公开(公告)号：US20050020778A1

公开(公告)日：2005-01-27

申请号：US10918906

申请日：2004-08-16

申请人： Alexander DeGroot ,  James Stevens ,  Sylvie Desjardins ,  Jeffrey Weinhold ,  Edmund Caenahan ,  David Gillespie ,  Daniel VanderLende

发明人： Alexander DeGroot ,  James Stevens ,  Sylvie Desjardins ,  Jeffrey Weinhold ,  Edmund Caenahan ,  David Gillespie ,  Daniel VanderLende

IPC分类号： C08F2/00 ,  C08F4/02 ,  C08F4/64 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F290/04 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/00

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2314/02 ,  C08L2314/06 ,  Y02P20/52 ,  Y10S526/943 ,  C08F2/001 ,  C08F4/65904 ,  C08F2/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2/00 ,  C08F2500/08 ,  C08F2500/05 ,  C08F2500/17 ,  C08F2500/26

摘要： A process of making a polymer is described. The process includes contacting one or more olefinic monomers in the presence of at least a high molecular weight (HMW) catalyst and at least a low molecular weight (LMW) catalyst in a polymerization reactor system; and effectuating the polymerization of the one or more olefinic monomers in the polymerization reactor system to obtain an olefin polymer, wherein the LMW catalyst has an RvL, defined as R v L = [ vinyl ] [ vinyl ] + [ vinylidene ] + [ cis ] + [ trans ] wherein [vinyl] is the concentration of vinyl groups in the olefin polymer produced by the low molecular weight catalyst expressed in vinyls/1,000 carbon atoms; [vinylidene], [cis] and [trans] are the concentration of vinylidene, cis and trans groups in the olefin polymer expressed in the number of the respective groups per 1,000 carbon atoms, of greater than 0.12, and wherein the HMW catalyst has a reactivity ratio, r1 of about 5 or less.

公开(公告)号：US20050065286A1

公开(公告)日：2005-03-24

申请号：US10920485

申请日：2004-08-17

申请人： Alexander DeGroot ,  James Stevens ,  Sylvie Desjardins ,  Jeffrey Weinhold ,  Edmund Carnahan ,  David Gillespie ,  Daniel Vanderlende

发明人： Alexander DeGroot ,  James Stevens ,  Sylvie Desjardins ,  Jeffrey Weinhold ,  Edmund Carnahan ,  David Gillespie ,  Daniel Vanderlende

IPC分类号： C08F2/00 ,  C08F4/02 ,  C08F4/64 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F290/04 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08F4/44

CPC分类号： C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2314/02 ,  C08L2314/06 ,  Y02P20/52 ,  Y10S526/943 ,  C08F2/001 ,  C08F4/65904 ,  C08F2/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2/00 ,  C08F2500/08 ,  C08F2500/05 ,  C08F2500/17 ,  C08F2500/26

摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: M ⁢   ⁢ S ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: M ⁢   ⁢ S ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.

公开(公告)号：US08901260B2

公开(公告)日：2014-12-02

申请号：US12750311

申请日：2010-03-30

申请人： Ayush A. Bafna ,  Mehmet Demirors ,  Sylvie Desjardins ,  Douglas S. Ginger ,  Colleen M. Tice ,  Terry A. Pearce

发明人： Ayush A. Bafna ,  Mehmet Demirors ,  Sylvie Desjardins ,  Douglas S. Ginger ,  Colleen M. Tice ,  Terry A. Pearce

IPC分类号： C08F210/16 ,  C08L23/08 ,  C08F4/60 ,  C08L23/06 ,  B32B7/02 ,  B32B27/32

CPC分类号： C08L23/06 ,  B32B7/02 ,  B32B27/32 ,  C08F210/16 ,  C08L23/0815 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/26

摘要： An interpolymer of ethylene and at least one alpha-olefin is claimed, wherein the ethylene interpolymer is characterized as having an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less then about 1.95 and wherein the interpolymer has a CDBI of less than 60%. The interpolymer of ethylene and at least one alpha-olefin can also be characterized as having a high density (HD) fraction and an overall density such that % HD fraction

