公开(公告)号：US06350717B1

公开(公告)日：2002-02-26

申请号：US09385458

申请日：1999-08-30

申请人： Andrea Frenzel ,  Cristina Freire Erdbrügger ,  Ekkehard Schwab ,  Michael Hesse ,  Gerd Linden ,  Herbert Wanjek ,  Hans-Martin Allmann

发明人： Andrea Frenzel ,  Cristina Freire Erdbrügger ,  Ekkehard Schwab ,  Michael Hesse ,  Gerd Linden ,  Herbert Wanjek ,  Hans-Martin Allmann

IPC分类号： B01J2358

CPC分类号： C07C7/163 ,  B01J23/44 ,  B01J23/50 ,  B01J37/0201 ,  C07C5/05 ,  C07C5/09 ,  C07C2523/44 ,  C07C2523/50 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/04

摘要： A catalyst comprising at least one metal of the 10th group of the Periodic Table of the Elements and at least one metal of the 11th group of the Periodic Table of the Elements on an aluminum oxide support, wherein the metal or metals of the 10th group is or are essentially concentrated in an outer layer close to the surface of the catalyst particle, the metal or metals of the 11th group is or are distributed essentially uniformly over the volume of the catalyst particle and the weight ratio of the metal or metals of the 11th group to the metal or metals of the 10th group is not more than 1.95.

摘要翻译： 一种催化剂，其包含元素周期表第10族中的至少一种金属和氧化铝载体上元素周期表第11族的至少一种金属，其中第10族的金属或金属为 或基本上集中在接近催化剂颗粒表面的外层中，第11组的金属或金属基本均匀地分布在催化剂颗粒的体积上，并且第11位的金属或金属的重量比 第10组金属或金属组不超过1.95。

公开(公告)号：US08492566B2

公开(公告)日：2013-07-23

申请号：US12936807

申请日：2009-04-07

申请人： Hagen Wilmer ,  Jürgen Zühlke ,  Thomas Lautensack ,  Hans-Martin Allmann ,  Frank Rosowski ,  Cornelia Katharina Dobner

发明人： Hagen Wilmer ,  Jürgen Zühlke ,  Thomas Lautensack ,  Hans-Martin Allmann ,  Frank Rosowski ,  Cornelia Katharina Dobner

IPC分类号： C07D307/89

CPC分类号： C07C51/265 ,  C07D307/89

摘要： What is described is a process for starting up a gas phase oxidation reactor for oxidation of o-xylene to phthalic anhydride, said reactor comprising at least one catalyst layer and being temperature-controllable by means of a heat carrier medium, wherein a) the catalyst layer is interrupted by a moderator layer which is less catalytically active than the catalyst layer or is catalytically inactive, b) a gas stream is passed through the reactor with an initial loading of o-xylene and at an initial temperature of the heat transfer medium, c) the loading of the gas stream is increased to a target loading and, in parallel, the temperature of the heat transfer medium is lowered to an operating temperature. The introduction of the moderator layer allows the loading to be increased more rapidly and the startup time to be shortened.

摘要翻译： 描述的是用于启动用于将邻二甲苯氧化成邻苯二甲酸酐的气相氧化反应器的方法，所述反应器包括至少一个催化剂层，并且可通过热载体介质温度控制，其中a）催化剂 层被催化剂层催化活性较低或催化无活性的中间体层中断，b）气流以邻二甲苯的初始负荷和传热介质的初始温度通过反应器， c）将气流的负载增加到目标负载，并且并联地将传热介质的温度降低到工作温度。 调节器层的引入允许加载更快速并且启动时间被缩短。

公开(公告)号：US20080312450A1

公开(公告)日：2008-12-18

申请号：US11994516

申请日：2006-06-30

申请人： Samuel Neto ,  Frank Rosowski ,  Sebastian Storck ,  Juergen Zuehlke ,  Hans-Martin Allmann ,  Thomas Lautensack ,  Rainer Steeg

发明人： Samuel Neto ,  Frank Rosowski ,  Sebastian Storck ,  Juergen Zuehlke ,  Hans-Martin Allmann ,  Thomas Lautensack ,  Rainer Steeg

IPC分类号： C07D213/79 ,  C07C27/10 ,  C07D307/60 ,  C07D307/89 ,  C07C51/16

CPC分类号： C07D307/34 ,  B01J23/002 ,  B01J2523/00 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/824

摘要： Methods comprising: providing an oxidation catalyst bed; and starting up the oxidation catalyst at a temperature of 360° C. to 400° C. with an amount of air of 1.0 to 3.5 standard m3/h and a hydrocarbon loading of 20 to 65 g/standard m3, such that a hot spot having a temperature of 390° C. to

摘要翻译： 方法包括：提供氧化催化剂床; 并在360℃至400℃的温度下启动氧化催化剂，空气量为1.0-3.5标准立方米/小时，烃装载量为20至65克/标准立方米，使得热点 在催化剂床的前7-20％中形成温度为390℃至<450℃的温度。

