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    Indoline compounds useful for dyeing keratinous fibres
    1.
    发明授权
    Indoline compounds useful for dyeing keratinous fibres 失效
    可用于染色角质纤维的二氢吲哚化合物

    公开(公告)号：US5556989A

    公开(公告)日：1996-09-17

    申请号：US401671

    申请日：1995-03-10

    申请人： Alain Lagrange ,  Jean J. Vandenbosche ,  Herv e Andrean

    发明人： Alain Lagrange ,  Jean J. Vandenbosche ,  Herv e Andrean

    IPC分类号： A61K8/00 ,  A61K8/42 ,  A61K8/49 ,  A61Q5/10 ,  C07D209/08 ,  C09B57/00 ,  D06P3/22

    CPC分类号： A61Q5/10 ,  A61K8/492 ,  C07D209/08

    摘要： The invention relates to indoline compounds of formula (I): ##STR1## in which: R.sub.1 and R.sub.2 denote hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, nitro, hydroxyl, alkoxy or NHR where R can be hydrogen, alkyl, monohydroxyalkyl or polyhydroxyalkyl;X denotes oxygen or sulfur;R.sub.3 represents --OR.sub.4 or NR.sub.5 R.sub.6 whereR.sub.4 denotes alkyl, alkenyl, benzyl, alkoxyalkyl or haloalkyl;R.sub.5 and R.sub.6 denote alkyl;R.sub.1 and R.sub.2 not simultaneously denoting hydrogen or nitro and when R.sub.1 denotes alkyl, alkoxy or mono- or polyhydroxyalkyl, R.sub.2 denotes NHR or hydroxyl,and to their use in dyeing keratinous fibers.

    摘要翻译： 本发明涉及式（I）的二氢吲哚化合物：其中：R 1和R 2表示氢，烷基，单羟基烷基，多羟基烷基，硝基，羟基，烷氧基或NHR，其中R可以是氢，烷基，单羟基烷基或 聚羟烷基 X表示氧或硫; R3表示-OR4或NR5R6，其中R4表示烷基，烯基，苄基，烷氧基烷基或卤代烷基; R5和R6表示烷基; R1和R2不同时表示氢或硝基，当R1表示烷基，烷氧基或单羟基或多羟基烷基时，R2表示NHR或羟基，也用于染色角质纤维。

    Indoline-based products, processes for preparing them and their use in cosmetics
    2.
    发明授权
    Indoline-based products, processes for preparing them and their use in cosmetics 失效
    基于二氢吲哚的产品，其制备方法及其在化妆品中的应用

    公开(公告)号：US5583234A

    公开(公告)日：1996-12-10

    申请号：US119072

    申请日：1993-12-29

    申请人： Alain Lagrange ,  Herv e Andrean ,  Alex Junino

    发明人： Alain Lagrange ,  Herv e Andrean ,  Alex Junino

    IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/49 ,  A61K8/89 ,  A61K8/891 ,  A61K8/92 ,  A61Q1/00 ,  A61Q1/02 ,  A61Q1/10 ,  A61Q3/00 ,  A61Q3/02 ,  A61Q5/00 ,  A61Q5/10 ,  A61Q17/04 ,  C07D209/04 ,  C07D209/08 ,  C07D209/10 ,  C08G61/12 ,  C08G73/06 ,  C08K5/3417 ,  C08L101/00 ,  C09B69/10 ,  A61K7/13

    CPC分类号： A61Q17/04 ,  A61K8/492 ,  A61Q1/02 ,  A61Q5/10 ,  C08G61/124 ,  C09B69/104

    摘要： An indoline product obtained by oxidizing at least one compound of formula (I), ##STR1## wherein R.sub.1 and R.sub.3 independently represent a hydrogen atom or a C.sub.1-4 alkyl grouping; R.sub.2 represents a hydrogen atom, a C.sub.1-4 alkyl grouping, a carboxyl grouping or C.sub.1-4 alkoxycarbonyl; R.sub.4 is a hydrogen atom, a C.sub.1-4 alkyl grouping, hydroxyl, C.sub.1-4 alkoxy, C.sub.1-10 amino or alkylamino, or halogen; R.sub.5 is a hydrogen atom, a hydroxyl grouping, C.sub.1-4 alkoxy or amino; with the proviso that at least one of the radicals R.sub.4 or R.sub.5 is a hydroxyl, alkoxy or amino grouping, and that when R.sub.5 is an amino grouping, R.sub.4 is not an alkylamino radical; R.sub.4 and R.sub.5 may also form a C.sub.1-2 alkylenedioxy ring and are in positions 5 and 6; and corresponding salts thereof. Said product may be used in cosmetics as make-up for the hair, eyebrows, eyelashes, nails, etc., and/or skin.

