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公开(公告)号：US5128307A
公开(公告)日：1992-07-07
申请号：US649299
申请日：1991-01-30
申请人： Herbert Wanjek , Claus Witte , Michael J. Sprague , Matthias Irgang , Wolfgang Hoelderich , Wolf D. Mross
发明人： Herbert Wanjek , Claus Witte , Michael J. Sprague , Matthias Irgang , Wolfgang Hoelderich , Wolf D. Mross
CPC分类号： B01J37/031 , B01J23/72 , B01J23/80 , B01J35/1014 , B01J35/1019 , C01B3/16 , Y02P20/52
摘要： Copper-containing catalysts for low temperature shift conversion at from 150.degree. to 300.degree. C. and under from 10 to 40 bar, which additionally contain aluminum and zinc, if necessary in the form of the compounds or oxides and are prepared by coprecipitation, the copper-containing catalysts containing potassium and having a BET surface area adapted to the potassium content, and the potassium content being brought to 0.1-3.0% by weight at a BET surface of from 30 to 160 m.sup.2 /g, are used for the preparation of hydrogen and carbon dioxide from carbon monoxide and water.
摘要翻译： 在150〜300℃，10〜40巴下进行低温转化转化的含铜催化剂，如果需要，还含有铝和锌，如果需要，可以以化合物或氧化物的形式，通过共沉淀制备 含有钾的具有适合于钾含量的BET表面积的含铜催化剂和在BET表面积为30〜160m 2 / g的钾含量为0.1-3.0重量％用于制备 来自一氧化碳和水的氢和二氧化碳。
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公开(公告)号：US4711930A
公开(公告)日：1987-12-08
申请号：US875572
申请日：1986-06-18
申请人： Wolfgang Hoelderich , Werner Biffar , Matthias Irgang , Wolf D. Mross , Michael Kroener , Eberhard Ambach
发明人： Wolfgang Hoelderich , Werner Biffar , Matthias Irgang , Wolf D. Mross , Michael Kroener , Eberhard Ambach
IPC分类号： B01J23/85 , B01J23/88 , B01J27/188 , B01J27/198 , B01J27/199 , B01J35/04 , C01B3/16 , C07B61/00 , C07C1/00 , C07C5/333 , C07C15/46 , C07C67/00 , C07C231/00 , C07C231/12 , C07C233/03 , B01J23/84 , B01J27/18
CPC分类号： B01J23/8872 , B01J23/85 , B01J23/8877 , B01J27/188 , C01B3/16 , C07C5/3332 , Y02P20/52 , Y10T428/24149
摘要： A honeycomb catalyst consisting of from 30 to 95% by weight, calculated as Fe.sub.2 O.sub.3, of an iron compound and from 0.1 to 60% by weight, calculated as Al.sub.2 O.sub.3, CeO.sub.2 or Cr.sub.2 O.sub.3, of an aluminum, cerium and/or chromium compound and/or from 1 to 50% by weight of an alkali metal compound, in particular potassium, calculated as K.sub.2 O, and/or from 0.2 to 20% by weight, calculated as MeO.sub.3, of an element of sub-group 6, preferably MoO.sub.3 and WO.sub.3, and/or from 0.1 to 20% by weight, calculated as V.sub.2 O.sub.5, of a compound of vanadium and/or from 0.1 to 20% by weight, calculated as P.sub.2 O.sub.5, of a compound of phosphorus, a process for the preparation of the honeycomb catalyst, and the use of the catalyst for organic reactions.