公开(公告)号：US08263789B2

公开(公告)日：2012-09-11

申请号：US12520648

申请日：2007-12-12

申请人： Hagen Wilmer ,  Jürgen Zühlke ,  Thomas Lautensack ,  Hans-Martin Allmann ,  Frank Rosowski ,  Cornelia Dobner

发明人： Hagen Wilmer ,  Jürgen Zühlke ,  Thomas Lautensack ,  Hans-Martin Allmann ,  Frank Rosowski ,  Cornelia Dobner

IPC分类号： C07D307/89

CPC分类号： B01J8/067 ,  B01J8/0496 ,  B01J23/002 ,  B01J35/0006 ,  B01J35/026 ,  B01J2208/024 ,  B01J2208/025 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16

摘要： The present invention relates to a process for gas-phase oxidation, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed through two or more catalyst zones. Furthermore, the present invention relates to a catalyst system for gas-phase reaction using a preliminary zone.

摘要翻译： 本发明涉及一种气相氧化方法，其中包含芳烃和分子氧的气流通过两个或多个催化剂区。 此外，本发明涉及使用预备区域进行气相反应的催化剂体系。

公开(公告)号：US20090286999A1

公开(公告)日：2009-11-19

申请号：US12296885

申请日：2007-04-05

申请人： Hagen Wilmer ,  Cornelia Dobner ,  Frank Rosowski ,  Jürgen Zühlke ,  Sebastian Storck ,  Hans-Martin Allmann ,  Thomas Lautensack

发明人： Hagen Wilmer ,  Cornelia Dobner ,  Frank Rosowski ,  Jürgen Zühlke ,  Sebastian Storck ,  Hans-Martin Allmann ,  Thomas Lautensack

IPC分类号： C07D307/89 ,  B01J8/04 ,  C07C51/21

CPC分类号： B01J23/002 ,  B01J23/22 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/1004 ,  B01J2523/00 ,  C07C51/265 ,  C07C51/313 ,  C07D307/89 ,  C07C63/16 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/53

摘要： The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides which has at least three catalyst layers arranged one on top of the other in the reaction tube, with the proviso that the most inactive catalyst layer is preceded in the upstream direction by a more active catalyst layer. The invention further relates to a process for gas phase oxidation in which a gaseous stream which comprises one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers, the least active catalyst layer being upstream of a more active catalyst layer.

摘要翻译： 本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂体系，其具有在反应管中一个在另一个上排列的至少三个催化剂层，条件是最不活泼的催化剂层在上游 方向通过更活泼的催化剂层。 本发明还涉及一种用于气相氧化的方法，其中包含一种烃和分子氧的气流通过多个催化剂层，最少活性催化剂层位于较活泼的催化剂层的上游。

公开(公告)号：US5856262A

公开(公告)日：1999-01-05

申请号：US711904

申请日：1996-09-12

申请人： Klemens Flick ,  Christof Herion ,  Hans-Martin Allmann

发明人： Klemens Flick ,  Christof Herion ,  Hans-Martin Allmann

IPC分类号： B01J23/48 ,  B01J23/58 ,  B01J23/60 ,  B01J23/89 ,  B01J37/02 ,  C07B61/00 ,  C07C5/08 ,  C07C7/167 ,  C07C11/04 ,  C07C11/24 ,  B01J21/08

CPC分类号： B01J23/58 ,  B01J37/0205 ,  C07C7/167 ,  C07C2521/08 ,  C07C2523/44

摘要： A silica-supported catalyst suitable for the selective hydrogenation of acetylene in hydrocarbonaceous streams, comprising from 0.001 to 1% by weight, based on the supported catalyst, of palladium and from 0.005 to 5% by weight, based on the supported catalyst, of at least one promoter metal of groups 1 and 2 of the periodic table, obtainable by impregnating a silica support with a solution comprising at least one promoter metal, drying the impregnated support, impregnating with a palladium-including solution, drying and calcining.

摘要翻译： 一种二氧化硅负载的催化剂，适用于烃类物流中的乙炔的选择性氢化，其中负载型催化剂为0.001-1％（重量），以负载型催化剂为基准，为0.005〜5％ 通过用包含至少一种促进剂金属的溶液浸渍二氧化硅载体，干燥浸渍的载体，用含钯溶液浸渍，干燥和煅烧而获得的元素周期表第1和2族的至少一种促进剂金属。

公开(公告)号：US5847250A

公开(公告)日：1998-12-08

申请号：US984844

申请日：1997-12-04

申请人： Klemens Flick ,  Christof Herion ,  Hans-Martin Allmann

发明人： Klemens Flick ,  Christof Herion ,  Hans-Martin Allmann

IPC分类号： B01J23/48 ,  B01J23/58 ,  B01J23/60 ,  B01J23/89 ,  B01J37/02 ,  C07B61/00 ,  C07C5/08 ,  C07C7/167 ,  C07C11/04 ,  C07C11/24

CPC分类号： B01J23/58 ,  B01J37/0205 ,  C07C7/167 ,  C07C2521/08 ,  C07C2523/44

摘要： A silica-supported catalyst suitable for the selective hydrogenation of acetylene in hydrocarbonaceous streams, comprising from 0.001 to 1% by weight, based on the supported catalyst, of palladium and from 0.005 to 5% by weight, based on the supported catalyst, of at least one promoter metal of groups 1 and 2 of the periodic table, obtainable by impregnating a silica support with a solution comprising at least one promoter metal, drying the impregnated support, impregnating with a palladium-including solution, drying and calcining.

