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公开(公告)号:US07718311B2
公开(公告)日:2010-05-18
申请号:US11267116
申请日:2005-11-03
申请人: Akira Yamaguchi , Tadahiko Kubota , Atsumichi Kawashima , Akinori Kita , Satoshi Mizutani , Hiroshi Inoue
发明人: Akira Yamaguchi , Tadahiko Kubota , Atsumichi Kawashima , Akinori Kita , Satoshi Mizutani , Hiroshi Inoue
CPC分类号: H01M4/58 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M6/168 , H01M10/0431 , H01M10/0436 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/4235 , H01M2004/027
摘要: A battery capable of improving battery characteristics such as cycle characteristics is provided. An electrolytic solution is impregnated in a separator. The electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Fluorine ion content in the electrolytic solution is preferably from 10 weight ppm to 3200 weight ppm. Thereby, chemical stability of the electrolytic solution is improved, and cycle characteristics are improved. The present invention is effective for the case using an anode active material containing Sn or Si as an element for an anode.
摘要翻译: 提供了能够提高电池特性例如循环特性的电池。 将电解液浸渍在隔膜中。 电解液含有4-氟-1,3-二氧戊环-2-酮。 电解液中的氟离子含量优选为10重量ppm〜3200重量ppm。 由此,提高了电解液的化学稳定性,提高了循环特性。 本发明对于使用含有Sn或Si作为阳极元素的负极活性物质的情况是有效的。
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公开(公告)号:USRE44489E1
公开(公告)日:2013-09-10
申请号:US13475199
申请日:2012-05-18
申请人: Akira Yamaguchi , Tadahiko Kubota , Atsumichi Kawashima , Akinori Kita , Satoshi Mizutani , Hiroshi Inoue
发明人: Akira Yamaguchi , Tadahiko Kubota , Atsumichi Kawashima , Akinori Kita , Satoshi Mizutani , Hiroshi Inoue
CPC分类号: H01M4/58 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M6/168 , H01M10/0431 , H01M10/0436 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/4235 , H01M2004/027
摘要: A battery capable of improving battery characteristics such as cycle characteristics is provided. An electrolytic solution is impregnated in a separator. The electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Fluorine ion content in the electrolytic solution is preferably from 10 weight ppm to 3200 weight ppm. Thereby, chemical stability of the electrolytic solution is improved, and cycle characteristics are improved. The present invention is effective for the case using an anode active material containing Sn or Si as an element for an anode.
摘要翻译: 提供了能够提高电池特性例如循环特性的电池。 将电解液浸渍在隔膜中。 电解液含有4-氟-1,3-二氧戊环-2-酮。 电解液中的氟离子含量优选为10重量ppm〜3200重量ppm。 由此,提高了电解液的化学稳定性,提高了循环特性。 本发明对于使用含有Sn或Si作为阳极元素的负极活性物质的情况是有效的。
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公开(公告)号:US20060068292A1
公开(公告)日:2006-03-30
申请号:US11225540
申请日:2005-09-13
申请人: Satoshi Mizutani , Hiroshi Inoue , Akira Yamaguchi , Akinori Kita
发明人: Satoshi Mizutani , Hiroshi Inoue , Akira Yamaguchi , Akinori Kita
CPC分类号: H01M10/0525 , H01M4/362 , H01M4/387 , H01M4/587 , H01M10/0569
摘要: A battery with a high capacity and superior cycle characteristics and an anode active material used in the battery are provided. An anode includes an anode active material capable of reacting with lithium. The anode active material includes at least tin, cobalt and carbon as elements, and the carbon content is within a range from 9.9 wt % to 29.7 wt % inclusive, and the ratio of cobalt to the total of tin and cobalt is within a range from 30 wt % to 70 wt % inclusive. Thereby, while a high capacity is maintained, cycle characteristics can be improved.
摘要翻译: 提供了具有高容量和优异的循环特性的电池以及用于电池中的阳极活性材料。 阳极包括能够与锂反应的负极活性物质。 负极活性物质至少包含锡,钴和碳作为元素,碳含量在9.9重量%至29.7重量%的范围内,钴与钴和钴的总量的比例在 30重量%〜70重量%。 因此,在保持高容量的同时,可以提高循环特性。
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公开(公告)号:US20080193856A1
公开(公告)日:2008-08-14
申请号:US12026594
申请日:2008-02-06
申请人: Satoshi Mizutani , Hiroshi Inoue , Akinori Kita , Akira Yamaguchi
发明人: Satoshi Mizutani , Hiroshi Inoue , Akinori Kita , Akira Yamaguchi
CPC分类号: H01M10/0569 , H01M4/134 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/463 , H01M4/52 , H01M4/5805 , H01M4/587 , H01M4/625 , H01M10/0525 , H01M10/0587 , H01M10/4235 , H01M2004/021 , H01M2004/027 , Y02E60/122
摘要: A battery with the high capacity, the superior cycle characteristics, and the superior initial charge and discharge efficiency, and an anode active material used for it are provided. The anode active material contains at least tin, cobalt, carbon, and phosphorus as an element. A carbon content is from 9.9 wt % to 29.7 wt %, a phosphorus content is from 0.1 wt % to 2.2 wt %, and a cobalt ration to the total of the tin and the cobalt is from 24 wt % to 70 wt %.