    摘要翻译： PCT No.PCT / FR93 / 00030 Sec。 371日期1993年12月29日第 102（e）日期1993年12月29日PCT 1993年1月13日PCT PCT。 第WO93 / 13744号公报 日期：1993年7月22日通过氧化至少一种式（I）化合物，其中R 1和R 3独立地表示氢原子或C 1-4烷基; R2表示氢原子，C1-4烷基，羧基或C1-4烷氧基羰基; R4是氢原子，C1-4烷基，羟基，C1-4烷氧基，C1-10氨基或烷基氨基或卤素; R5是氢原子，羟基，C1-4烷氧基或氨基; 条件是基团R 4或R 5中的至少一个是羟基，烷氧基或氨基，并且当R 5是氨基时，R 4不是烷基氨基; R4和R5也可以形成C1-2亚烷基二氧基环，位于5和6位; 及其相应的盐。 所述产品可用于化妆品中作为头发，眉毛，睫毛，指甲等的化妆和/或皮肤。

    Dyeing compositions containing indoline compounds and process for dyeing keratinous fibres
    5.
    发明授权
    Dyeing compositions containing indoline compounds and process for dyeing keratinous fibres 失效
    含有二氢吲哚化合物的染色组合物和染色角质纤维的方法

    公开(公告)号：US5427588A

    公开(公告)日：1995-06-27

    申请号：US165853

    申请日：1993-12-14

    申请人： Alain Lagrange ,  Jean J. Vandenbosche ,  Herve Andrean

    发明人： Alain Lagrange ,  Jean J. Vandenbosche ,  Herve Andrean

    IPC分类号： A61K8/00 ,  A61K8/42 ,  A61K8/49 ,  A61Q5/10 ,  C07D209/08 ,  C09B57/00 ,  D06P3/22 ,  A61K7/13

    CPC分类号： A61Q5/10 ,  A61K8/492 ,  C07D209/08

    摘要： The invention relates to indoline compounds of formula (I): ##STR1## in which: R.sub.1 and R.sub.2 denote hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, nitro, hydroxyl, alkoxy or NHR where R can be hydrogen, alkyl, monohydroxyalkyl or polyhydroxyalkyl;X denotes oxygen or sulfur;R.sub.3 represents --OR.sub.4 or NR.sub.5 R.sub.6 whereR4 denotes alkyl, alkenyl, benzyl, alkoxyalkyl or haloalkyl;R.sub.5 and R.sub.6 denote alkyl;R.sub.1 and R.sub.2 not simultaneously denoting hydrogen or nitro and when R.sub.1 denotes alkyl, alkoxy or mono- or polyhydroxyalkyl, R.sub.2 denotes NHR or hydroxyl,and to their use in dyeing keratinous fibers.

    摘要翻译： 本发明涉及式（I）的二氢吲哚化合物：其中：R 1和R 2表示氢，烷基，单羟基烷基，多羟基烷基，硝基，羟基，烷氧基或NHR，其中R可以是氢，烷基，单羟基烷基或 聚羟烷基 X表示氧或硫; R3表示-OR4或NR5R6，其中R4表示烷基，烯基，苄基，烷氧基烷基或卤代烷基; R5和R6表示烷基; R1和R2不同时表示氢或硝基，当R1表示烷基，烷氧基或单羟基或多羟基烷基时，R2表示NHR或羟基，也用于染色角质纤维。

    Hair treatment process using a direct emulsion comprising an oxidizing agent and a direct emulsion containing an alkaline agent
    8.
    发明授权
    Hair treatment process using a direct emulsion comprising an oxidizing agent and a direct emulsion containing an alkaline agent 有权
    使用包含氧化剂和含有碱性试剂的直接乳液的直接乳液的头发处理方法

    公开(公告)号：US08758450B2

    公开(公告)日：2014-06-24

    申请号：US13638940

    申请日：2011-03-30

    申请人： Leila Hercouet ,  Alain Lagrange

    发明人： Leila Hercouet ,  Alain Lagrange

    IPC分类号： A61Q5/10

    CPC分类号： A61Q5/08 ,  A61K8/06 ,  A61K8/062 ,  A61K8/31 ,  A61K8/33 ,  A61K2800/4322 ,  A61K2800/88 ,  A61Q5/065 ,  A61Q5/10

