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公开(公告)号：US4491630A
公开(公告)日：1985-01-01
申请号：US460512
申请日：1983-01-24
CPC分类号： G03C7/39252 , G03C7/384
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing at least one kind of compound represented by the following general formula (I): ##STR1## wherein each substituent represented by R.sub.1, R.sub.2, R.sub.3, X, or Ar and m are defined within the specification, said silver halide color photographic light-sensitive material comprises a compound represented by the following general formula (II) in the silver halide emulsion layer containing the compound represented by the above general formula (I) and/or a hydrophilic colloid layer which is positioned at the remoter side than the silver halide emulsion layer from the support: ##STR2## wherein each substituent represented by Y, R.sub.4, R.sub.5, R.sub.6, R.sub.7 or Ar is defined within the specification.The silver halide color photographic light-sensitive material can provide a magenta color image having excellent photographic properties without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.
摘要翻译： 一种卤化银彩色照相感光材料，其包含其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有由以下通式（I）表示的至少一种化合物：其中每个由R 1，R 2表示的取代基 所述卤化银彩色照相感光材料包含由以上通式表示的化合物的卤化银乳剂层中的由以下通式（II）表示的化合物：其中，R 3，X或Ar和m定义在本说明书中， 式（I）和/或位于距离载体的卤化银乳剂层更远侧的亲水胶体层：其中由Y，R4，R5，R6，R7或Ar表示的每个取代基 在规范内定义。 卤化银彩色摄影感光材料即使当在运行状态下在处理溶液中处理彩色照相材料时，也可以提供具有优异的照相性能的品红色图像，而不会发生污渍。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。
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2.发明授权
公开(公告)号：US4865963A
公开(公告)日：1989-09-12
申请号：US913792
申请日：1986-09-30
申请人： Nobuo Furutachi , Tadahisa Sato , Seiki Sakanoue , Akio Mitsui , Minoru Sakai , Masakazu Morigaki , Hidetoshi Kobayashi , Nobuo Sakai , Kiyoshi Nakazyo , Takeshi Hirose , Toshio Kawagishi
发明人： Nobuo Furutachi , Tadahisa Sato , Seiki Sakanoue , Akio Mitsui , Minoru Sakai , Masakazu Morigaki , Hidetoshi Kobayashi , Nobuo Sakai , Kiyoshi Nakazyo , Takeshi Hirose , Toshio Kawagishi
IPC分类号： C07D487/04 , G03C7/30 , G03C7/305 , G03C7/38
CPC分类号： C07D487/04 , G03C7/301 , G03C7/30529 , G03C7/3835
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] ##STR1## wherein, R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R.sup.1 and R.sup.2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R.sub.1 and R.sub.2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R.sup.1, R.sup.2 or X.By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.
摘要翻译： 一种卤化银彩色照相材料，包括其上具有至少一个卤化银乳剂层的载体，所述卤化银乳剂层含有由通式[I]表示的吡唑并苯系列品红成色剂，其中R1和R2各自表示 氢原子或取代基; X表示在与芳族伯胺显影剂的氧化产物反应时释放的氢原子或释放基团; 所述R 1和R 2中的至少一个是具有与所述骨架直接键合的仲或叔碳原子的烷基，所述R 1和R 2中的至少一个是亚磺酰氨基烷基或氨磺酰基烷基; 并且品红色成色剂可以在所述R1，R2或X的位置形成二聚体或更多聚合物。通过组合使用高沸点有机溶剂和紫外线吸收剂，耐光性和着色性显着提高。
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公开(公告)号：US4463085A
公开(公告)日：1984-07-31
申请号：US449812
申请日：1982-12-14
申请人： Akio Mitsui , Masakazu Morigaki
发明人： Akio Mitsui , Masakazu Morigaki
CPC分类号： G03C7/39248 , G03C7/3012
摘要： A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing at least one kind of 2-equivalent magenta coupler represented by the following general formula (Ia): ##STR1## wherein Ar represents phenyl substituted with at least one halogen, alkyl, alkoxy, alkoxycarbonyl or cyano; Y represents acylamino or anilino; and Z represents a group capable of being released by coupling, and at least one kind of piperidine compound represented by the following general formula (II): ##STR2## wherein R.sub.1 represents hydrogen or alkyl; R.sub.2 represents alkyl, hydroxyalkyl, alkenyl alkynyl or benzyl; W represents hydrogen, alkyl, hydroxy, silyloxy, alkylamino, aryloxy, allyl, alkoxy, acylamino, sulfonamido, alkoxycarbonyl, carboxy, acyloxy or phosphoric acid oxy. The silver halide color photographic light-sensitive material can provide a good magenta color image without the occurrence of strain, even when the color photographic material is processed in a processing solution under the running condition.
