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1.发明申请PROCESS FOR THE OXIDATION OF HYDROCARBONS WITH THE USE OF IRIDIUM METAL CATALYST COMPLEXES 有权使用卤化物金属催化剂复合物来氧化烃类的方法公开(公告)号：US20130245324A1
公开(公告)日：2013-09-19
申请号：US13611072
申请日：2012-09-12
CPC分类号： C07C29/50 , B01J31/1825 , B01J31/183 , B01J2231/70 , B01J2531/0244 , B01J2531/827 , C07C46/04 , C07D235/20 , C07C31/02
摘要： Provided is a process for effectively and efficiently oxidizing alkyl-containing molecules with the use of an oxygen-containing gas. An iridium metal catalyst complex with the iridium being coordinated with the nitrogen atoms of a benzimidazolyl-containing ligand is used as the catalyst. The process generates alcohols, ketones and aldehydes directly from alkyl-containing molecules and/or aromatic molecules.
摘要翻译： 提供了使用含氧气体有效地高效地氧化含烷基的分子的方法。 使用与含苯并咪唑基的配体的氮原子配位的铱金属催化剂络合物作为催化剂。 该方法直接从含烷基的分子和/或芳族分子产生醇，酮和醛。
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2.发明申请NOVEL IRIDIUM CATALYST COMPLEXES AND C-H BOND ACTIVATED PRODUCTS THEREFROM 有权新型IRIDIUM催化剂复合物和C-H结合活性产物公开(公告)号：US20130245277A1
公开(公告)日：2013-09-19
申请号：US13611089
申请日：2012-09-12
IPC分类号： B01J31/18
CPC分类号： B01J31/183 , B01J23/468 , C07C5/333 , C07C5/52 , C07C17/202 , C07C2531/22 , C07F15/004 , C07C11/12 , C07C11/02 , C07C25/02
摘要： Provided is a novel iridium catalyst complex which is useful in the dehydrogenation of alkanes. The iridium complex comprises the metal iridium atom complexed with a benzimidazolyl-containing ligand. The iridium atom can be coordinated with the nitrogen atoms in the benzimidazolyl-containing ligand to form an NCN pincer ligand complex. In another embodiment, the iridium catalyst is used, with or without a co-catalyst, in a dehydrogenation reaction converting alkanes to olefins. The reaction can be in a closed or open system, and can be run in a liquid or gaseous phase.
摘要翻译： 提供了一种可用于烷烃脱氢的新型铱催化剂络合物。 铱络合物包含与含苯并咪唑基的配体络合的金属铱原子。 铱原子可以与含苯并咪唑基的配体中的氮原子配位以形成NCN钳子配体络合物。 在另一个实施方案中，铱催化剂在有或没有助催化剂的情况下用于将烷烃转化为烯烃的脱氢反应。 该反应可以在封闭或开放的系统中，并且可以在液相或气相中运行。
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公开(公告)号：US20130090503A1
公开(公告)日：2013-04-11
申请号：US13612572
申请日：2012-09-12
IPC分类号： C07C2/74
CPC分类号： C07C2/74 , C07C2/32 , C07C5/3337 , C07C2531/22 , C07C2531/28 , C07C11/02 , C07C9/22
摘要： Provided is a process for preparing oligomers from an alkane. The process comprises (a) contacting an alkane under dehydrogenation conditions in the presence of a dehydrogenation catalyst such as an iridium catalyst complex comprising iridium complexed with a benzimidiazolyl-containing ligand to form olefins, and (b) contacting the olefins prepared in step (a) under oligomerization conditions with an oligomerization catalyst such as a nickel, platinum or palladium metal catalyst complex comprising the metal complexed with a nitrogen containing bi- or tridentate ligand to prepare oligomers of the olefins, and hydrogenating the olefin oligomers. In one embodiment, the ligands of the catalyst complexes in step (a) and step (b) can be the same.
