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1.发明授权Phosphorus and halogen containing polymers of bis-hydroxyethyl terephthalate as flame retardant additives 失效含磷和含卤素聚合物的双羟乙基对苯二甲酸酯作为阻燃添加剂
公开(公告)号：US4030933A
公开(公告)日：1977-06-21
申请号：US566005
申请日：1975-04-07
摘要： The present invention provides a process for preparing phosphorus and halogen containing polymers useful as flame retardant additives in cellulose acetate or cellulose triacetate fibers or films. The phosphorus and halogen containing polymers may be prepared by reacting a halogenated derivative of bis-hydroxyethyl terephthalate with a halogen containing phosphorus monomer having the formula ##STR1## wherein R represents a radical selected from the group consisting of (a) alkyl, (b) bromoalkyl, (c) chloroalkyl, (d) alkylamido and (e) dialkylamido radicals, wherein the alkyl substituents of the foregoing may contain from 1 to 10 carbon atoms, (f) cyclohexyl, (g) phenyl, (h) benzyl, (i) tolyl, and (j) xylyl, and X represents a halogen atom (preferably chlorine or bromine). Cellulose acetate and cellulose triacetate fibers and films containing as little as two percent by weight of the polymeric flame retardant additives are rendered both non-burning and resistant to loss of the polymeric flame retardant additive during use.
摘要翻译： 本发明提供一种制备含磷和卤素聚合物的方法，该聚合物可用作乙酸纤维素或三乙酸纤维素纤维或薄膜中的阻燃添加剂。 含磷和卤素的聚合物可以通过将对苯二甲酸双羟乙酯的卤代衍生物与具有式（Ⅰ）的含卤素的磷单体反应来制备，其中R表示选自（a）烷基，（b） 溴代烷基，（c）氯烷基，（d）烷基酰氨基和（e）二烷基酰氨基，其中前述烷基取代基可含有1-10个碳原子，（f）环己基，（g）苯基，（h） i）甲苯基，（j）二甲苯基，X表示卤素原子（优选氯或溴）。 乙酸纤维素和三乙酸纤维素纤维和含有少至2重量％的聚合物阻燃添加剂的薄膜在使用过程中既不燃，也不耐聚合阻燃添加剂的损失。
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公开(公告)号：US4035437A
公开(公告)日：1977-07-12
申请号：US663136
申请日：1976-03-02
CPC分类号： C08G69/26
摘要： This invention relates to high molecular weight polyamide resin compositions which are uniquely stable under hydrolytic conditions. The polyamide resin compositions are produced by the condensation of a diamine with a sterically-hindered neo-acid derivative such as .alpha.,.alpha.,.alpha.',.alpha.'-tetramethyl-p-phenylenediacetic acid.
摘要翻译： 本发明涉及在水解条件下独特稳定的高分子量聚酰胺树脂组合物。 聚酰胺树脂组合物通过二胺与空间位阻的新酸衍生物如α，α，α'，α'-四甲基 - 对苯二乙酸缩合而制备。
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3.发明授权High temperature polyester resins from 4,4'-bis(p-hydroxyphenoxy)diphenyl ether and terephthalic acid 失效来自4,4 {40-双（对羟基苯氧基）二苯基醚和对苯二甲酸的高温聚酯树脂
公开(公告)号：US4071499A
公开(公告)日：1978-01-31
申请号：US713722
申请日：1976-08-12
IPC分类号： C08G63/00 , C08G63/19 , C08G63/66 , C08G63/672 , C08G63/18
CPC分类号： C08G63/672 , Y10T428/31786
摘要： This invention provides high temperature performance polyester resins which contain polyphenyl ether blocks as recurring structural units. The polyester resins are melt stable at temperatures up to about 400.degree. C.
摘要翻译： 本发明提供了含有聚苯醚嵌段作为重复结构单元的高温性能聚酯树脂。 聚酯树脂在高达约400℃的温度下是熔融稳定的。
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公开(公告)号：US4064107A
公开(公告)日：1977-12-20
申请号：US713723
申请日：1976-08-12
CPC分类号： C08G18/3243 , C08G2150/20
摘要： This invention provides high temperature performance polyurea resins which contain polyphenyl ether blocks as recurring structural units. The polyurea resins are melt stable at temperatures up to about 400.degree. C and higher.
摘要翻译： 本发明提供含有聚苯醚嵌段作为重复结构单元的高温性能聚脲树脂。 聚脲树脂在高达约400℃和更高的温度下是熔融稳定的。
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公开(公告)号：US4031063A
公开(公告)日：1977-06-21
申请号：US558748
申请日：1975-03-17
IPC分类号： C08G63/181 , C08G63/19 , C08G63/682 , C08G63/18 , C08G63/26 , C08G63/60 , C08G63/68
CPC分类号： C08G63/19 , C08G63/181 , C08G63/6826
摘要： This invention relates to high molecular weight polyester resin compositions which are uniquely stable under hydrolytic conditions. The polyester resin compositions are produced by the condensation of a dihydric polyol with a sterically-hindered neo-acid derivative such as .alpha.,.alpha.,.alpha.',.alpha.'-tetramethyl-p-phenylenediacetic acid.