摘要翻译： 要求保护乙烯和至少一种α-烯烃的互聚物，其中乙烯互聚物的特征在于具有平均Mv和互聚物与高结晶部分Thc之间的谷值温度，使得在Thc以上的馏分的平均Mv为 ATREF除以ATREF（Mhc / Mp）的全部聚合物的平均Mv小于约1.95，其中互聚物的CDBI小于60％。 乙烯和至少一种α-烯烃的互聚物也可以表征为具有高密度（HD）级分和总体密度，使得％HD分数<-2733.3 + 2988.7×+ 144111.5（x-0.92325）2，其中x为 密度以克/立方厘米计。 还公开了包含新型互聚物的制造物品。

公开(公告)号：US20140080970A1

公开(公告)日：2014-03-20

申请号：US14116070

申请日：2012-05-23

申请人： Sylvie Desjardins ,  Mehmet Demirors ,  Ellen Donkers ,  Manvel Fontaine ,  Cristina Serrat

发明人： Sylvie Desjardins ,  Mehmet Demirors ,  Ellen Donkers ,  Manvel Fontaine ,  Cristina Serrat

IPC分类号： C08F4/685

CPC分类号： C08F110/02 ,  C08F4/685 ,  C08F10/02 ,  C08F210/16 ,  C08F2410/03 ,  C08J5/18 ,  C08J2323/06 ,  D01F6/04 ,  C08F4/6341 ,  C08F4/6385 ,  C08F4/6374 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6357

摘要： Novel catalyst compositions comprising three or more transition metals are effective in increasing catalyst efficiency, reducing polydispersity, and increasing uniformity in molecular weight distribution when used in olefin, and particularly, linear low density polyethylene (LLDPE), polymerizations. The resulting polymers may be used to form differentiated products including, for example, films that may exhibit improved optical and mechanical properties.

摘要翻译： 包含三种或更多种过渡金属的新型催化剂组合物在用于烯烃，特别是线性低密度聚乙烯（LLDPE））聚合中时，有效地提高催化剂效率，降低多分散性和增加分子量分布的均匀性。 所得聚合物可用于形成分化产物，包括例如可能表现出改善的光学和机械性能的膜。

公开(公告)号：US08273449B2

公开(公告)日：2012-09-25

申请号：US12594963

申请日：2008-04-04

申请人： Sylvie Desjardins ,  Marc A. Springs ,  Phillip D. Hustad ,  Nathan J. Wiker ,  Jesus Nieto ,  Wayde V. Konze

发明人： Sylvie Desjardins ,  Marc A. Springs ,  Phillip D. Hustad ,  Nathan J. Wiker ,  Jesus Nieto ,  Wayde V. Konze

IPC分类号： C08F210/02 ,  B32B27/32

CPC分类号： C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08F4/52 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

摘要： The instant invention is a polyethylene film, and method of making the same. The polyethylene film according to instant invention includes at least one heterogeneously branched ethylene/α-olefin copolymer having a density in the range of about 0.910 to about 0.930 g/cm3, a molecular weight distribution in the range of about 2.8 to 3.8, a melt index (I2) in the range of about 0.3 to about 4 g/10 min, and an I10/I2 ratio in the range of 6.5 to about 7.8. The film has a normalized dart impact strength of equal or greater than (6666-7012*density) g/mil, a normalized tear strength of equal or greater than (440*e−(density−0.915)2/2*(0.00949)2) g/mil, and a haze in the range of 3 to 10 percent. The method of making the polyethylene film according to instant invention includes the following steps: (1) providing at least one heterogeneously branched ethylene/α-olefin copolymer having a density in the range of about 0.910 to about 0.930 g/cm3, a molecular weight distribution in the range of about 2.8 to 3.8, a melt index (I2) in the range of about 0.3 to about 4 g/10 min, and an I10/I2 ratio in the range of 6.5 to about 7.8; (2) processing the heterogeneously branched ethylene/α-olefin copolymer via blown film extrusion process or cast film extrusion process; and (3) thereby forming a film having a normalized dart impact strength of equal or greater than (6666-7012*density) g/mil, a normalized tear strength of equal or greater than (440*e−(density−0.915)2/2*(0.00949)2) g/mil, and a haze in the range of 3 to 10 percent.

