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    Biomass Compositions for Catalytic Gasification
    4.
    发明申请
    Biomass Compositions for Catalytic Gasification 有权
    用于催化气化的生物质组合物

    公开(公告)号：US20090217587A1

    公开(公告)日：2009-09-03

    申请号：US12395447

    申请日：2009-02-27

    申请人： Pattabhi K. Raman ,  Edwin J. Hippo ,  Nelson Yee

    发明人： Pattabhi K. Raman ,  Edwin J. Hippo ,  Nelson Yee

    IPC分类号： C10L3/00 ,  B01J27/20

    CPC分类号： C10L5/44 ,  C10J3/482 ,  C10J3/54 ,  C10J2300/0903 ,  C10J2300/0916 ,  C10J2300/0943 ,  C10J2300/0986 ,  C10L1/326 ,  C10L5/04 ,  Y02E50/10 ,  Y02E50/30 ,  Y02P20/145 ,  Y02P20/52

    摘要： Particulate compositions are described comprising an intimate mixture of a biomass, such as switchgrass or hybrid poplar, a non-biomass carbonaceous material, such as petroleum coke or coal, and a gasification catalyst, where the gasification catalyst is loaded onto at least one of the biomass or non-biomass for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.

    摘要翻译： 描述了颗粒组合物，其包括生物质如柳枝稷或混合杨树的紧密混合物，非生物质碳质材料如石油焦炭或煤和气化催化剂，其中气化催化剂被加载到至少一个 生物质或非生物质用于在蒸汽存在下气化以形成包括甲烷在内的多种气体，并且形成至少一种或多种氢，一氧化碳和其它高级烃。 还提供了用于制备颗粒组合物并将颗粒组合物转化为多种气态产物的方法。

    Hydrogenation of coal and subsequent liquefaction of hydrogenated undissolved coal
    5.
    发明授权
    Hydrogenation of coal and subsequent liquefaction of hydrogenated undissolved coal 失效
    煤的氢化和随后的氢化未溶解煤的液化

    公开(公告)号：US4879021A

    公开(公告)日：1989-11-07

    申请号：US237636

    申请日：1988-08-26

    申请人： Edwin J. Hippo ,  Alfred G. Comolli ,  Robert O'Brien

    发明人： Edwin J. Hippo ,  Alfred G. Comolli ,  Robert O'Brien

    IPC分类号： C10G1/00 ,  C10G1/08 ,  F02B3/06

    CPC分类号： C10G1/006 ,  C10G1/083 ,  C10G1/086 ,  F02B3/06

    摘要： A process for the hydrogenation of undissolved coal and subsequent liquefaction of the hydrogenated coal particles to provide useful hydrocarbon liquid products including naphtha, gasoline and diesel fuel. These low boiling hydrocarbon liquids are produced by the process comprising: (a) mixing solid coal particles with a coal derived solvent in a solvent/coal ratio ranging from about 8/1 to about 1.5/1 to provide a flowable coal/oil slurry of solid coal particles; (b) passing the coal/oil slurry and hydrogen upwardly through a first reaction zone containing a coal-derived liquid and bed of particulate catalyst maintained at a temperature ranging from about 400.degree. to about 700.degree. F. and a hydrogen partial pressure of 100 to 2000 psig for a time sufficient to hydrogenate the solid coal particles; and (c) withdrawing the coal/oil slurry having the hydrogenated coal particles from the first reaction zone and passing the coal/oil slurry to a second reaction zone containing a catalytic bed which is maintained at a temperature of between about 700.degree. and about 850.degree. F. and a hydrogen partial pressure of 9 to 2000 psig to liquefy and convert the coal to useful hydrocarbon liquid fuel products. The first and second reaction zones may include the same or different catalysts such as Co/Mo on a porous substrate, or the second reaction zone can include a noble metal such as platinum on a porous substrate such as alumina or silica.