摘要翻译： 一种蜂窝状催化剂，其以Al 2 O 3，CeO 2或Cr 2 O 3计算的铝，铈和/或铬化合物和/或铬化合物计为30至95重量％，以Fe 2 O 3计，铁化合物和0.1至60重量％ 或1至50重量％的碱金属化合物，特别是钾（以K 2 O计）和/或0.2至20重量％（以MeO 3计），为第6族元素，优选MoO 3和WO 3 ，和/或0.1至20重量％，以V 2 O 5计，钒化合物和/或按重量计0.1至20重量％的磷化合物，磷化合物的制备方法 催化剂和催化剂用于有机反应。
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公开(公告)号：US4806679A
公开(公告)日：1989-02-21
申请号：US633279
申请日：1984-07-23
IPC分类号： C07C67/34 , B01J29/00 , B01J29/04 , C07B61/00 , C07C67/00 , C07C69/025 , C07C69/16 , C07C67/293 , C07C69/28
CPC分类号： C07C67/00
摘要： 1,4-Diacyloxybut-2-enes and 3,4-diacyloxybut-1-enes are converted into one another in the gas phase or liquid phase at from 100.degree. to 350.degree. C. under atmospheric or superatmospheric pressure in the presence of a zeolite as a catalyst.
摘要翻译： 1,4-二酰氧基丁-2-烯和3,4-二酰氧基丁-1-烯在气相或液相中在大气压或超大气压下在100-350℃下，在 沸石作为催化剂。
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4.发明授权
公开(公告)号：US4503281A
公开(公告)日：1985-03-05
申请号：US577762
申请日：1984-02-07
CPC分类号： B01J29/86 , C07C1/20 , C07C2529/86 , Y02P30/42
摘要： C.sub.2 -C.sub.4 -olefins are prepared by catalytic conversion of methanol and/or dimethyl ether in the presence of a zeolite catalyst at elevated temperatures, by a process in which the catalyst used is a pure borosilicate zeolite which has been tableted or extruded without a binder and treated with hydrofluoric acid and hydrochloric acid. The treatment of the catalyst with hydrofluoric acid is carried out using 0.001-1N HF, and that with hydrochloric acid is carried out using 3-25% strength acid. The time-on-stream of the catalyst is improved.
摘要翻译： 通过在沸石催化剂存在下在高温下通过甲醇和/或二甲醚的催化转化制备C 2 -C 4 - 烯烃，其中使用的催化剂是纯硼硅酸盐沸石，其已被压片或挤出而没有粘合剂 并用氢氟酸和盐酸处理。 用氢氟酸处理催化剂使用0.001-1N HF进行催化剂，盐酸使用3-25％强度的酸进行。 提高了催化剂的时间流动性。
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5.发明授权
公开(公告)号：US4929759A
公开(公告)日：1990-05-29
申请号：US418939
申请日：1989-10-06
IPC分类号： B01J29/04 , B01J29/86 , C07C209/60
CPC分类号： B01J29/86 , B01J29/04 , C07C209/60 , Y02P20/582
摘要： Amines are prepared from an olefin and ammonia or a primary or secondary amine, or a mixture of these, in the presence of a borosilicate or borogermanate zeolite of the pentasil type as a catalyst, by a process in which the amine obtained is isolated from the reaction mixture, and unreacted starting materials are recycled.
摘要翻译： 在硼烷硅酸盐或硼烷类硼沸石沸石作为催化剂的存在下，由烯烃和氨或伯胺或仲胺或它们的混合物制备胺，其中所得的胺与 反应混合物和未反应的起始原料被再循环。
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公开(公告)号：US4929758A
公开(公告)日：1990-05-29
申请号：US212161
申请日：1988-06-13
IPC分类号： C07B61/00 , B01J21/00 , B01J29/04 , B01J29/40 , C07C67/00 , C07C209/00 , C07C209/60 , C07C211/02
CPC分类号： C07C209/60 , Y02P20/582
摘要： Amines are prepared from an olefin and ammonia or a primary and/or secondary amine in the presence of a zeolite catalyst of the pentasil type. Iron silicate zeolites of the pentasil type having an SiO.sub.2 /Fe.sub.2 O.sub.3 ratio greater than or equal to 10 are preferably used.
