公开(公告)号：US06350717B1

公开(公告)日：2002-02-26

申请号：US09385458

申请日：1999-08-30

申请人： Andrea Frenzel ,  Cristina Freire Erdbrügger ,  Ekkehard Schwab ,  Michael Hesse ,  Gerd Linden ,  Herbert Wanjek ,  Hans-Martin Allmann

发明人： Andrea Frenzel ,  Cristina Freire Erdbrügger ,  Ekkehard Schwab ,  Michael Hesse ,  Gerd Linden ,  Herbert Wanjek ,  Hans-Martin Allmann

IPC分类号： B01J2358

CPC分类号： C07C7/163 ,  B01J23/44 ,  B01J23/50 ,  B01J37/0201 ,  C07C5/05 ,  C07C5/09 ,  C07C2523/44 ,  C07C2523/50 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/04

摘要： A catalyst comprising at least one metal of the 10th group of the Periodic Table of the Elements and at least one metal of the 11th group of the Periodic Table of the Elements on an aluminum oxide support, wherein the metal or metals of the 10th group is or are essentially concentrated in an outer layer close to the surface of the catalyst particle, the metal or metals of the 11th group is or are distributed essentially uniformly over the volume of the catalyst particle and the weight ratio of the metal or metals of the 11th group to the metal or metals of the 10th group is not more than 1.95.

摘要翻译： 一种催化剂，其包含元素周期表第10族中的至少一种金属和氧化铝载体上元素周期表第11族的至少一种金属，其中第10族的金属或金属为 或基本上集中在接近催化剂颗粒表面的外层中，第11组的金属或金属基本均匀地分布在催化剂颗粒的体积上，并且第11位的金属或金属的重量比 第10组金属或金属组不超过1.95。

公开(公告)号：US5128307A

公开(公告)日：1992-07-07

申请号：US649299

申请日：1991-01-30

申请人： Herbert Wanjek ,  Claus Witte ,  Michael J. Sprague ,  Matthias Irgang ,  Wolfgang Hoelderich ,  Wolf D. Mross

发明人： Herbert Wanjek ,  Claus Witte ,  Michael J. Sprague ,  Matthias Irgang ,  Wolfgang Hoelderich ,  Wolf D. Mross

IPC分类号： B01J23/72 ,  B01J23/80 ,  B01J35/10 ,  C01B3/16

CPC分类号： B01J37/031 ,  B01J23/72 ,  B01J23/80 ,  B01J35/1014 ,  B01J35/1019 ,  C01B3/16 ,  Y02P20/52

摘要： Copper-containing catalysts for low temperature shift conversion at from 150.degree. to 300.degree. C. and under from 10 to 40 bar, which additionally contain aluminum and zinc, if necessary in the form of the compounds or oxides and are prepared by coprecipitation, the copper-containing catalysts containing potassium and having a BET surface area adapted to the potassium content, and the potassium content being brought to 0.1-3.0% by weight at a BET surface of from 30 to 160 m.sup.2 /g, are used for the preparation of hydrogen and carbon dioxide from carbon monoxide and water.

摘要翻译： 在150〜300℃，10〜40巴下进行低温转化转化的含铜催化剂，如果需要，还含有铝和锌，如果需要，可以以化合物或氧化物的形式，通过共沉淀制备 含有钾的具有适合于钾含量的BET表面积的含铜催化剂和在BET表面积为30〜160m 2 / g的钾含量为0.1-3.0重量％用于制备 来自一氧化碳和水的氢和二氧化碳。

公开(公告)号：US20050035486A1

公开(公告)日：2005-02-17

申请号：US10501874

申请日：2003-02-04

申请人： Rainer Klostermann ,  Komrad Richter ,  Michael Senge ,  Herbert Wanjek ,  Werner Biffar

发明人： Rainer Klostermann ,  Komrad Richter ,  Michael Senge ,  Herbert Wanjek ,  Werner Biffar

IPC分类号： B29C31/04 ,  C08F2/00 ,  C08G69/04 ,  C08G69/16 ,  C08G69/28 ,  C08G85/00 ,  B29C47/00

CPC分类号： C08G69/04 ,  C08G69/16 ,  C08G69/28

摘要： An apparatus suitable for producing shaped bodies comprising thermoplastic polymers from monomers which form such polymers in a batch process comprises a) at least one reactor suitable for the batchwise preparation of a melt of a thermoplastic polymer from monomers which form such a polymer, b) a piping system suitable as circulation line for the melt of the thermoplastic polymer and c) at least one apparatus suitable for the production of shaped bodies from the melt of a thermoplastic polymer, wherein the reactor or reactors a) is/are connected to the piping system b) and the apparatus or apparatuses c) is/are connected to the piping system b), and an apparatus for producing shaped bodies comprising thermoplastic polymers in such an apparatus.