摘要翻译： 本发明是一种聚乙烯薄膜及其制造方法。 根据本发明的聚乙烯膜包括至少一种非均相支化的乙烯/α-烯烃共聚物，其密度在约0.910至约0.930g / cm 3范围内，分子量分布在约2.8至3.8的范围内，熔体 指数（I 2）在约0.3至约4g / 10min的范围内，I10 / I2比在6.5至约7.8的范围内。 标准化的落镖冲击强度等于或大于（6666-7012 *密度）g / mil，归一化的撕裂强度等于或大于（440 * e-（密度-0.915）2/2 *（0.00949） 2）g / mil，雾度在3％至10％的范围内。 根据本发明的制备聚乙烯膜的方法包括以下步骤：（1）提供至少一种密度在约0.910至约0.930g / cm 3范围内的非均匀支化的乙烯/α-烯烃共聚物，分子量 分布在约2.8至3.8的范围内，熔体指数（I 2）在约0.3至约4g / 10min的范围内，I10 / I2比在6.5至约7.8的范围内; （2）通过吹膜挤出法或流延膜挤出法处理非均匀支化的乙烯/α-烯烃共聚物; （3），由此形成具有等于或大于（6666-7012 *密度）g / mil的标准化落镖冲击强度的膜，标准化的撕裂强度等于或大于（440 * e-（密度-0.915）2 /2*(0.00949)2）g / mil，雾度在3％到10％的范围内。

公开(公告)号：US20100119793A1

公开(公告)日：2010-05-13

申请号：US12594963

申请日：2008-04-04

申请人： Sylvie Desjardins ,  Marc A. Springs ,  Phillip D. Hustad ,  Nathan J. Wiker ,  Jesus Nieto ,  Wayde V. Konze

发明人： Sylvie Desjardins ,  Marc A. Springs ,  Phillip D. Hustad ,  Nathan J. Wiker ,  Jesus Nieto ,  Wayde V. Konze

IPC分类号： B32B27/32 ,  C08F210/02 ,  C08F210/14 ,  B29C47/14

CPC分类号： C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08F4/52 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

摘要： The instant invention is a polyethylene film, and method of making the same. The polyethylene film according to instant invention includes at least one heterogeneously branched ethylene/α-olefin copolymer having a density in the range of about 0.910 to about 0.930 g/cm3, a molecular weight distribution in the range of about 2.8 to 3.8, a melt index (I2) in the range of about 0.3 to about 4 g/10 min, and an I10/I2 ratio in the range of 6.5 to about 7.8. The film has a normalized dart impact strength of equal or greater than (6666-7012*density) g/mil, a normalized tear strength of equal or greater than (440*e−(density−0.915)2/2*(0.00949)2) g/mil, and a haze in the range of 3 to 10 percent. The method of making the polyethylene film according to instant invention includes the following steps: (1) providing at least one heterogeneously branched ethylene/α-olefin copolymer having a density in the range of about 0.910 to about 0.930 g/cm3, a molecular weight distribution in the range of about 2.8 to 3.8, a melt index (I2) in the range of about 0.3 to about 4 g/10 min, and an I10/I2 ratio in the range of 6.5 to about 7.8; (2) processing the heterogeneously branched ethylene/α-olefin copolymer via blown film extrusion process or cast film extrusion process; and (3) thereby forming a film having a normalized dart impact strength of equal or greater than (6666-7012*density) g/mil, a normalized tear strength of equal or greater than (440*e−(density−0.915)2/2*(0.00949)2) g/mil, and a haze in the range of 3 to 10 percent.