摘要翻译： 本发明涉及在水解条件下独特稳定的高分子量聚酯树脂组合物。 聚酯树脂组合物通过二元多元醇与空间位阻的新酸衍生物如α，α，α'，α'-四甲基 - 对苯二乙酸缩合而制备。
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公开(公告)号：US4208502A
公开(公告)日：1980-06-17
申请号：US489628
申请日：1974-07-18
IPC分类号： C08F20/30 , C08F222/10
CPC分类号： C08F20/30
摘要： Curable compositions are provided by the interaction of bis(2-hydroxyethyl) tetrachloroterephthalate with acrylic acid derivatives to form flame retardant unsaturated esters of tetrachloroterephthalic acid.
摘要翻译： 通过双（2-羟乙基）四氯对苯二甲酸酯与丙烯酸衍生物的相互作用提供可固化组合物以形成四氯对苯二甲酸的阻燃不饱和酯。
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公开(公告)号：US4169945A
公开(公告)日：1979-10-02
申请号：US867269
申请日：1978-01-05
CPC分类号： C08B37/0087 , C08B37/0093 , C08B37/0096 , Y10S507/922
摘要： This invention provides an improved process for producing alkyl ethers of polygalactomannan gum by contacting polygalactomannan gum with alkyl halide in the presence of a metal hydroxide catalyst and a quaternary ammonium phase-transfer agent.
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公开(公告)号：US5234974A
公开(公告)日：1993-08-10
申请号：US901324
申请日：1992-06-19
IPC分类号： C09D5/00 , C09D5/14 , C09D133/14
CPC分类号： C09D5/14 , C09D133/14 , C09D5/00
摘要： An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.
摘要翻译： 公开了一种碱溶性涂料配方。 这种涂料制剂包含挥发性水性载体; 水溶性载体中的碱溶性亲水聚合物; 在水性载体中也是碱溶性多价金属离子的键合形成剂; 和水性载体中的有效量的挥发性碱成分，用于溶解亲水性聚合物以及多价金属离子的键合形成剂。 在水性载体中，亲水性聚合物和多价金属离子的结合剂形成剂的相对量，在挥发性水性载体从其上蒸发后，可有效地在基材上形成碱溶性聚合物涂层。
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9.发明授权Compatible blends of main chain and side chain thermotropic liquid crystal polymers 失效主链和侧链热致液晶聚合物的兼容混合物
公开(公告)号：US4842754A
公开(公告)日：1989-06-27
申请号：US111179
申请日：1987-10-22
摘要： This invention relates to compatible blends of liquid crystal main chain polymers and liquid crystal side chain polymers having the same or similar mesogenic groups.
摘要翻译： 本发明涉及具有相同或相似的介晶基团的液晶主链聚合物和液晶侧链聚合物的相容共混物。
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公开(公告)号：US4554377A
公开(公告)日：1985-11-19
申请号：US631047
申请日：1984-07-16
IPC分类号： C07C233/00 , C07C103/133 , C07C102/00
CPC分类号： C07C233/00
摘要： The invention relates to the preparation of N-.alpha.-alkoxyethyl-carboxylic acid amides from dimethyl acetal and a carboxylic acid amide such as acetamide and to the preparation of secondary N-vinyl carboxylic acid amides such as N-vinyl acetamide therefrom.The reaction of dimethyl acetal and the carboxylic acid amide involves an equilibrium disproportionation wherein excess dimethyl acetal is used in sufficient amounts, e.g., in a molar ratio of from about 2 to 60:1 mole ratio, so as to force the equilibrium to the desired N-.alpha.-alkoxyethyl-carboxylic acid amide intermediate product. Equilibrium is reached in about 0.1 to 150 hours at a temperature about 0.degree. to 100.degree. C. The intermediate N-.alpha.-alkoxyethyl-carboxylic acid amide is pyrolyzed in accordance with a known pyrolysis reaction so as to obtain the corresponding N-vinyl acetamide.
摘要翻译： 本发明涉及由二甲基缩醛和羧酸酰胺如乙酰胺制备N-烷基氧基乙基 - 羧酸酰胺，以及由N-乙烯基乙酰胺等N-乙烯基乙酰胺制备。 二甲基缩醛和羧酸酰胺的反应涉及平衡歧化，其中过量的二甲基缩醛以足够的量使用，例如摩尔比为约2至60:1摩尔比，以便使平衡达到所需的 N-烷氧基乙基 - 羧酸酰胺中间产物。 在约0℃至100℃的温度下，平衡达到约0.1至150小时。根据已知的热解反应热解中间体N-烷氧基乙基 - 酰胺酰胺，得到相应的N-乙烯基乙酰胺 。
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