摘要翻译： 胺在戊烯型沸石催化剂存在下由烯烃和氨或初级和/或仲胺制备。 优选使用SiO 2 / Fe 2 O 3比例大于或等于10的pentasil型铁硅酸盐沸石。
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公开(公告)号：US4560822A
公开(公告)日：1985-12-24
申请号：US730687
申请日：1985-05-03
申请人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Gerd Fouquet
发明人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Gerd Fouquet
IPC分类号： C07C11/12 , B01J29/00 , C07B61/00 , C07C1/00 , C07C1/24 , C07C11/18 , C07C13/21 , C07C13/23 , C07C45/50 , C07C67/00
CPC分类号： C07C1/24 , C07C2101/16 , C07C2529/06 , C07C2529/86 , C07C2529/88
摘要： Dienes are prepared by dehydration of aldehydes at elevated temperatures by a method in which the dehydration is carried out using a zeolite as a catalyst.
摘要翻译： 二烯通过使用沸石作为催化剂进行脱水的方法在升高的温度下脱醛而制备。
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公开(公告)号：US4474741A
公开(公告)日：1984-10-02
申请号：US316070
申请日：1981-10-28
CPC分类号： C07C2/66 , B01J29/40 , C01B33/2869 , C01B39/02 , C07C1/20 , C07C2529/40 , Y02P30/20 , Y02P30/42 , Y10S423/22 , Y10S423/34
摘要： A process for the preparation of a crystalline aluminosilicate of the pentasil type by hydrothermal crystallization of SiO.sub.2 and Al(OH).sub.3 in the presence of an alkali metal salt at from 80.degree. to 250.degree. C., wherein the crystallization is carried out in ether or aqueous ether. Particularly suitable solvents include the ethers from the group of the poly-(ethylene glycol) dimethyl ethers and mixtures of these ethers with water. The use of these crystalline aluminosilicates as catalysts for alkylating aromatics, and for preparing olefins and/or aromatics from methanol and/or dimethyl ether is also described.
摘要翻译： 一种通过在80-250℃的碱金属盐存在下，通过SiO 2和Al（OH）3的水热结晶来制备pentasil型结晶硅铝酸盐的方法，其中结晶在乙醚中进行 或乙醚水溶液。 特别合适的溶剂包括来自聚（乙二醇）二甲醚的醚和这些醚与水的混合物的醚。 还描述了这些结晶铝硅酸盐作为烷基化芳族化合物的催化剂以及用于由甲醇和/或二甲醚制备烯烃和/或芳族化合物的用途。
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公开(公告)号：US4616098A
公开(公告)日：1986-10-07
申请号：US649977
申请日：1984-09-12
CPC分类号： B01J29/86 , C07C1/20 , C07C2521/12 , C07C2529/86 , Y02P20/52 , Y02P30/42
摘要： Olefins are prepared by converting methanol and/or dimethyl ether in the presence of a zeolite catalyst at elevated temperatures by a process wherein the catalyst used is a borosilicate zeolite which has been molded together with an amorphous binder containing aluminum oxide and silicon dioxide. The advantage of using the borosilicate catalyst is that the yield of C.sub.2 -C.sub.4 -olefins is improved at the expense of formation of higher hydrocarbons.
摘要翻译： 烯烃是通过在沸石催化剂存在下在升高的温度下通过转化甲醇和/或二甲醚的方法制备的，其中使用的催化剂是与含有氧化铝和二氧化硅的无定形粘合剂一起模制的硼硅酸盐沸石。 使用硼硅酸盐催化剂的优点是以高碳烃形成为代价改善了C2-C4-烯烃的产率。
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公开(公告)号：US4434314A
公开(公告)日：1984-02-28
申请号：US417523
申请日：1982-09-13
CPC分类号： C07C1/20 , C07C2529/04
摘要： A process for the preparation of olefins from methanol and/or dimethyl ether by conversion in the presence of a zeolite catalyst, in particular a borosilicate zeolite, at elevated temperature, with the addition of a small amount of an electron donor.
摘要翻译： 通过在沸石催化剂，特别是硼硅酸盐沸石的存在下，在升高的温度下，通过加入少量的电子给体来转化，从甲醇和/或二甲醚中制备烯烃的方法。
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