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1.发明授权Compatible blends of main chain and side chain thermotropic liquid crystal polymers 失效主链和侧链热致液晶聚合物的兼容混合物
公开(公告)号：US4842754A
公开(公告)日：1989-06-27
申请号：US111179
申请日：1987-10-22
摘要： This invention relates to compatible blends of liquid crystal main chain polymers and liquid crystal side chain polymers having the same or similar mesogenic groups.
摘要翻译： 本发明涉及具有相同或相似的介晶基团的液晶主链聚合物和液晶侧链聚合物的相容共混物。
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2.发明授权Compatible blends of main chain and side chain thermotropic liquid crystal polymers 失效主链和侧链热致液晶聚合物的兼容混合物
公开(公告)号：US4952334A
公开(公告)日：1990-08-28
申请号：US449221
申请日：1989-12-05
摘要： This invention relates to compatible blends of liquid crystal main chain polymer and liquid crystal side polymers having the same or similar mesogenic groups.
摘要翻译： 本发明涉及液晶主链聚合物和具有相同或相似的介晶基团的液晶侧聚合物的相容共混物。
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3.发明授权Crosslinkable thermotropic polyesters derived from allylically substituted hydroxybenzoic acid and a process for preparing a shaped article of the polyesters 失效衍生自烯丙基取代的羟基苯甲酸的可交联的热致聚酯和制备聚酯的成型制品的方法
公开(公告)号：US4626584A
公开(公告)日：1986-12-02
申请号：US775278
申请日：1985-09-11
CPC分类号： C08G63/065 , C08G63/605
摘要： A novel polyester is provided which is capable of forming an anisotropic melt and which, subsequent to being formed into shaped articles, is capable of crosslinking to render the article highly heat stable. The polyester preferably consists of approximately 1 to 40 mole percent of 3-allyl-4-oxybenzoyl and/or 3-methylallyl-4-oxybenzoyl moieties copolymerized with oxyaroyl moieties and/or dioxaryl and dicarboxyaryl moieties. The process comprises heating a monomer mixture of allylically substituted hydroxybenzoic acid and aromatic hydroxy acids and/or aromatic diols and diacids to prepare the polyester; melt processing the polyester to form a solid shaped article; and heating to substantially crosslink the allylic groups while substantially retaining the configuration of the solid shaped article.
摘要翻译： 提供了能够形成各向异性熔体的新型聚酯，其在形成成型制品之后能够交联以使制品高度热稳定。 聚酯优选由约1至40摩尔％的与烯酰基部分和/或二氧杂芳基和二羧基芳基部分共聚的3-烯丙基-4-羟基苯甲酰基和/或3-甲基烯丙基-4-氧基苯甲酰基部分组成。 该方法包括加热烯丙基取代的羟基苯甲酸和芳族羟基酸和/或芳族二醇和二酸的单体混合物以制备聚酯; 熔融加工聚酯以形成固体成型制品; 并加热至基本上交联烯丙基，同时基本上保持固体成型制品的构型。
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公开(公告)号：US5234974A
公开(公告)日：1993-08-10
申请号：US901324
申请日：1992-06-19
IPC分类号： C09D5/00 , C09D5/14 , C09D133/14
CPC分类号： C09D5/14 , C09D133/14 , C09D5/00
摘要： An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.
摘要翻译： 公开了一种碱溶性涂料配方。 这种涂料制剂包含挥发性水性载体; 水溶性载体中的碱溶性亲水聚合物; 在水性载体中也是碱溶性多价金属离子的键合形成剂; 和水性载体中的有效量的挥发性碱成分，用于溶解亲水性聚合物以及多价金属离子的键合形成剂。 在水性载体中，亲水性聚合物和多价金属离子的结合剂形成剂的相对量，在挥发性水性载体从其上蒸发后，可有效地在基材上形成碱溶性聚合物涂层。
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公开(公告)号：US4554377A
公开(公告)日：1985-11-19
申请号：US631047
申请日：1984-07-16
IPC分类号： C07C233/00 , C07C103/133 , C07C102/00
CPC分类号： C07C233/00
摘要： The invention relates to the preparation of N-.alpha.-alkoxyethyl-carboxylic acid amides from dimethyl acetal and a carboxylic acid amide such as acetamide and to the preparation of secondary N-vinyl carboxylic acid amides such as N-vinyl acetamide therefrom.The reaction of dimethyl acetal and the carboxylic acid amide involves an equilibrium disproportionation wherein excess dimethyl acetal is used in sufficient amounts, e.g., in a molar ratio of from about 2 to 60:1 mole ratio, so as to force the equilibrium to the desired N-.alpha.-alkoxyethyl-carboxylic acid amide intermediate product. Equilibrium is reached in about 0.1 to 150 hours at a temperature about 0.degree. to 100.degree. C. The intermediate N-.alpha.-alkoxyethyl-carboxylic acid amide is pyrolyzed in accordance with a known pyrolysis reaction so as to obtain the corresponding N-vinyl acetamide.