摘要翻译： 一种卤化银彩色照相感光材料，其包含在其上涂覆有至少一个卤化银乳剂层的载体，所述彩色照相感光材料含有至少一种由以下通式（Ia）表示的2-当量品红成色剂， （Ia）其中Ar表示被至少一个卤素，烷基，烷氧基，烷氧基羰基或氰基取代的苯基; Y表示酰氨基或苯胺基; Z表示可通过偶联而释放的基团，以及由以下通式（II）表示的至少一种哌啶化合物：其中R 1表示氢或烷基; R2代表烷基，羟基烷基，烯基炔基或苄基; W表示氢，烷基，羟基，甲硅烷氧基，烷基氨基，芳氧基，烯丙基，烷氧基，酰氨基，亚磺酰氨基，烷氧基羰基，羧基，酰氧基或磷酸氧基。 即使在运行条件下在处理溶液中处理彩色照相材料，卤化银彩色照相感光材料也可以提供良好的品红色图像而不产生应变。
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公开(公告)号：US4456682A
公开(公告)日：1984-06-26
申请号：US420689
申请日：1982-09-21
CPC分类号： G03C7/39252
摘要： A silver halide color photographic material is disclosed. The material has improved developing characteristics which are obtained by containing both a substantially light-insensitive silver halide and at least one specific 3-pyrazolidone compound. The substantially light-insensitive silver halide includes a halogen composition consisting of 0 to 100 percent of bromide, 0 to 2 percent of iodine and the residual percent of chlorine, a mean grain size of 0.01 to 0.3.mu., and a coverage of 5 to 500 mg/m.sup.2. The 3-pyrazolidone compound has the following general formula (I): ##STR1## wherein X represents a hydrogen atom or an acetyl group; R represents an aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, an alkyl group or an aryl group, and they may be the same as or different from one another. The material can be developed at an increased speed and is not accompanied by undesirable photographic effects such as fogging.
摘要翻译： 公开了一种卤化银彩色照相材料。 该材料具有改善的显影特性，其通过含有基本上不受光的卤化银和至少一种特定的3-吡唑烷酮化合物而获得。 基本上不光敏的卤化银包括卤素组合物，其由0-100％的溴化物，0-2％的碘和氯的残余百分比组成，平均粒径为0.01至0.3μm，覆盖率为5至500 mg / m2。 3-吡唑烷酮化合物具有以下通式（I）：其中X表示氢原子或乙酰基;（I） R表示芳基; 并且R 1，R 2，R 3和R 4各自表示氢原子，烷基或芳基，并且它们可以彼此相同或不同。 该材料可以以增加的速度进行显影，并且不伴随不期望的照相效果，如起雾。
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公开(公告)号：US4409324A
公开(公告)日：1983-10-11
申请号：US420665
申请日：1982-09-21
CPC分类号： G03C7/388 , G03C7/39252
摘要： A multilayer color photographic sensitive material is disclosed. The material is comprised of a support base and a silver halide emulsion layer. The material contains at least one layer containing a high boiling solvent and an oil-soluble coupler, wherein the volume ratio of solvent to coupler is 1/2 or less, and a compound represented by the general formula (I): ##STR1## wherein X is a hydrogen atom or an acetyl group, R is an aryl group, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group. The material produces sharp images even though it contains a low oil/coupler ratio. Furthermore, there is no retardation of development.
摘要翻译： 公开了一种多层彩色感光材料。 该材料由支撑基底和卤化银乳剂层组成。 该材料含有至少一层包含高沸点溶剂和油溶性成色剂，其中溶剂与偶合剂的体积比为1/2或更小，以及由通式（I）表示的化合物：
（ I）其中X是氢原子或乙酰基，R是芳基，R 1，R 2，R 3和R 4可以相同或不同，各自表示氢原子，烷基或芳基。 该材料即使含有较低的油/耦合比，也能产生清晰的图像。 此外，发展没有阻碍。 -
公开(公告)号：US6106991A
公开(公告)日：2000-08-22
申请号：US399360
申请日：1999-09-20
申请人： Toshiki Taguchi , Takeshi Shibata , Nobuo Seto , Hideaki Naruse , Akio Mitsui
发明人： Toshiki Taguchi , Takeshi Shibata , Nobuo Seto , Hideaki Naruse , Akio Mitsui
CPC分类号： G03C8/26
摘要： There is disclosed a photographic element which contains, in a binder on a base, a specified compound having a group that is capable of causing chemical reaction with a reactive group contained in the binder, to form a covalent bond. According to the photographic element, a color image excellent in light-fastness can be obtained.