    摘要： The subject of the present invention is therefore a method for the lightening and/or lightening dyeing of keratin materials, which consists in treating the keratin fibers with at least: a) one direct emulsion (A) comprising one or more fatty substances free of carboxylic acid groups, one or more surfactants, an amount of water of greater than 5% by weight of the total weight of the emulsion, and one or more oxidizing agents; and b) one direct emulsion (B) comprising one or more fatty substances free of carboxylic acid groups, one or more surfactants, an amount of water of greater than 5% by weight of the total weight of the emulsion, and one or more alkaline agents; the concentration of fatty substances free of carboxylic acid groups being at least equal to 25% by weight of the total weight of the composition obtained after mixing the two direct emulsions (A) and (B). This process does not have the drawbacks caused by the presence of high contents of alkaline agents, and uses dyeing and/or bleaching compositions having improved lightening properties and that are stable over time, while at the same time remaining at least as effective in terms of the uniformity of the lightening, while at the same time preserving the quality of the keratin fiber.

    摘要翻译： 因此，本发明的主题是减轻和/或减轻对角蛋白材料的染色的方法，其包括至少在以下方面处理角蛋白纤维：a）一种直接乳液（A），其包含一种或多种不含羧酸的脂肪物质 酸基团，一种或多种表面活性剂，大于乳液总重量的5重量％的水和一种或多种氧化剂; 和b）包含一种或多种不含羧酸基团的脂肪物质的一种直接乳液（B），一种或多种表面活性剂，大于乳剂总重量的5重量％的水量和一种或多种碱 代理人 不含羧酸基团的脂肪物质的浓度至少等于混合两种直接乳液（A）和（B）后获得的组合物的总重量的25重量％。 该方法不具有由高含量碱性试剂的存在引起的缺点，并且使用具有改善的发光性能并且随时间稳定的染色和/或漂白组合物，同时在至少与 减轻均匀性，同时保持角蛋白纤维的质量。

    Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine and at least one inorganic base, and device therefor
    10.
    发明授权
    Process for lightening or lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine and at least one inorganic base, and device therefor 有权
    在至少一种有机胺和至少一种无机碱的存在下减轻或减轻直接染色或氧化染色的方法及其装置

    公开(公告)号：US07935154B2

    公开(公告)日：2011-05-03

    申请号：US12642536

    申请日：2009-12-18

    申请人： Leïla Hercouet ,  Alain Lagrange

    发明人： Leïla Hercouet ,  Alain Lagrange

    IPC分类号： A61Q5/10

    CPC分类号： A61K8/19 ,  A61K8/22 ,  A61K8/25 ,  A61K8/31 ,  A61K8/41 ,  A61K8/43 ,  A61K8/44 ,  A61K8/4946 ,  A61K2800/31 ,  A61Q5/065 ,  A61Q5/08 ,  A61Q5/10

    摘要： Provided is a process for lightening or dyeing keratin fibers, including human keratin fibers such as the hair, in the presence of an oxidizing agent, wherein the following are applied to the keratin fibers: (a) an anhydrous cosmetic composition (A) comprising at least one fatty substance and at least one surfactant, (b) a cosmetic composition (B) comprising at least one organic amine with a pKb of less than 12 at 25° C. and at least one mineral base, and (c) a composition (C) comprising at least one oxidizing agent; when the process described herein is a process for dyeing keratin fibers, composition (B) further comprises at least one dye. Also provided is a multi-compartment device comprising a first compartment having the anhydrous cosmetic composition, a second compartment having at least one organic amine with a pKb of less than 12 at 25° C., and also at least one mineral base and optionally at least one dye, and a third compartment having an oxidizing composition.

    摘要翻译： 本发明提供一种在氧化剂存在下使人角蛋白纤维如毛发变亮或着色的方法，其中将以下应用于角蛋白纤维：（a）无水化妆品组合物（A），其包含： 至少一种脂肪物质和至少一种表面活性剂，（b）包含至少一种在25℃下pKb小于12的有机胺和至少一种矿物基质的化妆品组合物（B），和（c）组合物 （C）包含至少一种氧化剂; 当本文所述的方法是染色角蛋白纤维的方法时，组合物（B）还包含至少一种染料。 还提供了一种多隔室装置，其包括具有无水化妆品组合物的第一隔室，具有至少一种在25℃下pKb小于12的有机胺的第二隔室，以及至少一种矿物碱， 至少一种染料，以及具有氧化组合物的第三隔室。