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    Method for producing phthalic anhydride
    1.
    发明授权
    Method for producing phthalic anhydride 有权
    邻苯二甲酸酐的制造方法

    公开(公告)号：US06700000B1

    公开(公告)日：2004-03-02

    申请号：US09700452

    申请日：2000-11-15

    申请人： Thomas Heidemann ,  Herbert Wanjek

    发明人： Thomas Heidemann ,  Herbert Wanjek

    IPC分类号： C07D30789

    CPC分类号： B01J35/0006 ,  B01J23/002 ,  B01J27/198 ,  B01J37/0223 ,  B01J2523/00 ,  C07D307/89 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/53 ,  B01J2523/55

    摘要： Phthalic anhydride is prepared by catalytic gas-phase oxidation of xylene and/or naphthalene by a gas comprising molecular oxygen in a fixed bed at elevated temperature and using at least three coated catalysts arranged in superposed zones, which catalysts have a layer of catalytically active metal oxides applied to a core of support material. In the process described, the catalyst activity rises from zone to zone from the gas inlet end to the gas outlet end and the activity of the catalysts of the individual zones is set such that the least active catalyst comprises a lower amount of active composition and, if desired, additionally more alkali metal selected from the group consisting of potassium, rubidium and cesium as dopant than the catalyst of the next zone and the subsequent even more active catalyst comprises the same amount of active composition and even less alkali metal as dopant or a greater amount of active composition and, if desired, less alkali metal as dopant than the catalyst of the second zone, with further conditions.

    摘要翻译： 邻苯二甲酸酐通过在固定床中在升高的温度下通过包含分子氧的气体二甲苯和/或萘的催化气相氧化制备，并且使用布置在重叠区中的至少三个涂覆的催化剂，该催化剂具有催化活性金属层 施加到支撑材料的芯的氧化物。 在所描述的方法中，催化剂活性从气体入口端到气体出口端从区域上升，并且各个区域的催化剂的活性被设定为使得最低活性催化剂包含较少量的活性组合物， 如果需要，另外还有更多的选自钾，铷和铯作为掺杂剂的碱金属比下一个区域的催化剂和随后的甚至更活泼的催化剂包含相同量的活性组合物，甚至更少的碱金属作为掺杂剂或 更多量的活性组合物和如果需要，具有比第二区域的催化剂更少的碱金属作为掺杂剂，具有进一步的条件。

    Method for producing phthalic anhydride by means of catalytic vapor-phase oxidation of o-xylol/naphthalene mixtures
    2.
    发明授权
    Method for producing phthalic anhydride by means of catalytic vapor-phase oxidation of o-xylol/naphthalene mixtures 失效
    通过邻甲酚/萘混合物的催化气相氧化生产邻苯二甲酸酐的方法

    公开(公告)号：US06362345B1

    公开(公告)日：2002-03-26

    申请号：US09700427

    申请日：2000-11-15

    申请人： Thomas Heidemann ,  Heiko Arnold ,  Gerhard Hefele ,  Herbert Wanjek

    发明人： Thomas Heidemann ,  Heiko Arnold ,  Gerhard Hefele ,  Herbert Wanjek

    IPC分类号： C07D30789

    CPC分类号： C07C51/265 ,  C07C51/313 ,  C07C63/16

    摘要： In a process for preparing phthalic anhydride by catalytic gas-phase oxidation of o-xylene/naphthalene mixtures by molecular oxygen, use is made of a catalyst I in a first zone on the gas inlet side which makes up from 25 to 75 percent by volume of the total catalyst volume, comprising, in each case based on the catalytically active composition, from 1 to 10% by weight of vanadium oxide (calculated as V205), from 1 to 10% by weight of antimony oxide (calculated as Sb203) and from 80 to 98% by weight of titanium dioxide of the anatase type having a BET surface area of from 13 to 28 m2/g and also from 0.05 to 1% by weight of cesium (calculated as Cs) applied to a steatite support and a catalyst II in a second zone which makes up the remaining 75 to 25 percent by volume of the total catalyst volume, comprising, in each case based on the catalytically active composition, from 1 to 10% by weight of vanadium oxide (calculated as V205), from 1 to 10% by weight of antimony oxide (calculated as Sb203) and from 80 to 98% by weight of titanium dioxide of the anatase type having a BET surface area of from 13 to 28 m2/g and from 0.01 to 1% by weight of phosphorus oxide (calculated as P) and also from 0.01 to 0.2% by weight of cesium (calculated as Cs) applied to a steatite support, wherein the cesium content of the catalyst II is less than 15% by weight of the cesium content of the catalyst I and the catalyst I and the catalyst II have been prepared without addition of compounds of niobium.