公开(公告)号：US20110034707A1

公开(公告)日：2011-02-10

申请号：US12936807

申请日：2009-04-07

申请人： Hagen Wilmer ,  Zürgen Zühike ,  Thomas Lautensack ,  Hans-Martin Allmann ,  Frank Rosowski ,  Cornelia Katharina Dobner

发明人： Hagen Wilmer ,  Zürgen Zühike ,  Thomas Lautensack ,  Hans-Martin Allmann ,  Frank Rosowski ,  Cornelia Katharina Dobner

IPC分类号： C07D307/89

CPC分类号： C07C51/265 ,  C07D307/89

摘要： What is described is a process for starting up a gas phase oxidation reactor for oxidation of o-xylene to phthalic anhydride, said reactor comprising at least one catalyst layer and being temperature-controllable by means of a heat carrier medium, wherein a) the catalyst layer is interrupted by a moderator layer which is less catalytically active than the catalyst layer or is catalytically inactive, b) a gas stream is passed through the reactor with an initial loading of o-xylene and at an initial temperature of the heat transfer medium, c) the loading of the gas stream is increased to a target loading and, in parallel, the temperature of the heat transfer medium is lowered to an operating temperature. The introduction of the moderator layer allows the loading to be increased more rapidly and the startup time to be shortened.

摘要翻译： 描述的是用于启动用于将邻二甲苯氧化成邻苯二甲酸酐的气相氧化反应器的方法，所述反应器包括至少一个催化剂层，并且可通过热载体介质温度控制，其中a）催化剂 层被催化剂层催化活性较低或催化无活性的中间体层中断，b）气流以邻二甲苯的初始负荷和传热介质的初始温度通过反应器， c）将气流的负载增加到目标负载，并且并联地将传热介质的温度降低到工作温度。 调节器层的引入允许加载更快速并且启动时间被缩短。

公开(公告)号：US20090171101A1

公开(公告)日：2009-07-02

申请号：US12298453

申请日：2007-04-27

申请人： Thomas Lautensack ,  Hans-Martin Allmann ,  Hagen Wilmer

发明人： Thomas Lautensack ,  Hans-Martin Allmann ,  Hagen Wilmer

IPC分类号： C07D307/89

CPC分类号： B01J35/0006 ,  B01J23/002 ,  B01J23/22 ,  B01J2523/00 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/15 ,  B01J2523/47

摘要： A process for gas phase oxidation in which a gaseous stream which comprises at least one aromatic hydrocarbon and molecular oxygen is passed through one or more catalyst layers, wherein a moderator layer is arranged between two catalyst layers arranged in succession in flow direction of the gaseous stream, the moderator layer being less catalytically active than the catalysts adjacent upstream and downstream or being catalytically inactive. The desired oxidation products are obtained in high yield over prolonged periods.

摘要翻译： 一种用于气相氧化的方法，其中包含至少一种芳族烃和分子氧的气态物流通过一个或多个催化剂层，其中调节剂层布置在连续排列在气流的流动方向上的两个催化剂层之间 ，慢化剂层比邻近上游和下游的催化剂具有较低的催化活性，或者是催化无活性的。 在长时间内以高产率获得所需的氧化产物。

公开(公告)号：US20080200685A1

公开(公告)日：2008-08-21

申请号：US11916731

申请日：2006-05-31

申请人： Samuel Neto ,  Frank Rosowski ,  Sebastian Storck ,  Jurgen Zuhlke ,  Hans-Martin Allmann ,  Thomas Lautensack ,  Rainer Steeg

发明人： Samuel Neto ,  Frank Rosowski ,  Sebastian Storck ,  Jurgen Zuhlke ,  Hans-Martin Allmann ,  Thomas Lautensack ,  Rainer Steeg

IPC分类号： B01J37/08 ,  C07C51/16 ,  C07D307/34 ,  C07D307/89 ,  C07D211/00

CPC分类号： B01J37/0018 ,  B01J23/22 ,  B01J37/0219 ,  B01J37/0221 ,  B01J37/14 ,  C07C51/265 ,  C07C63/16

摘要： Processes comprising providing a catalyst precursor, and heating the catalyst precursor to a temperature of at least 350° C. in an atmosphere comprising air, wherein air is fed into the atmosphere at a rate of 0.05 to 4.0 standard m3/h, and wherein the catalyst precursor is activated at a temperature of at least 350° C. for more than 9 hours are described along with catalysts formed thereby and uses for such catalysts.

摘要翻译： 方法包括提供催化剂前体，并将催化剂前体在包含空气的气氛中加热到至少350℃的温度，其中空气以0.05至4.0标准m 3的速率进料到大气中， SUP> / h，并且其中催化剂前体在至少350℃的温度下活化超过9小时，以及由此形成的催化剂被描述并用于这种催化剂。