摘要翻译: 提供具有高容量,优异的循环特性和优异的初始充放电效率的电池以及用于其的负极活性材料。 负极活性物质至少含有锡,钴,碳和磷作为元素。 碳含量为9.9重量%〜29.7重量%,磷含量为0.1重量%〜2.2重量%,钴和钴总量的钴比例为24重量%〜70重量%。
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公开(公告)号:US20060099515A1
公开(公告)日:2006-05-11
申请号:US11267116
申请日:2005-11-03
申请人: Akira Yamaguchi , Tadahiko Kubota , Atsumichi Kawashima , Akinori Kita , Satoshi Mizutani , Hiroshi Inoue
发明人: Akira Yamaguchi , Tadahiko Kubota , Atsumichi Kawashima , Akinori Kita , Satoshi Mizutani , Hiroshi Inoue
CPC分类号: H01M4/58 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M6/168 , H01M10/0431 , H01M10/0436 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/4235 , H01M2004/027
摘要: A battery capable of improving battery characteristics such as cycle characteristics is provided. An electrolytic solution is impregnated in a separator. The electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Fluorine ion content in the electrolytic solution is preferably from 10 weight ppm to 3200 weight ppm. Thereby, chemical stability of the electrolytic solution is improved, and cycle characteristics are improved. The present invention is effective for the case using an anode active material containing Sn or Si as an element for an anode.
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公开(公告)号:US08993166B2
公开(公告)日:2015-03-31
申请号:US12026594
申请日:2008-02-06
申请人: Satoshi Mizutani , Hiroshi Inoue , Akinori Kita , Akira Yamaguchi
发明人: Satoshi Mizutani , Hiroshi Inoue , Akinori Kita , Akira Yamaguchi
IPC分类号: H01M4/38 , H01M10/0569 , H01M4/134 , H01M4/36 , H01M4/58 , H01M10/0587 , H01M4/52 , H01M4/46 , H01M4/587 , H01M4/62 , H01M10/0525 , H01M10/42 , H01M4/02
CPC分类号: H01M10/0569 , H01M4/134 , H01M4/364 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/463 , H01M4/52 , H01M4/5805 , H01M4/587 , H01M4/625 , H01M10/0525 , H01M10/0587 , H01M10/4235 , H01M2004/021 , H01M2004/027 , Y02E60/122
摘要: A battery with the high capacity, the superior cycle characteristics, and the superior initial charge and discharge efficiency, and an anode active material used for it are provided. The anode active material contains at least tin, cobalt, carbon, and phosphorus as an element. A carbon content is from 9.9 wt % to 29.7 wt %, a phosphorus content is from 0.1 wt % to 2.2 wt %, and a cobalt ration to the total of the tin and the cobalt is from 24 wt % to 70 wt %.
摘要翻译: 提供具有高容量,优异的循环特性和优异的初始充放电效率的电池以及用于其的负极活性材料。 负极活性物质至少含有锡,钴,碳和磷作为元素。 碳含量为9.9重量%〜29.7重量%,磷含量为0.1重量%〜2.2重量%,钴和钴总量的钴比例为24重量%〜70重量%。
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公开(公告)号:US07927744B2
公开(公告)日:2011-04-19
申请号:US11225540
申请日:2005-09-13
申请人: Satoshi Mizutani , Hiroshi Inoue , Akira Yamaguchi , Akinori Kita
发明人: Satoshi Mizutani , Hiroshi Inoue , Akira Yamaguchi , Akinori Kita
IPC分类号: H01M4/58
CPC分类号: H01M10/0525 , H01M4/362 , H01M4/387 , H01M4/587 , H01M10/0569
摘要: A battery with a high capacity and superior cycle characteristics and an anode active material used in the battery are provided. An anode includes an anode active material capable of reacting with lithium. The anode active material includes at least tin, cobalt and carbon as elements, and the carbon content is within a range from 9.9 wt % to 29.7 wt % inclusive, and the ratio of cobalt to the total of tin and cobalt is within a range from 30 wt % to 70 wt % inclusive. Thereby, while a high capacity is maintained, cycle characteristics can be improved.