摘要翻译： 本发明涉及由二甲基缩醛和羧酸酰胺如乙酰胺制备N-烷基氧基乙基 - 羧酸酰胺，以及由N-乙烯基乙酰胺等N-乙烯基乙酰胺制备。 二甲基缩醛和羧酸酰胺的反应涉及平衡歧化，其中过量的二甲基缩醛以足够的量使用，例如摩尔比为约2至60:1摩尔比，以便使平衡达到所需的 N-烷氧基乙基 - 羧酸酰胺中间产物。 在约0℃至100℃的温度下，平衡达到约0.1至150小时。根据已知的热解反应热解中间体N-烷氧基乙基 - 酰胺酰胺，得到相应的N-乙烯基乙酰胺 。
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公开(公告)号：US4150170A
公开(公告)日：1979-04-17
申请号：US882846
申请日：1978-03-02
CPC分类号： C09J7/0217 , C09J4/00 , C09J4/06
摘要： An improved process and product for use in ultraviolet curable pressure-sensitive adhesives is disclosed. The product, a standard ultraviolet curable pressure-sensitive adhesive to which has been added a benzoin C.sub.1 -C.sub.12 hydrocarbon alkyl ether and a triplet state sensitizer, exhibits adhesive strength properties which are substantially greater than those of prior art systems.
摘要翻译： 公开了用于紫外线固化型压敏粘合剂的改进方法和产品。 该产品是已经添加了苯偶姻C 1 -C 12烃烷基醚和三线态敏化剂的标准紫外线固化型压敏粘合剂，显示出显着大于现有技术体系的粘合强度性能。
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7.发明授权
公开(公告)号：US4132705A
公开(公告)日：1979-01-02
申请号：US819727
申请日：1977-07-28
IPC分类号： C08G63/682 , C08G63/81 , C08G63/22
CPC分类号： C08G63/81 , C08G63/6824
摘要： A process for preparing certain halogenated aromatic polyesters having a predetermined molecular weight is provided. Such polyesters are prepared by solution polymerization of an appropriate bisphenol and diacid halide wherein the diacid halide is added to a solution containing the bisphenol until the viscosity of the resulting polymer containing solution reaches a predetermined solution viscosity limit at which time the further addition of diacid halide is terminated. The solution viscosity limit is indicative of the attainment of said predetermined molecular weight. The identification of said solution viscosity limit is achieved by a feedback mechanism wherein the viscosity of the polymer containing solution is monitored or sensed during or after the addition of the diacid halide to the bisphenol containing solution.
摘要翻译： {PG，1]提供了制备具有预定分子量的某些卤代芳族聚酯的方法。 这种聚酯通过适当的双酚和二卤化物的溶液聚合制备，其中将二酸卤化物加入到含有双酚的溶液中，直到得到的含聚合物溶液的粘度达到预定的溶液粘度极限，此时进一步加入二酰卤 被终止。 溶液粘度极限表示达到所述预定分子量。 所述溶液粘度极限的鉴定通过反馈机制来实现，其中在向含双酚的溶液中加入二酸卤化物期间或之后监测或感测含聚合物的溶液的粘度。
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8.发明授权Phosphorus and halogen containing polymers of bis-hydroxyethyl terephthalate as flame retardant additives 失效含磷和含卤素聚合物的双羟乙基对苯二甲酸酯作为阻燃添加剂
公开(公告)号：US4030933A
公开(公告)日：1977-06-21
申请号：US566005
申请日：1975-04-07
摘要： The present invention provides a process for preparing phosphorus and halogen containing polymers useful as flame retardant additives in cellulose acetate or cellulose triacetate fibers or films. The phosphorus and halogen containing polymers may be prepared by reacting a halogenated derivative of bis-hydroxyethyl terephthalate with a halogen containing phosphorus monomer having the formula ##STR1## wherein R represents a radical selected from the group consisting of (a) alkyl, (b) bromoalkyl, (c) chloroalkyl, (d) alkylamido and (e) dialkylamido radicals, wherein the alkyl substituents of the foregoing may contain from 1 to 10 carbon atoms, (f) cyclohexyl, (g) phenyl, (h) benzyl, (i) tolyl, and (j) xylyl, and X represents a halogen atom (preferably chlorine or bromine). Cellulose acetate and cellulose triacetate fibers and films containing as little as two percent by weight of the polymeric flame retardant additives are rendered both non-burning and resistant to loss of the polymeric flame retardant additive during use.
