公开(公告)号：US5234974A

公开(公告)日：1993-08-10

申请号：US901324

申请日：1992-06-19

申请人： Glenn C. Calhoun ,  Robert W. Stackman ,  Michael E. Klinkhammer

发明人： Glenn C. Calhoun ,  Robert W. Stackman ,  Michael E. Klinkhammer

IPC分类号： C09D5/00 ,  C09D5/14 ,  C09D133/14

CPC分类号： C09D5/14 ,  C09D133/14 ,  C09D5/00

摘要： An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.

摘要翻译： 公开了一种碱溶性涂料配方。 这种涂料制剂包含挥发性水性载体; 水溶性载体中的碱溶性亲水聚合物; 在水性载体中也是碱溶性多价金属离子的键合形成剂; 和水性载体中的有效量的挥发性碱成分，用于溶解亲水性聚合物以及多价金属离子的键合形成剂。 在水性载体中，亲水性聚合物和多价金属离子的结合剂形成剂的相对量，在挥发性水性载体从其上蒸发后，可有效地在基材上形成碱溶性聚合物涂层。

公开(公告)号：US07999031B2

公开(公告)日：2011-08-16

申请号：US12611702

申请日：2009-11-03

申请人： Glenn C. Calhoun ,  Rodney M. Weston

发明人： Glenn C. Calhoun ,  Rodney M. Weston

IPC分类号： C09D5/02

CPC分类号： C08F2/10 ,  C08F2/06 ,  C08F220/14 ,  C08F220/18 ,  C08F220/34 ,  Y10T442/20 ,  Y10T442/60 ,  Y10T442/69

摘要： A method of making an ion triggerable cationic polymer by solution copolymerizing one or more vinyl-functional cationic monomers, one or more water insoluble or hydrophobic vinyl monomers with alkyl side chains up to 4 carbons long, and, optionally, a minor amount of one or more vinyl monomers with linear or branched alkyl groups longer than 4 carbons, alkyl hydroxy, polyoxyalkylene, or other functional groups. The solution polymerization is accomplished by free radical polymerization in a mixture of an organic solvent such as acetone and water. After polymerization is complete, the organic solvent is preferably removed by a continuous process. The continuous process is preferably performed using a plate evaporator system.

摘要翻译： 一种通过使一种或多种乙烯基官能阳离子单体，一种或多种水不溶性或疏水性乙烯基单体与最多4个碳原子的烷基侧链和任选地少量一个或多个乙烯基官能阳离子单体共聚而制备离子可触发阳离子聚合物的方法， 更多具有长于4个碳的直链或支链烷基的乙烯基单体，烷基羟基，聚氧化烯或其它官能团。 溶液聚合通过在有机溶剂如丙酮和水的混合物中的自由基聚合来完成。 聚合完成后，优选通过连续方法除去有机溶剂。 连续方法优选使用板式蒸发器系统进行。

公开(公告)号：US07592391B2

公开(公告)日：2009-09-22

申请号：US10803306

申请日：2004-03-18

申请人： Glenn C. Calhoun ,  Rodney M. Weston

发明人： Glenn C. Calhoun ,  Rodney M. Weston

IPC分类号： C09D5/02

CPC分类号： C08F220/14 ,  Y02P20/582 ,  Y10T442/20 ,  Y10T442/60 ,  Y10T442/69

摘要： A method of making an ion triggerable cationic polymer by solution copolymerizing one or more vinyl-functional cationic monomers, one or more water insoluble or hydrophobic vinyl monomers with alkyl side chains up to 4 carbons long, and, optionally, a minor amount of one or more vinyl monomers with linear or branched alkyl groups longer than 4 carbons, alkyl hydroxy, polyoxyalkylene, or other functional groups. The solution polymerization is accomplished by free radical polymerization in a mixture of acetone and water.

摘要翻译： 一种通过使一种或多种乙烯基官能阳离子单体，一种或多种水不溶性或疏水性乙烯基单体与最多4个碳原子的烷基侧链和任选地少量一个或多个乙烯基官能阳离子单体共聚而制备离子可触发阳离子聚合物的方法， 更多具有长于4个碳的直链或支链烷基的乙烯基单体，烷基羟基，聚氧化烯或其它官能团。 溶液聚合通过丙酮和水的混合物中的自由基聚合来完成。

公开(公告)号：US06518334B1

公开(公告)日：2003-02-11

申请号：US09532597

申请日：2000-03-22

申请人： Glenn C. Calhoun ,  Michael T. Sarkis

发明人： Glenn C. Calhoun ,  Michael T. Sarkis

IPC分类号： C08L302

CPC分类号： D21H21/16 ,  C08L77/00 ,  C08L93/04 ,  C09D11/03 ,  C09D177/00 ,  C09D193/04 ,  C09G1/04 ,  C08L33/00 ,  C08L2666/26 ,  C08L2666/02

摘要： This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.

