H01M4/52 ,  H01M4/5805 ,  H01M4/587 ,  H01M4/625 ,  H01M10/0525 ,  H01M10/0587 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2004/027 ,  Y02E60/122

摘要： A battery with the high capacity, the superior cycle characteristics, and the superior initial charge and discharge efficiency, and an anode active material used for it are provided. The anode active material contains at least tin, cobalt, carbon, and phosphorus as an element. A carbon content is from 9.9 wt % to 29.7 wt %, a phosphorus content is from 0.1 wt % to 2.2 wt %, and a cobalt ration to the total of the tin and the cobalt is from 24 wt % to 70 wt %.

摘要翻译： 提供具有高容量，优异的循环特性和优异的初始充放电效率的电池以及用于其的负极活性材料。 负极活性物质至少含有锡，钴，碳和磷作为元素。 碳含量为9.9重量％〜29.7重量％，磷含量为0.1重量％〜2.2重量％，钴和钴总量的钴比例为24重量％〜70重量％。

公开(公告)号：US07927744B2

公开(公告)日：2011-04-19

申请号：US11225540

申请日：2005-09-13

申请人： Satoshi Mizutani ,  Hiroshi Inoue ,  Akira Yamaguchi ,  Akinori Kita

发明人： Satoshi Mizutani ,  Hiroshi Inoue ,  Akira Yamaguchi ,  Akinori Kita

IPC分类号： H01M4/58

CPC分类号： H01M10/0525 ,  H01M4/362 ,  H01M4/387 ,  H01M4/587 ,  H01M10/0569

摘要： A battery with a high capacity and superior cycle characteristics and an anode active material used in the battery are provided. An anode includes an anode active material capable of reacting with lithium. The anode active material includes at least tin, cobalt and carbon as elements, and the carbon content is within a range from 9.9 wt % to 29.7 wt % inclusive, and the ratio of cobalt to the total of tin and cobalt is within a range from 30 wt % to 70 wt % inclusive. Thereby, while a high capacity is maintained, cycle characteristics can be improved.

摘要翻译： 提供了具有高容量和优异的循环特性的电池以及用于电池中的阳极活性材料。 阳极包括能够与锂反应的负极活性物质。 负极活性物质至少包含锡，钴和碳作为元素，碳含量在9.9重量％至29.7重量％的范围内，钴与钴和钴的总量的比例在 30重量％〜70重量％。 因此，在保持高容量的同时，可以提高循环特性。