摘要翻译： 本发明是一种聚乙烯薄膜及其制造方法。 根据本发明的聚乙烯膜包括至少一种非均相支化的乙烯/α-烯烃共聚物，其密度在约0.910至约0.930g / cm 3范围内，分子量分布在约2.8至3.8的范围内，熔体 指数（I 2）在约0.3至约4g / 10min的范围内，I10 / I2比在6.5至约7.8的范围内。 标准化的落镖冲击强度等于或大于（6666-7012 *密度）g / mil，归一化的撕裂强度等于或大于（440 * e-（密度-0.915）2/2 *（0.00949） 2）g / mil，雾度在3％至10％的范围内。 根据本发明的制备聚乙烯膜的方法包括以下步骤：（1）提供至少一种密度在约0.910至约0.930g / cm 3范围内的非均匀支化的乙烯/α-烯烃共聚物，分子量 分布在约2.8至3.8的范围内，熔体指数（I 2）在约0.3至约4g / 10min的范围内，I10 / I2比在6.5至约7.8的范围内; （2）通过吹膜挤出法或流延膜挤出法处理非均匀支化的乙烯/α-烯烃共聚物; （3），由此形成具有等于或大于（6666-7012 *密度）g / mil的标准化落镖冲击强度的膜，标准化的撕裂强度等于或大于（440 * e-（密度-0.915）2 /2*(0.00949)2）g / mil，雾度在3％到10％的范围内。

公开(公告)号：US09255160B2

公开(公告)日：2016-02-09

申请号：US14116070

申请日：2012-05-23

申请人： Sylvie Desjardins ,  Mehmet Demirors ,  Ellen Donkers ,  Philip P. Fontaine ,  Cristina Serrat

发明人： Sylvie Desjardins ,  Mehmet Demirors ,  Ellen Donkers ,  Philip P. Fontaine ,  Cristina Serrat

IPC分类号： C08F4/685 ,  C08F10/02 ,  C08F210/16

CPC分类号： C08F110/02 ,  C08F4/685 ,  C08F10/02 ,  C08F210/16 ,  C08F2410/03 ,  C08J5/18 ,  C08J2323/06 ,  D01F6/04 ,  C08F4/6341 ,  C08F4/6385 ,  C08F4/6374 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/6357

摘要： Novel catalyst compositions comprising three or more transition metals are effective in increasing catalyst efficiency, reducing polydispersity, and increasing uniformity in molecular weight distribution when used in olefin, and particularly, linear low density polyethylene (LLDPE), polymerizations. The resulting polymers may be used to form differentiated products including, for example, films that may exhibit improved optical and mechanical properties.

摘要翻译： 包含三种或更多种过渡金属的新型催化剂组合物在用于烯烃，特别是线性低密度聚乙烯（LLDPE））聚合中时，有效地提高催化剂效率，降低多分散性和增加分子量分布的均匀性。 所得聚合物可用于形成分化产物，包括例如可能表现出改善的光学和机械性能的膜。

公开(公告)号：US20100324202A1

公开(公告)日：2010-12-23

申请号：US12750311

申请日：2010-03-30

申请人： Ayush A. Bafna ,  Mehmet Demirors ,  Sylvie Desjardins ,  Douglas S. Ginger ,  Colleen M. Tice ,  Terry A. Pearce

发明人： Ayush A. Bafna ,  Mehmet Demirors ,  Sylvie Desjardins ,  Douglas S. Ginger ,  Colleen M. Tice ,  Terry A. Pearce

IPC分类号： C08L23/08 ,  C08F210/02 ,  C08F4/12 ,  C08F4/50

CPC分类号： C08L23/06 ,  B32B7/02 ,  B32B27/32 ,  C08F210/16 ,  C08L23/0815 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/26

摘要： An interpolymer of ethylene and at least one alpha-olefin is claimed, wherein the ethylene interpolymer is characterized as having an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less then about 1.95 and wherein the interpolymer has a CDBI of less than 60%. The interpolymer of ethylene and at least one alpha-olefin can also be characterized as having a high density (HD) fraction and an overall density such that % HD fraction

摘要翻译： 要求保护乙烯和至少一种α-烯烃的互聚物，其中乙烯互聚物的特征在于具有平均Mv和互聚物与高结晶部分Thc之间的谷值温度，使得在Thc以上的馏分的平均Mv为 ATREF除以ATREF（Mhc / Mp）的全部聚合物的平均Mv小于约1.95，其中互聚物的CDBI小于60％。 乙烯和至少一种α-烯烃的互聚物也可以表征为具有高密度（HD）级分和总体密度，使得％HD分数<-2733.3 + 2988.7×+ 144111.5（x-0.92325）2，其中x为 密度以克/立方厘米计。 还公开了包含新型互聚物的制造物品。