摘要翻译： 本发明涉及包含聚羧酰胺树脂与碱分散树脂的聚合物共混物。 本发明还涉及聚合物共混物制备水性分散体的用途。 水分散体是通过在碱性分散树脂中在水性介质中加热聚酰胺聚酰胺树脂得到的。 本发明还涉及含有水分散体的涂料组合物。 这种涂料组合物包括油墨，地板饰面，套印清漆，上浆，油漆和粘合剂。

公开(公告)号：US5399612A

公开(公告)日：1995-03-21

申请号：US35539

申请日：1993-03-23

申请人： Glenn C. Calhoun

发明人： Glenn C. Calhoun

IPC分类号： C08L33/02 ,  C08L83/08 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D183/08

CPC分类号： C09D133/064 ,  C09D183/08 ,  C08L83/08 ,  Y10T428/31663

摘要： Novel polymeric compositions are disclosed. The polymeric compositions, in particular, are either soluble or readily dispersible in water. Such polymeric compositions can be characterized as polymeric blends containing at least one acid-functional vinyl polymer and at least one amino-functional siloxane polymer. The novel polymeric blends further include volatile aqueous media comprising water and base in an amount that is effective for preventing the acid-functional moieties of the vinyl polymer from chemically reacting with the amino-functional moieties of the siloxane polymer. Such compositions or "blends", in general, comprise 60-99.9 parts-by-weight of the acid-functional vinyl polymer and 0.1-40 parts-by-weight of the amino-functional siloxane polymer, based upon total weight of the blended polymeric composition. Also disclosed are methods of producing the blended polymeric composition. The blended polymeric compositions are able to provide various substrates with surface coatings that are characterized as quasi-crosslinked, alkali-soluble polymeric networks exhibiting enhanced surface properties.

摘要翻译： 公开了新的聚合物组合物。 聚合物组合物，特别是可溶于或容易分散在水中。 这种聚合物组合物可以表征为含有至少一种酸官能乙烯基聚合物和至少一种氨基官能的硅氧烷聚合物的聚合物共混物。 新型聚合物共混物还包括含有水和碱的挥发性水性介质，其量对于防止乙烯基聚合物的酸官能部分与硅氧烷聚合物的氨基官能部分发生化学反应有效。 通常，这样的组合物或“共混物”基于共混物的总重量，包含60-99.9重量份的酸官能的乙烯基聚合物和0.1-40重量份的氨基官能的硅氧烷聚合物 聚合物组合物。 还公开了制备共混聚合物组合物的方法。 共混的聚合物组合物能够提供具有表征为具有增强的表面性质的准交联的碱溶性聚合物网络的表面涂层的各种基材。

公开(公告)号：US06858678B2

公开(公告)日：2005-02-22

申请号：US10013752

申请日：2001-10-29

申请人： Kevin M. Andrist ,  John E. Blasko ,  Glenn C. Calhoun ,  Frederick C. Hansen ,  Dean R. Hellwig ,  Kurt A. Hessenius ,  Steven M. Hurley ,  D. Sunil Jayasuriya ,  Matthew G. Lee ,  Stephen J. Maccani ,  H. Thomas Mills, Jr. ,  Gregory R. Peterson ,  Paul E. Sandvick ,  Dennis M. Wilson ,  John P. Wiruth

发明人： Kevin M. Andrist ,  John E. Blasko ,  Glenn C. Calhoun ,  Frederick C. Hansen ,  Dean R. Hellwig ,  Kurt A. Hessenius ,  Steven M. Hurley ,  D. Sunil Jayasuriya ,  Matthew G. Lee ,  Stephen J. Maccani ,  H. Thomas Mills, Jr. ,  Gregory R. Peterson ,  Paul E. Sandvick ,  Dennis M. Wilson ,  John P. Wiruth

IPC分类号： C08L23/00 ,  B01F17/00 ,  C08F2/02 ,  C08F20/04 ,  C08F22/06 ,  C08F220/06 ,  C08F220/18 ,  C09D133/04 ,  C09G1/16 ,  C09J133/04 ,  D21H17/28 ,  D21H17/37 ,  D21H21/16 ,  C08F8/14

CPC分类号： B01F17/0085 ,  B01F17/0028 ,  B01F17/005 ,  C08F2/02 ,  C08F20/04 ,  C08F22/06 ,  C08F220/06 ,  C08F220/18 ,  C09G1/16 ,  D21H17/28 ,  D21H17/37 ,  D21H21/16