摘要翻译： 公开了一种照相元件，其在基材中的粘合剂中含有能够与粘合剂中所含的反应性基团发生化学反应的基团的特定化合物，形成共价键。 根据摄影元件，可以获得耐光性优异的彩色图像。
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公开(公告)号：US4792518A
公开(公告)日：1988-12-20
申请号：US186715
申请日：1988-04-22
申请人： Shigeru Kuwashima , Akio Mitsui , Masaru Sano
发明人： Shigeru Kuwashima , Akio Mitsui , Masaru Sano
CPC分类号： G03C1/015 , G03C7/3041 , G03C2001/0357 , G03C2200/06 , G03C5/50 , G03C7/00
摘要： A silver halide color reversal reflection print photosensitive material comprises at least one blue-sensitive layer, at least one green-sensitive layer and at least one red-sensitive layer on a support. In the characteristic curves of the color sensitive layers, a fluctuation width of point-gammas and absolute values of point-gammas are defined. The distribution of the grain size of the silver halide grains in silver halide emulsions contained in the color sensitive layer can be controlled by forming the grains in the presence of a silver halide solvent.
摘要翻译： 卤化银彩色反转印刷感光材料包括至少一个蓝色感光层，至少一个感光层和至少一个支持体上的红色敏感层。 在色敏层的特征曲线中，定义了点伽马的波动宽度和点伽马的绝对值。 包含在感光层中的卤化银颗粒中的卤化银颗粒的粒度分布可以通过在卤化银溶剂存在下形成晶粒来控制。
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8.发明授权Color photographic light-sensitive material containing +-alkyl substituted hydroquinone 失效含有{30-烷基取代的氢醌的彩色照相感光材料
公开(公告)号：US4121939A
公开(公告)日：1978-10-24
申请号：US815753
申请日：1977-07-14
申请人： Keiichi Adachi , Akio Mitsui
发明人： Keiichi Adachi , Akio Mitsui
IPC分类号： G03C7/26 , C07C27/00 , C07C39/08 , C07C67/00 , G03C7/392 , G03C8/08 , G03C1/48 , G03C1/06 , G03C1/10 , G03C1/40
CPC分类号： G03C7/39216
摘要： A color photographic light-sensitive material comprising a support having thereon at least one layer of a silver halide photographic emulsion with the light-sensitive material containing at least one hydroquinone compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, ##STR2## or a precursor thereof.
摘要翻译： 一种彩色摄影感光材料，其包括其上具有至少一层卤化银照相乳剂的支持体，所述感光材料含有由以下通式（I）表示的至少一种氢醌化合物： 其中R1表示氢原子，或其前体。
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公开(公告)号：US5336590A
公开(公告)日：1994-08-09
申请号：US952157
申请日：1992-09-28
申请人： Akio Mitsui
发明人： Akio Mitsui
CPC分类号： G03C7/3003 , Y10S430/141
摘要： A silver halide color photographic photosensitive material is disclosed which comprises a transparent support on which there are provided at least one cyan color forming coupler containing layer, at least one magenta color forming coupler containing layer, and at least one yellow color forming coupler containing layer, and at least one light-insensitive layer, wherein a compound represented by formula (I), a compound represented by formula (IIa) or (IIb) or both, and an internal latent image forming silver halide grain are contained in the photographic material: ##STR1## wherein Z.sup.11 represents a group of non-metal atoms which is required to form a five or six membered heterocyclic ring, and Z.sup.11 may be substituted with substituent groups; R.sup.11 is an aliphatic group; and R.sup.12 is a hydrogen atom, an aliphatic group or an aromatic group; R.sup.11 and R.sup.12 may be substituted with substituent groups; R.sup.12 may be joined to the heterocyclic ring completed by Z.sup.11 to form a ring; provided that at least one of the groups R.sup.11, R.sup.12 and Z.sup.11 contains an alkyl group, an acyl group, a hydrazine group or a hydrazone group, R.sup.11 and R.sup.12 may be combined to form a dihydropyridinium skeleton; moreover, at least one of the groups R.sup.11, R.sup.12 and Z.sup.11 may have a group which promotes adsorption on silver halide; and Y.sup.11 is a charge balancing counter ion and n is 0 or 1: ##STR2## wherein R.sub.21, R.sub.22 and R.sub.23 each represents an aliphatic group, an aromatic group, or a heterocyclic group; R.sub.25 represents an aniline group or an acylamino group; R.sub.24 represents a substituted phenyl group; X.sup.21 represents a linkage group and X.sup.21 may not exist; R.sub.26 represents a group which can be substituted on a benzene ring; and m represents an integer of 0 to 4.
