摘要:
The present invention relates to articles and heat storage devices for storage of thermal energy. The articles include a metal base sheet and a metal cover sheet, wherein the metal base sheet and the metal cover sheet are sealingly joined to form one or more sealed spaces. The articles include a thermal energy storage material that is contained within the sealed spaces. The sealed spaces preferably are substantially free of water or includes liquid water at a concentration of about 1 percent by volume or less at a temperature of about 25° C., based on the total volume of the sealed spaces. The articles include one or more of the following features: a) the pressure in a sealed space is about 700 Torr or less, when the temperature of the thermal energy storage material is about 25° C.; b) the metal cover sheet includes one or more stiffening features, wherein the stiffening features include indents into the sealed space, protrusions out of the sealed space, or both, that are sufficient in size and number to reduce the maximum von Mises stress in the cover sheet during thermal cycling; c) the metal cover sheet and/or the metal base sheet includes one or more volume expansion features; or d) the metal cover sheet has a thickness, tc, and the metal base sheet has a thickness, tb, wherein tc is greater than tb; so that the article is durable. For example, the article does not leak after thermal cycling between about 25° C. and about 240° C., for 1,000 cycles.
摘要:
The present invention relates to a thermal energy storage material (TESM) system (and associated methods). The TESM system comprises i) a container having a wall surface; and ii) a TESM in at least partial contact with the wall surface. The TESM may include, consist essentially of, or consist of a metal containing compound comprising at least two different metal cations and one or more polyatomic anions. The at least two metal cations may include lithium cations. The TESM may have a liquidus temperature, TL, from about 100° C. to about 250° C. The TESM may exhibits a heat storage density from 300° C. to 80° C. of at least 1 MJ/l. The TESM system may be free of water. If any water is present in the TESM system, the water concentration preferably is less than about 10 wt. %. Preferably, the TESM system is generally resistant to corrosion at temperatures of about 300° C.
摘要:
The device for storing and discharging heat which includes a housing; a first blister pack and a second blister pack each having a plurality of capsules; a thermal energy storage material contained in the capsules; and an evacuated space capable of insulating the housing. The blister packs include a first ply and a second ply that are joined together. The housing includes openings for flowing a heat transfer fluid through the device. The device includes a flow path for a heat transfer fluid that includes a volume between the first and second blister packs. The separation between the first and second blister packs is less than 5 mm.
摘要:
Improved thermal energy storage materials, devices and systems employing the same and related methods. The thermal energy storage materials may include a phase change material that includes a metal-containing compound. This invention is directed at methods of encapsulating thermal energy storage materials, devices containing encapsulated thermal energy storage materials, and capsular structures for encapsulating thermal energy storage materials.
摘要:
A device for storing and discharging heat that employs thermal energy storage materials (TESM) and related methods of manufacturing the device. The device includes a housing, an array of capsules within the housing, and TESM contained in the capsules. The device exhibits a high initial power density. The TESM is encapsulated between metal plies. The metal plies may have a thickness on the order of 10−1 to 102 μm. The capsules may have a thickness from 0.5 mm to 20 mm. The volume fraction of TESM in the housing may be 0.5 or more. The housing includes an inlet, an outlet, and one or more flow paths for flowing a heat transfer fluid through the housing. The flow paths and the capsules are arranged so that the device has the required average initial power density.
摘要:
The present invention relates to a thermal energy storage material (TESM) system (and associated methods) that reproducibly stores and recovers latent heat. The Thermal energy storage material system comprises i) at least one first metal containing material including at least one first metal compound that includes a nitrate ion, a nitrite ion, or both; and ii) at least one second metal containing material including at least one second metal compound. The thermal energy storage material system may water. If any water is present in the thermal energy storage material system, the water concentration should be less than about 10 wt. %. The thermal energy storage material has a liquidus temperature, TL, from about 100° C. to about 250° C. and exhibits a heat storage density from 300° C. to 80° C. of at least about 1 MJ/l, so that upon being used in a system that generates heat, at least a portion of the heat is captured and stored by the thermal energy storage material and subsequently released for use. The thermal energy storage material system is generally resistant to corrosion at temperatures of about 300° C. Exemplary metal compounds include one or more cations selected from the group consisting of Li, Na, K, Be, Mg, Ca, Al, and Ga.
摘要:
A thermal energy storage material (TESM) system (and associated methods) that reproducibly stores and recovers latent heat comprising i) at least one first metal containing material including at least one first metal compound that includes a nitrate ion, a nitrite ion, or both; ii) at least one second metal containing material including at least one second metal compound; and iii) optionally including water, wherein the water concentration if any is present is less than about 10 wt. %; wherein the TESM has a liquidus temperature, TL, from about 100° C. to about 250° C.; and wherein the TESM exhibits a heat storage density from 300° C. to 80° C. of at least about 1 MJ/l; so that upon being used in a system that generates heat, at least a portion of the heat is captured and stored by the TESM and subsequently released for use, and the system is generally resistant to corrosion at temperatures of about 300° C.
摘要:
The invention is directed at devices, systems, and processes for managing the temperature of an electrochemical call including a device 10 comprising an inlet for receiving a heat transfer fluid; one or more electrochemical cell compartments 12 for receiving one or more electrochemical calls 20; one or more thermal energy storage material compartments 14 containing one or more thermal energy storage materials 18; and one or more heat transfer fluid compartments 16 for flowing the heat transfer fluid through the device; wherein the space between the one or more heat transfer fluid compartments 16 and the one or more electrochemical cell compartments 12 preferably includes one or more first regions 22 (i.e. portion) that are substantially free of the thermal energy storage material 18; and the space between the one or more heat transfer fluid compartments 16 and the one or more thermal energy storage material compartments 14 preferably includes one or more second regions 24 (i.e. portion) that are substantially free of an electrochemical cell 20; so that the heat transfer fluid compartment 16 is in direct thermal communication with both the thermal energy storage material compartment 14 and the electrochemical cell compartment 12.
摘要:
The thermal energy storage material (TESM) system includes a container having a wall surface, and a TESM in at least partial contact with the wall surface. The TESM may include, consist essentially of, or consist of a metal containing compound comprising lithium, one or more different metal cations (i.e., different from lithium) and one or more polyatomic anions. The TESM may have a liquidus temperature, TL, from about 100° C. to about 250° C. The TESM may exhibits a heat storage density from 1 MJ/l to 1.84 MJ/l, as measured from 300° C. to 80° C. The TESM system may be free of water. If any water is present in the TESM system, the water concentration preferably is less than 10 wt. %. Preferably, the TESM system is generally resistant to corrosion at temperatures of about 300° C.
摘要:
The invention is directed at articles and devices for thermal energy storage, and for process of storing energy using these articles and devices. The articles comprise a capsular structure 10 having one or more sealed spaces 14, wherein the sealed spaces encapsulate one or more thermal energy storage materials 26: wherein the capsular structure has one or more fluid passages 16 which are sufficiently large to allow a heat transfer fluid to flow through the one or more fluid passages; and when a heat transfer fluid contacts the capsular structure 10 the thermal energy storage material 26 is Isolated from the heal transfer fluid. The devices include two or more articles arranged so that a fluid, such as a heat transfer fluid, may flow through the fluid passage 16 of an article before or after flowing through a space between two of the articles.