摘要翻译： 提供了从烷烃制备低聚物的方法。 该方法包括（a）在脱氢条件下，在脱氢催化剂存在下使烷烃接触，所述脱氢催化剂例如包含与含苯并咪唑基的配体络合的铱的铱催化剂络合物以形成烯烃，和（b）使步骤（a ）在低聚条件下用低聚催化剂如镍，铂或钯金属催化剂络合物，其包含与含氮双配位配位体络合的金属，以制备烯烃的低聚物，并氢化烯烃低聚物。 在一个实施方案中，步骤（a）和步骤（b）中的催化剂配合物的配体可以相同。
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公开(公告)号：US20150073185A1
公开(公告)日：2015-03-12
申请号：US14483008
申请日：2014-09-10
CPC分类号： C07C5/03 , B01J31/0208 , B01J31/183 , B01J31/2409 , B01J2231/20 , B01J2231/766 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C2/32 , C07C5/333 , C07C5/48 , C07C5/52 , C07C2531/02 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07C11/02 , C07C9/00
摘要： Provided is a Group 9 novel metal catalyst complex further comprising a ketone-containing cocatalyst. The metal catalyst complex is useful in generating olefins from alkanes with great efficiency. In one embodiment, provided is an iridium catalyst complex useful in the dehydrogenation of alkanes comprising a ketone-containing cocatalyst and iridium complexed with a tridentate ligand. Also provided is a novel dehydrogenation method which utilizes the catalyst composition. In other embodiments, a novel process for preparing oligomers from alkanes utilizing the catalyst composition is provided.
摘要翻译： 提供了另外包含含酮助催化剂的第9族新型金属催化剂络合物。 金属催化剂络合物可用于以高效率从烷烃产生烯烃。 在一个实施方案中，提供了一种可用于含有酮的助催化剂和与三齿配体络合的铱的烷烃脱氢的铱催化剂络合物。 还提供了一种利用催化剂组合物的新型脱氢方法。 在其它实施方案中，提供了利用催化剂组合物从烷烃制备低聚物的新方法。
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公开(公告)号：US09289759B2
公开(公告)日：2016-03-22
申请号：US13611089
申请日：2012-09-12
CPC分类号： B01J31/183 , B01J23/468 , C07C5/333 , C07C5/52 , C07C17/202 , C07C2531/22 , C07F15/004 , C07C11/12 , C07C11/02 , C07C25/02
摘要： Provided is a novel iridium catalyst complex which is useful in the dehydrogenation of alkanes. The iridium complex comprises the metal iridium atom complexed with a benzimidazolyl-containing ligand. The iridium atom can be coordinated with the nitrogen atoms in the benzimidazolyl-containing ligand to form an NCN pincer ligand complex. In another embodiment, the iridium catalyst is used, with or without a co-catalyst, in a dehydrogenation reaction converting alkanes to olefins. The reaction can be in a closed or open system, and can be run in a liquid or gaseous phase.
摘要翻译： 提供了一种可用于烷烃脱氢的新型铱催化剂络合物。 铱络合物包含与含苯并咪唑基的配体络合的金属铱原子。 铱原子可以与含苯并咪唑基的配体中的氮原子配位以形成NCN钳子配体络合物。 在另一个实施方案中，铱催化剂在有或没有助催化剂的情况下用于将烷烃转化为烯烃的脱氢反应。 该反应可以在封闭或开放的系统中，并且可以在液相或气相中运行。
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公开(公告)号：US09278894B2
公开(公告)日：2016-03-08
申请号：US13612572
申请日：2012-09-12
CPC分类号： C07C2/74 , C07C2/32 , C07C5/3337 , C07C2531/22 , C07C2531/28 , C07C11/02 , C07C9/22
摘要： Provided is a process for preparing oligomers from an alkane. The process comprises (a) contacting an alkane under dehydrogenation conditions in the presence of a dehydrogenation catalyst such as an iridium catalyst complex comprising iridium complexed with a benzimidiazolyl-containing ligand to form olefins, and (b) contacting the olefins prepared in step (a) under oligomerization conditions with an oligomerization catalyst such as a nickel, platinum or palladium metal catalyst complex comprising the metal complexed with a nitrogen containing bi- or tridentate ligand to prepare oligomers of the olefins, and hydrogenating the olefin oligomers. In one embodiment, the ligands of the catalyst complexes in step (a) and step (b) can be the same.