摘要翻译： 公开了一种卤化银彩色照相感光材料，其包括透明支撑体，在该透明支撑体上设置有至少一种形成青色的成色剂，含有至少一种品红色形成成色剂的含有层，以及至少一种形成黄色的成色剂的层， 和至少一种不透光层，其中由式（I）表示的化合物，由式（IIa）或（IIb）表示的化合物或两者，以及内部潜像形成卤化银颗粒包含在照相材料中： （I）其中Z11表示形成五或六元杂环所需的一组非金属原子，Z 11可以被取代基取代; R11是脂族基团; R 12为氢原子，脂肪族基团或芳香族基团; R 11和R 12可以被取代基取代; R12可以连接到由Z11完成的杂环以形成环; 条件是组R11，R12和Z11中的至少一个含有烷基，酰基，肼基或腙基，R 11和R 12可以结合形成二氢吡啶骨架; 此外，基团R11，R12和Z11中的至少一个可以具有促进卤化银吸附的基团; （IIa）（IIb）其中R21，R22和R23各自表示脂族基团，芳族基团或杂环基团;并且Y11为电荷平衡反离子，n为0或1。 R25表示苯胺基或酰氨基; R 24表示取代的苯基; X21表示连接基，X21可以不存在; R26表示可在苯环上取代的基团; m表示0〜4的整数。
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10.发明授权
公开(公告)号：US4232114A
公开(公告)日：1980-11-04
申请号：US939108
申请日：1978-09-01
申请人： Keiichi Adachi , Tadao Shishido , Akio Mitsui
发明人： Keiichi Adachi , Tadao Shishido , Akio Mitsui
CPC分类号： G03C7/39216 , C07C37/14 , C07C37/16 , C07C39/245 , C07C2101/14
摘要： A color photographic light-sensitive element having (1) reduced fog, (2) low reduction in sensitivity and (3) good yellow dye image light fastness, and comprising a support having thereon at least one silver halide photographic emulsion and optionally one or more non-light-sensitive subsidiary layers, wherein a blue-sensitive silver halide photographic emulsion layer and/or a non-light-sensitive layer adjacent thereto contains at least one asymmetrical hydroquinone compound selected from the group consisting of 2-methyl-5-tert-octylhydroquinone, 2-tert-butyl-5-tert- amylhydroquinone, 2-tert-butyl-5-tert-hexylhydroquinone, 2-methyl-5-tert-hexylhydroquinone, 2-methyl-5-tert-amylhydroquinone, 2-methyl-5-(1'-methylcyclohexyl)hydroquinone and precursors thereof wherein either or both hydroxyl groups are modified with an acyl group represented by the formulae: ##STR1## wherein R represents an alkyl group.
摘要翻译： 一种彩色照相感光元件，其具有（1）减雾，（2）灵敏度降低低，（3）黄色染料图像耐光性良好，并且包括其上具有至少一种卤化银照相乳剂和任选的一种或多种 非敏感性辅助层，其中感蓝卤化银照相乳剂层和/或与其相邻的非感光层含有至少一种不对称氢醌化合物，其选自2-甲基-5-叔 2-叔丁基-5-叔戊基氢醌，2-叔丁基-5-叔己基氢醌，2-甲基-5-叔己基氢醌，2-甲基-5-叔戊基氢醌，2-甲基-5-叔己基氢醌，2-甲基-5-叔己基氢醌， -5-（1'-甲基环己基）氢醌及其前体，其中羟基之一或两者用下式表示的酰基进行改性：其中R表示烷基。
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