    摘要翻译： 在通过分子氧的邻二甲苯/萘混合物的催化气相氧化制备邻苯二甲酸酐的方法中，使用在气体入口侧的第一区中的催化剂I，其占25-75体积％ 的总催化剂体积，包括在每种情况下基于催化活性组合物，1-10重量％的氧化钒（按V205计算），1-10重量％的氧化锑（以Sb 2 O 3计）和 80至98重量％的具有13至28平方米/克的BET表面积为13至28平方米/克的锐钛矿型二氧化钛和0.05至1重量％的应用于滑石支撑的铯（以Cs计算） 催化剂II在构成总催化剂体积的剩余75至25体积％的第二区域中，在每种情况下基于催化活性组合物，包含1-10重量％的氧化钒（以V205计算） ，1至10重量％的氧化锑（计算为 Sb 2 O 3）和80〜98重量％的BET表面积为13〜28m 2 / g，0.01〜1重量％的氧化磷（P计算）的锐钛矿型二氧化钛，0.01 至0.2重量％的铯（以Cs计算），其中催化剂II的铯含量小于催化剂I的铯含量的15重量％，催化剂I和催化剂II具有 在不添加铌化合物的情况下制备。

    Catalysts and method for the hydroamination of olefins
    5.
    发明授权
    Catalysts and method for the hydroamination of olefins 有权
    烯烃水解催化剂和方法

    公开(公告)号：US08529869B2

    公开(公告)日：2013-09-10

    申请号：US13265457

    申请日：2010-04-19

    申请人： Thomas Heidemann ,  Jens Kehrer

    发明人： Thomas Heidemann ,  Jens Kehrer

    IPC分类号： C01B39/46 ,  C07C209/60

    CPC分类号： B01J29/7057 ,  B01J29/7007 ,  B01J37/0201 ,  B01J2229/186 ,  C07C209/60 ,  C07C211/07

    摘要： The present invention relates to a hydroamination catalyst comprising boron beta zeolites, wherein the hydroamination catalyst is doped with lithium, and also a process for producing it. The present patent application further relates to a process for preparing amines by reaction of ammonia or primary or secondary amines with olefins at elevated temperatures and pressures in the presence of the hydroamination catalyst of the invention.

    摘要翻译： 本发明涉及包含硼沸石的水解催化剂，其中所述水化催化剂掺杂有锂，并且还涉及其生产方法。 本专利申请还涉及在本发明的水解催化剂存在下，在升高的温度和压力下，通过氨或伯胺或仲胺与烯烃的反应来制备胺的方法。

    METHOD FOR DIRECT AMINATION OF HYDROCARBONS TO FORM AMINO HYDROCARBONS WITH THE ELECTROCHEMICAL SEPARATION OF HYDROCARBON
    6.
    发明申请
    METHOD FOR DIRECT AMINATION OF HYDROCARBONS TO FORM AMINO HYDROCARBONS WITH THE ELECTROCHEMICAL SEPARATION OF HYDROCARBON 有权
    碳氢化合物的电化学分离直接氨化到氨基碳氢化合物的方法

    公开(公告)号：US20120111732A1

    公开(公告)日：2012-05-10

    申请号：US13383321

    申请日：2010-07-08

    申请人： Petr Kubanek ,  Alexander Panchenko ,  Andreas Fischer ,  Thomas Heidemann

    发明人： Petr Kubanek ,  Alexander Panchenko ,  Andreas Fischer ,  Thomas Heidemann

    IPC分类号： C25B1/02 ,  H01M8/06

    CPC分类号： C07C209/02 ,  C25B3/00 ,  Y02P20/582 ,  C07C211/46

    摘要： Process for the direct amination of hydrocarbons to aminohydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one hydrocarbon and at least one aminating reagent to form a reaction mixture R comprising aminohydrocarbons and hydrogen and b) electrochemical separation of at least part of the hydrogen formed in the reaction from the reaction mixture R by means of a gastight membrane-electrode assembly having at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane, b1) reduced to hydrogen and/or b2) reacted with oxygen from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane to form water over the cathode catalyst on the permeate side.