公开(公告)号：US20080306217A1

公开(公告)日：2008-12-11

申请号：US12159514

申请日：2006-12-12

申请人： Teresa P. Karjala ,  Selim Yalvac ,  Cynthia L. Rickey ,  Sylvie Desjardins ,  Marc A. Springs

发明人： Teresa P. Karjala ,  Selim Yalvac ,  Cynthia L. Rickey ,  Sylvie Desjardins ,  Marc A. Springs

IPC分类号： C08F210/02 ,  C08L23/08 ,  C08L23/16 ,  C08F10/14 ,  C08F10/08 ,  C08L31/00 ,  C08L35/00 ,  C08L45/00 ,  C08L33/24 ,  C08L33/02 ,  C08L35/02 ,  C08L43/04 ,  C08L39/04 ,  C08L37/00 ,  C08L33/20

CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08L23/0815 ,  C08L51/06 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08L2314/06 ,  C08F4/64 ,  C08L2666/24 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/01 ,  C08F4/64079 ,  C08F4/64013

摘要： The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.

摘要翻译： 本发明提供包含一种或多种乙烯互聚物，并且其中互聚物或组合物在177℃下的熔体粘度为1至30,000cP，并且其中至少一种乙烯互聚物的Rv为0.3-0.99。 本发明还提供包含至少一种低分子量（LMW）乙烯互聚物和至少一种高分子量（HMW）乙烯互聚物的组合物，并且其中该组合物在177℃具有1至30,000cP的熔体粘度 ，并且其中来自低分子量互聚物和高分子量互聚物的Rv的总和为0.3至2.本发明还提供了制备这种组合物的方法，使这种组合物的互聚物官能化的方法，以及 包含由本发明组合物制备的至少一种组分的制品。

公开(公告)号：US20120041148A1

公开(公告)日：2012-02-16

申请号：US13262554

申请日：2010-03-30

申请人： Ayush A. Bafna ,  Mehmet Demirors ,  Sylvie Desjardins ,  Douglas S. Ginger ,  Colleen M. Tice ,  Terry A. Pearce

发明人： Ayush A. Bafna ,  Mehmet Demirors ,  Sylvie Desjardins ,  Douglas S. Ginger ,  Colleen M. Tice ,  Terry A. Pearce

IPC分类号： C08F210/02 ,  C08F4/42 ,  C08F4/12 ,  C08L23/04 ,  C08L23/06

CPC分类号： C08L23/06 ,  B32B7/02 ,  B32B27/32 ,  C08F210/16 ,  C08L23/0815 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/26

摘要： An interpolymer of ethylene and at least one alpha-olefin is claimed, wherein the ethylene interpolymer is characterized as having an average Mv and a valley temperature between the interpolymer and high crystalline fraction, Thc, such that the average Mv for a fraction above Thc from ATREF divided by average Mv of the whole polymer from ATREF (Mhc/Mp) is less then about 1.95 and wherein the interpolymer has a CDBI of less than 60%. The interpolymer of ethylene and at least one alpha-olefin can also be characterized as having a high density (HD) fraction and an overall density such that % HD fraction

摘要翻译： 要求保护乙烯和至少一种α-烯烃的互聚物，其中乙烯互聚物的特征在于具有平均Mv和互聚物与高结晶部分Thc之间的谷值温度，使得在Thc以上的馏分的平均Mv为 ATREF除以ATREF（Mhc / Mp）的全部聚合物的平均Mv小于约1.95，其中互聚物的CDBI小于60％。 乙烯和至少一种α-烯烃的互聚物也可以表征为具有高密度（HD）级分和总体密度，使得％HD分数<-2733.3 + 2988.7×+ 144111.5（x-0.92325）2，其中x为 密度以克/立方厘米计。 还公开了包含新型互聚物的制造物品。