    摘要翻译： 一种氢化未溶解煤的方法，随后液化氢化煤颗粒以提供有用的烃液体产物，包括石脑油，汽油和柴油。 这些低沸点烃液体通过以下方法制备，该方法包括：（a）将固体煤颗粒与来自煤的溶剂以约8/1至约1.5/1的溶剂/煤比混合，以提供可流动的煤/油浆 固体煤颗粒; （b）将煤/油浆和氢气向上通过包含煤源液体的第一反应区和保持在约400至约700°F温度范围内的颗粒催化剂床和氢分压为100 至2000psig一段足以使固体煤颗粒氢化的时间; 和（c）从第一反应区取出具有氢化煤粒子的煤/油浆料，并将煤/油浆料送入含有催化床的第二反应区，该反应区保持在约700℃至约850℃之间的温度 DEG，氢分压为9-2000psig，将煤液化并转化为有用的烃类液体燃料产品。 第一反应区和第二反应区可以包括相同或不同的催化剂，例如多孔基材上的Co / Mo，或者第二反应区可以在多孔基材如氧化铝或二氧化硅上包括贵金属如铂。

    Coal catalytic hydrogenation process using direct coal slurry feed to reactor with controlled mixing conditions
    6.
    发明授权
    Coal catalytic hydrogenation process using direct coal slurry feed to reactor with controlled mixing conditions 失效
    煤催化加氢工艺，使用直接煤浆进料到具有受控混合条件的反应器

    公开(公告)号：US4495055A

    公开(公告)日：1985-01-22

    申请号：US574223

    申请日：1984-01-26

    申请人： Alfred G. Comolli ,  Edwin J. Hippo

    发明人： Alfred G. Comolli ,  Edwin J. Hippo

    IPC分类号： C10G1/06 ,  C10G1/08

    CPC分类号： C10G1/083

    摘要： A process for improved catalytic hydrogenation of coal to produce increased yields of low boiling hydrocarbon liquids and gas products, in which a coal-oil slurry is fed directly with only limited preheating into an ebullated bed catalytic reaction zone to provide increased hydroconversion and improved yields of low boiling hydrocarbon liquids. In the process, a coal is slurried with a hydrogenated coal-derived liquid and heated to only a limited extent, as defined by a temperature-time severity unit index (STTU) less than about 0.1, so as to avoid depleting the hydrogen donor capacity of the solvent liquid, and the slurry is then fed directly into an ebullated bed catalytic reaction zone maintained at 650.degree.-900.degree. F. temperature and 1000-5000 psi hydrogen partial pressure. Supplemental heat is provided to the reaction zone as needed by heating recycled reactor liquid and recycled hydrogen streams to temperatures above the reaction zone temperature. If desired, effluent liquid from the reaction zone can be advantageously passed with hydrogen to a second ebullated bed catalytic reaction zone for further hydrogentation reaction at different severity selected to provide increased conversion of the coal and coal derived liquids and produce increased yields and/or improved selectivity of light hydrocarbon liquid products.

    摘要翻译： 一种用于改进煤的催化氢化以产生低沸点烃液体和气体产物的产率的方法，其中将煤油浆料直接进料至有限的预热进入沸腾床催化反应区域以提供增加的加氢转化率和提高的产率 低沸点烃类液体。 在此过程中，煤与氢化的煤衍生液体一起制浆，只有在温度 - 时间苛刻度单位指数（STTU）小于约0.1的限定范围内加热至有限程度，以避免耗尽氢气供体的能力 的溶剂液体，然后将浆料直接进料到保持在650-900°F温度和1000-5000psi氢分压的沸腾床催化反应区中。 通过将再循环的反应器液体和再循环的氢气流加热到高于反应区温度的温度，根据需要将补充的热量提供给反应区。 如果需要，来自反应区的流出液体可以有利地通过氢气到达第二沸腾床催化反应区域，用于进一步加氢反应，以选择不同的严重程度来提供煤和煤得到的液体的增加的转化率并产生增加的产率和/或改进 轻烃液体产品的选择性。