摘要翻译： 本发明提供一种制备含磷和卤素聚合物的方法，该聚合物可用作乙酸纤维素或三乙酸纤维素纤维或薄膜中的阻燃添加剂。 含磷和卤素的聚合物可以通过将对苯二甲酸双羟乙酯的卤代衍生物与具有式（Ⅰ）的含卤素的磷单体反应来制备，其中R表示选自（a）烷基，（b） 溴代烷基，（c）氯烷基，（d）烷基酰氨基和（e）二烷基酰氨基，其中前述烷基取代基可含有1-10个碳原子，（f）环己基，（g）苯基，（h） i）甲苯基，（j）二甲苯基，X表示卤素原子（优选氯或溴）。 乙酸纤维素和三乙酸纤维素纤维和含有少至2重量％的聚合物阻燃添加剂的薄膜在使用过程中既不燃，也不耐聚合阻燃添加剂的损失。
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公开(公告)号：US5147915A
公开(公告)日：1992-09-15
申请号：US759253
申请日：1991-09-13
IPC分类号： C09D5/00 , C09D5/14 , C09D133/14
CPC分类号： C09D5/14 , C09D133/14 , C09D5/00
摘要： An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.
摘要翻译： 公开了一种碱溶性涂料配方。 这种涂料制剂包含挥发性水性载体; 水溶性载体中的碱溶性亲水聚合物; 在水性载体中也是碱溶性多价金属离子的键合形成剂; 和水性载体中的有效量的挥发性碱成分，用于溶解亲水性聚合物以及多价金属离子的键合形成剂。 在水性载体中，亲水性聚合物和多价金属离子的结合剂形成剂的相对量，在挥发性水性载体从其上蒸发后，可有效地在基材上形成碱溶性聚合物涂层。
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公开(公告)号：US4814399A
公开(公告)日：1989-03-21
申请号：US77271
申请日：1987-07-24
IPC分类号： C08G73/18
CPC分类号： C08G73/18
摘要： A substituted polybenzimidazole polymer is disclosed wherein sulfoalkyl derivatives of polybenzimidazole are produced by the reaction of a polybenzimidazole polymer with a sultone. Beta sultones may be directly reacted with the polybenzimidazole polymer to produce a sulfoethyl derivative of polybenzimidazole. However, when gamma, delta or eta sultones are used, the polybenzimidazole polymer preferably is first reacted with an alkali hydride to produce the polyanion of polybenzimidazole. The polybenzimidazole polyanion is then reacted with the sultone to produce a sulfoalkyl derivative of polybenzimidazole polymer. These derivatives may find great use as ion exchange devices or for reverse osmosis or ultrafiltration devices.
摘要翻译： 公开了一种取代的聚苯并咪唑聚合物，其中聚苯并咪唑的磺烷基衍生物是通过聚苯并咪唑聚合物与磺内酯的反应产生的。 β磺内酯可以与聚苯并咪唑聚合物直接反应以产生聚苯并咪唑的磺乙基衍生物。 然而，当使用γ，δ或eta sultone时，优选首先使聚苯并咪唑聚合物与碱金属氢化物反应以制备聚苯并咪唑的聚阴离子。 然后将聚苯并咪唑聚阴离子与磺内酯反应以产生聚苯并咪唑聚合物的磺基烷基衍生物。 这些衍生物可以作为离子交换装置或用于反渗透或超滤装置发挥很大的用途。
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