    摘要翻译： 用于将烃直接胺化成氨基烃的方法，其包括以下步骤：a）包含至少一种烃和至少一种氨化试剂的进料流E的反应以形成包含氨基烃和氢的反应混合物R和b）电化学分离 通过具有至少一个选择性质子传导膜和在膜的每一侧上的至少一个电极催化剂的气密膜 - 电极组件在反应混合物R的反应中形成的至少一部分氢，其中至少部分 的氢被氧化成在膜的滞留侧上的阳极催化剂上的质子，并且质子在通过膜之后，b1）还原为氢和/或b2）与来自含氧流O的氧反应，其中 与膜的渗透侧接触以在渗透侧的阴极催化剂上形成水。

    OLIGOMERISATION OF OLEFINS
    8.
    发明申请
    OLIGOMERISATION OF OLEFINS 有权
    油脂的低级化

    公开(公告)号：US20110301398A1

    公开(公告)日：2011-12-08

    申请号：US13128895

    申请日：2009-11-18

    申请人： Thomas Heidemann ,  Armin Ulonska

    发明人： Thomas Heidemann ,  Armin Ulonska

    IPC分类号： C07C2/24

    CPC分类号： C07C2/10 ,  B01J23/755 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/755 ,  C10G50/00 ,  C10G2300/1088 ,  C10G2400/22

    摘要： Olefins are oligomerized by bringing at least one C2 to C8-olefin into contact with a nickel-containing heterogeneous catalyst. The catalyst is conditioned before contact with the olefin by passing an inert gas flow over the same, until the inert gas flow has a water content of less than 1000 ppm. Selectivity for the production of higher oligomers, in particular trimers relative to the formation of dimers is increased by the pretreatment.

    摘要翻译： 通过使至少一个C 2至C 8烯烃与含镍非均相催化剂接触来使烯烃低聚。 通过使惰性气体流过该惰性气体流，直到惰性气体流的含水量小于1000ppm，在与烯烃接触之前调节催化剂。 通过预处理可增加生产高级低聚物，特别是三聚体相对于二聚体形成的选择性。

    METHOD FOR PRE-TREATING HYDROAMINATION CATALYSTS
    10.
    发明申请
    METHOD FOR PRE-TREATING HYDROAMINATION CATALYSTS 有权
    预处理氢化催化剂的方法

    公开(公告)号：US20100174117A1

    公开(公告)日：2010-07-08

    申请号：US12601653

    申请日：2009-04-07

    申请人： Thomas Heidemann ,  Marcus Sigl

    发明人： Thomas Heidemann ,  Marcus Sigl

    IPC分类号： C07C209/60 ,  B01J23/00 ,  B01J27/28 ,  B01J29/04

    CPC分类号： C07C209/60 ,  B01J29/06 ,  B01J29/70 ,  B01J29/86 ,  B01J37/00 ,  B01J2229/38 ,  B01J2229/42 ,  C07C211/03

    摘要： The present invention relates to a process for the pretreatment of hydroamination catalysts, wherein the hydroamination catalyst is brought into contact with an ammonia-comprising mixture before the reaction of olefins with ammonia, a primary or secondary amine, with the ammonia-comprising mixture comprising less than 40% by weight of olefinThe invention further relates to a process for preparing alkylamines by reaction of olefins with ammonia, primary or secondary amines over a hydroamination catalyst, wherein the hydroamination catalyst is pretreated according to the invention before the reaction of the olefins by bringing the hydroamination catalyst into contact with an ammonia-comprising mixture comprising less than 40% by weight of olefin.

    摘要翻译： 本发明涉及一种用于预处理水解催化剂的方法，其中在烯烃与氨（伯或仲胺）反应之前，将氨化催化剂与含氨混合物接触，其中含氨混合物包含较少 超过40重量％的烯烃本发明还涉及一种通过烯烃与氨，伯胺或仲胺在水解催化剂上反应制备烷基胺的方法，其中在烯烃反应之前根据本发明预处理该催化剂， 使水解催化剂与包含小于40重量％烯烃的含氨混合物接触。