摘要翻译： 提供了从烷烃制备低聚物的方法。 该方法包括（a）在脱氢条件下，在脱氢催化剂存在下使烷烃接触，所述脱氢催化剂例如包含与含苯并咪唑基的配体络合的铱的铱催化剂络合物以形成烯烃，和（b）使步骤（a ）在低聚条件下用低聚催化剂如镍，铂或钯金属催化剂络合物，其包含与含氮双配位配位体络合的金属，以制备烯烃的低聚物，并氢化烯烃低聚物。 在一个实施方案中，步骤（a）和步骤（b）中的催化剂配合物的配体可以相同。
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7.发明授权Process for the oxidation of hydrocarbons with the use of iridium metal catalyst complexes 有权使用铱金属催化剂配合物对烃进行氧化的方法公开(公告)号：US08664447B2
公开(公告)日：2014-03-04
申请号：US13611072
申请日：2012-09-12
CPC分类号： C07C29/50 , B01J31/1825 , B01J31/183 , B01J2231/70 , B01J2531/0244 , B01J2531/827 , C07C46/04 , C07D235/20 , C07C31/02
摘要： Provided is a process for effectively and efficiently oxidizing alkyl-containing molecules with the use of an oxygen-containing gas. An iridium metal catalyst complex with the iridium being coordinated with the nitrogen atoms of a benzimidazolyl-containing ligand is used as the catalyst. The process generates alcohols, ketones and aldehydes directly from alkyl-containing molecules and/or aromatic molecules.
摘要翻译： 提供了使用含氧气体有效地高效地氧化含烷基的分子的方法。 将铱金属催化剂络合物与含有苯并咪唑基的配体的氮原子配位的铱金属催化剂络合物用作催化剂。 该方法直接从含烷基的分子和/或芳族分子产生醇，酮和醛。
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公开(公告)号：US09676682B2
公开(公告)日：2017-06-13
申请号：US14483008
申请日：2014-09-10
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , C07C5/03 , C07C5/333 , C07C5/48 , C07C2/32 , C07C5/52 , B01J31/02 , B01J31/18 , B01J31/24
CPC分类号： C07C5/03 , B01J31/0208 , B01J31/183 , B01J31/2409 , B01J2231/20 , B01J2231/766 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C2/32 , C07C5/333 , C07C5/48 , C07C5/52 , C07C2531/02 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07C11/02 , C07C9/00
摘要： Provided is a Group 9 novel metal catalyst complex further comprising a ketone-containing cocatalyst. The metal catalyst complex is useful in generating olefins from alkanes with great efficiency. In one embodiment, provided is an iridium catalyst complex useful in the dehydrogenation of alkanes comprising a ketone-containing cocatalyst and iridium complexed with a tridentate ligand. Also provided is a novel dehydrogenation method which utilizes the catalyst composition. In other embodiments, a novel process for preparing oligomers from alkanes utilizing the catalyst composition is provided.
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公开(公告)号：US08841500B2
公开(公告)日：2014-09-23
申请号：US13612599
申请日：2012-09-12
CPC分类号： C07C2/66 , C07C5/31 , C07C5/333 , C07C2529/70 , C07C2531/22 , C07C2531/24 , C07C15/44 , C07C15/02 , C07C13/48
摘要： Provided is a process for preparing alkyl aromatic compounds. The process comprises contacting an alkane under dehydrogenation conditions in the presence of a dehydrogenation catalyst, e.g., a pincer iridium catalyst, to form olefins, and then contacting the olefins generated with an aromatic compound under alkylation conditions. Both reactions are conducted in a single reactor, and occur simultaneously.
摘要翻译： 提供了制备烷基芳族化合物的方法。 该方法包括在脱氢条件下在脱氢催化剂（例如pin铱催化剂）存在下使烷烃接触以形成烯烃，然后在烷基化条件下使与芳族化合物产生的烯烃接触。 两个反应都在单个反应器中进行，同时发生。
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公开(公告)号：US20130116492A1
公开(公告)日：2013-05-09
申请号：US13612599
申请日：2012-09-12
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C5/31 , C07C5/333 , C07C2529/70 , C07C2531/22 , C07C2531/24 , C07C15/44 , C07C15/02 , C07C13/48
摘要： Provided is a process for preparing alkyl aromatic compounds. The process comprises contacting an alkane under dehydrogenation conditions in the presence of a dehydrogenation catalyst, e.g., a pincer iridium catalyst, to form olefins, and then contacting the olefins generated with an aromatic compound under alkylation conditions. Both reactions are conducted in a single reactor, and occur simultaneously.
摘要翻译： 提供了制备烷基芳族化合物的方法。 该方法包括在脱氢条件下在脱氢催化剂（例如pin铱催化剂）存在下使烷烃接触以形成烯烃，然后在烷基化条件下使与芳族化合物产生的烯烃接触。 两个反应都在单个反应器中进行，同时发生。
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