摘要翻译: 提供了具有高容量和优异的循环特性的电池以及用于电池中的阳极活性材料。 阳极包括能够与锂反应的负极活性物质。 负极活性物质至少包含锡,钴和碳作为元素,碳含量在9.9重量%至29.7重量%的范围内,钴与钴和钴的总量的比例在 30重量%〜70重量%。 因此,在保持高容量的同时,可以提高循环特性。
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公开(公告)号:US20050250008A1
公开(公告)日:2005-11-10
申请号:US10520915
申请日:2004-05-07
CPC分类号: H01M10/052 , H01M4/38 , H01M4/387 , H01M4/405 , H01M10/0565 , H01M2004/027
摘要: An anode material capable of providing a high capacity and improving cycle characteristics and a manufacturing method thereof, and a battery are provided. The anode material has a reaction phase containing an element capable of generating an intermetallic compound with Li and C. In this reaction phase, a half value width of a diffraction peak by X-ray diffraction is preferably 0.5° or more. Further, in this anode material, it is preferable that a peak of C is obtained in a region lower than 284.5 eV by XPS. In the case that Sn is contained as an element capable of generating an intermetallic compound with Li, it is preferable that an energy difference between a peak of 3d5/2 orbit of Sn and a peak of 1s orbit of C is larger than 200.1 eV. It becomes thereby possible that cohesion or crystallization of the element capable of generating an intermetallic compound with Li associated with charge and discharge can be inhibited.
摘要翻译: 提供能够提供高容量和改善循环特性的阳极材料及其制造方法和电池。 阳极材料具有包含能够与Li和C生成金属间化合物的元素的反应相。在该反应相中,通过X射线衍射的衍射峰的半值宽度优选为0.5°以上。 此外,在该阳极材料中,优选通过XPS在低于284.5eV的区域中获得C的峰。 在作为能够与Li产生金属间化合物的元素中含有Sn的情况下,优选Sn的3d×5/2轨道的峰值与1s轨道的峰值之间的能量差 的C大于200.1eV。 由此,可以抑制能够产生与充放电有关的金属间化合物的元素的内聚或结晶。
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公开(公告)号:US20060068285A1
公开(公告)日:2006-03-30
申请号:US11232304
申请日:2005-09-21
申请人: Akira Yamaguchi , Satoshi Mizutani , Hiroshi Inoue , Koji Sekai
发明人: Akira Yamaguchi , Satoshi Mizutani , Hiroshi Inoue , Koji Sekai
CPC分类号: H01M4/58 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/42 , H01M4/463 , H01M4/466 , H01M4/5805 , H01M10/052 , H01M10/0569 , H01M2004/027
摘要: A battery with a high capacity and superior cycle characteristics, and an anode active material used for it are provided. An anode active material contains tin as a first element, a second element, and a third element. The second element is at least one from the group consisting of boron, carbon, aluminum, and phosphorus, and the third element is at least one from the group consisting of silicon, magnesium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, zirconium, niobium, molybdenum, silver, indium, cerium, hafnium, tantalum, tungsten, and bismuth. The content of the second element in the anode active material is from 9.8 wt % to 49 wt %.
摘要翻译: 提供具有高容量和优异的循环特性的电池以及用于其的负极活性材料。 阳极活性材料包含锡作为第一元素,第二元素和第三元素。 第二元素是由硼,碳,铝和磷组成的组中的至少一种,第三元素是硅,镁,钛,钒,铬,锰,铁,钴, 镍,铜,锌,镓,锆,铌,钼,银,铟,铈,铪,钽,钨和铋。 负极活性物质中的第二元素的含量为9.8重量%〜49重量%。
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公开(公告)号:US20060115739A1
公开(公告)日:2006-06-01
申请号:US11267641
申请日:2005-11-03
申请人: Akira Yamaguchi , Kumiko Takagi , Yuzuru Fukushima , Satoshi Mizutani , Hiroshi Inoue , Atsumichi Kawashima
发明人: Akira Yamaguchi , Kumiko Takagi , Yuzuru Fukushima , Satoshi Mizutani , Hiroshi Inoue , Atsumichi Kawashima
CPC分类号: H01M10/4235 , H01M4/131 , H01M4/134 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/525 , H01M4/587 , H01M10/052 , H01M10/0567 , H01M10/0587 , H01M2004/021 , H01M2004/027 , H01M2300/004 , Y02E60/122
摘要: A battery capable of improving battery characteristics such as cycle characteristics and high temperature storage characteristics is provided. An anode includes an anode active material which includes Sn or Si as an element. A separator is impregnated with an electrolyte solution, and the electrolyte solution includes an acid anhydride such as succinic anhydride or a derivative thereof. Thereby, a coating is formed on the anode, and the decomposition of the electrolyte solution in the anode can be prevented. An electrolyte solution to which 4-fluoro-1,3-dioxolane-2-one is mixed is more preferably used.
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