摘要翻译： 一种适于生产成型体的装置，其包括以分批方法形成这种聚合物的单体的热塑性聚合物，其包括：a）至少一种适用于从形成这种聚合物的单体间歇制备热塑性聚合物熔体的反应器，b） 管道系统适合作为热塑性聚合物熔体的循环管线，以及c）至少一种适于从热塑性聚合物的熔体生产成形体的装置，其中反应器或反应器a）连接到管道系统 b）和装置或装置c）连接到管道系统b），以及用于在这种装置中制造包含热塑性聚合物的成形体的装置。

公开(公告)号：US06700000B1

公开(公告)日：2004-03-02

申请号：US09700452

申请日：2000-11-15

申请人： Thomas Heidemann ,  Herbert Wanjek

发明人： Thomas Heidemann ,  Herbert Wanjek

IPC分类号： C07D30789

CPC分类号： B01J35/0006 ,  B01J23/002 ,  B01J27/198 ,  B01J37/0223 ,  B01J2523/00 ,  C07D307/89 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55

摘要： Phthalic anhydride is prepared by catalytic gas-phase oxidation of xylene and/or naphthalene by a gas comprising molecular oxygen in a fixed bed at elevated temperature and using at least three coated catalysts arranged in superposed zones, which catalysts have a layer of catalytically active metal oxides applied to a core of support material. In the process described, the catalyst activity rises from zone to zone from the gas inlet end to the gas outlet end and the activity of the catalysts of the individual zones is set such that the least active catalyst comprises a lower amount of active composition and, if desired, additionally more alkali metal selected from the group consisting of potassium, rubidium and cesium as dopant than the catalyst of the next zone and the subsequent even more active catalyst comprises the same amount of active composition and even less alkali metal as dopant or a greater amount of active composition and, if desired, less alkali metal as dopant than the catalyst of the second zone, with further conditions.

摘要翻译： 邻苯二甲酸酐通过在固定床中在升高的温度下通过包含分子氧的气体二甲苯和/或萘的催化气相氧化制备，并且使用布置在重叠区中的至少三个涂覆的催化剂，该催化剂具有催化活性金属层 施加到支撑材料的芯的氧化物。 在所描述的方法中，催化剂活性从气体入口端到气体出口端从区域上升，并且各个区域的催化剂的活性被设定为使得最低活性催化剂包含较少量的活性组合物， 如果需要，另外还有更多的选自钾，铷和铯作为掺杂剂的碱金属比下一个区域的催化剂和随后的甚至更活泼的催化剂包含相同量的活性组合物，甚至更少的碱金属作为掺杂剂或 更多量的活性组合物和如果需要，具有比第二区域的催化剂更少的碱金属作为掺杂剂，具有进一步的条件。

公开(公告)号：US06362345B1

公开(公告)日：2002-03-26

申请号：US09700427

申请日：2000-11-15

申请人： Thomas Heidemann ,  Heiko Arnold ,  Gerhard Hefele ,  Herbert Wanjek

发明人： Thomas Heidemann ,  Heiko Arnold ,  Gerhard Hefele ,  Herbert Wanjek

IPC分类号： C07D30789

CPC分类号： C07C51/265 ,  C07C51/313 ,  C07C63/16

摘要： In a process for preparing phthalic anhydride by catalytic gas-phase oxidation of o-xylene/naphthalene mixtures by molecular oxygen, use is made of a catalyst I in a first zone on the gas inlet side which makes up from 25 to 75 percent by volume of the total catalyst volume, comprising, in each case based on the catalytically active composition, from 1 to 10% by weight of vanadium oxide (calculated as V205), from 1 to 10% by weight of antimony oxide (calculated as Sb203) and from 80 to 98% by weight of titanium dioxide of the anatase type having a BET surface area of from 13 to 28 m2/g and also from 0.05 to 1% by weight of cesium (calculated as Cs) applied to a steatite support and a catalyst II in a second zone which makes up the remaining 75 to 25 percent by volume of the total catalyst volume, comprising, in each case based on the catalytically active composition, from 1 to 10% by weight of vanadium oxide (calculated as V205), from 1 to 10% by weight of antimony oxide (calculated as Sb203) and from 80 to 98% by weight of titanium dioxide of the anatase type having a BET surface area of from 13 to 28 m2/g and from 0.01 to 1% by weight of phosphorus oxide (calculated as P) and also from 0.01 to 0.2% by weight of cesium (calculated as Cs) applied to a steatite support, wherein the cesium content of the catalyst II is less than 15% by weight of the cesium content of the catalyst I and the catalyst I and the catalyst II have been prepared without addition of compounds of niobium.

摘要翻译： 在通过分子氧的邻二甲苯/萘混合物的催化气相氧化制备邻苯二甲酸酐的方法中，使用在气体入口侧的第一区中的催化剂I，其占25-75体积％ 的总催化剂体积，包括在每种情况下基于催化活性组合物，1-10重量％的氧化钒（按V205计算），1-10重量％的氧化锑（以Sb 2 O 3计）和 80至98重量％的具有13至28平方米/克的BET表面积为13至28平方米/克的锐钛矿型二氧化钛和0.05至1重量％的应用于滑石支撑的铯（以Cs计算） 催化剂II在构成总催化剂体积的剩余75至25体积％的第二区域中，在每种情况下基于催化活性组合物，包含1-10重量％的氧化钒（以V205计算） ，1至10重量％的氧化锑（计算为 Sb 2 O 3）和80〜98重量％的BET表面积为13〜28m 2 / g，0.01〜1重量％的氧化磷（P计算）的锐钛矿型二氧化钛，0.01 至0.2重量％的铯（以Cs计算），其中催化剂II的铯含量小于催化剂I的铯含量的15重量％，催化剂I和催化剂II具有 在不添加铌化合物的情况下制备。