摘要： A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product. A polymeric surfactant includes at least one ethylenically unsaturated acid-functional monomer which has been radically incorporated into the polymeric surfactant and at least one ester of the incorporated ethylenically unsaturated acid-functional monomer which has a linear or branched chain alkyl group with greater than 11 carbon atoms. The molar critical micelle concentration of the polymeric surfactant is less than 1.0×10−2 moles/liter. Aqueous 2 percent solutions of certain polymeric surfactants have a surface tension of less than 45 mN/m at 30° C. and exhibit a decrease in surface tension of at least 5 mN/m as the temperature warms from 30° C. to 50° C.

摘要翻译： 连续本体聚合和酯化方法包括将至少一种烯属不饱和酸官能单体和至少一种具有大于11个碳原子的直链或支链链烷醇连续地加入到反应区中。 该方法包括保持通过反应区的流速足以提供小于60分钟的平均停留时间，并保持反应区中的温度足以产生聚合产物，该聚合物与至少一些烷醇作为聚合的 烯键式不饱和酸官能单体。 聚合物产品用于各种工艺中以生产水性组合物，包括乳液和分散体，例如油乳剂，蜡分散体，颜料分散体，表面活性剂和含有聚合产物的涂料。 聚合物表面活性剂包括至少一种烯键式不饱和酸官能单体，其已经自由地掺入聚合物表面活性剂和至少一种具有直链或支链烷基与大于11个碳的烯键式不饱和酸官能单体的酯 原子 聚合物表面活性剂的摩尔临界胶束浓度小于1.0×10 -2摩尔/升。 某些聚合物表面活性剂的2％水溶液在30℃下的表面张力小于45mN / m，并且随着温度从30℃升温到50℃，表面张力降低至少5mN / m C。

公开(公告)号：US20100048801A1

公开(公告)日：2010-02-25

申请号：US12611702

申请日：2009-11-03

申请人： Glenn C. Calhoun ,  Rodney M. Weston

发明人： Glenn C. Calhoun ,  Rodney M. Weston

IPC分类号： C08L41/00 ,  C08L31/00 ,  C08L39/00 ,  C08L33/06

CPC分类号： C08F2/10 ,  C08F2/06 ,  C08F220/14 ,  C08F220/18 ,  C08F220/34 ,  Y10T442/20 ,  Y10T442/60 ,  Y10T442/69

摘要： A method of making an ion triggerable cationic polymer by solution copolymerizing one or more vinyl-functional cationic monomers, one or more water insoluble or hydrophobic vinyl monomers with alkyl side chains up to 4 carbons long, and, optionally, a minor amount of one or more vinyl monomers with linear or branched alkyl groups longer than 4 carbons, alkyl hydroxy, polyoxyalkylene, or other functional groups. The solution polymerization is accomplished by free radical polymerization in a mixture of an organic solvent such as acetone and water. After polymerization is complete, the organic solvent is preferably removed by a continuous process. The continuous process is preferably performed using a plate evaporator system.

摘要翻译： 一种通过使一种或多种乙烯基官能阳离子单体，一种或多种水不溶性或疏水性乙烯基单体与最多4个碳原子的烷基侧链和任选地少量一个或多个乙烯基官能阳离子单体共聚而制备离子可触发阳离子聚合物的方法， 更多具有长于4个碳的直链或支链烷基的乙烯基单体，烷基羟基，聚氧化烯或其它官能团。 溶液聚合通过在有机溶剂如丙酮和水的混合物中的自由基聚合来完成。 聚合完成后，优选通过连续方法除去有机溶剂。 连续方法优选使用板式蒸发器系统进行。

公开(公告)号：US5147915A

公开(公告)日：1992-09-15

申请号：US759253

申请日：1991-09-13

申请人： Glenn C. Calhoun ,  Robert W. Stackman ,  Michael E. Klinkhammer

发明人： Glenn C. Calhoun ,  Robert W. Stackman ,  Michael E. Klinkhammer

IPC分类号： C09D5/00 ,  C09D5/14 ,  C09D133/14

CPC分类号： C09D5/14 ,  C09D133/14 ,  C09D5/00

摘要： An alkali-soluble coating formulation is disclosed. Such a coating formulation comprises a volatile, aqueous carrier; an alkali-soluble hydrophilic polymer, in the aqueous carrier; an alkali-soluble multivalent metal ion-containing bond-forming agent, also in the aqueous carrier; and an effective amount of a volatile alkali ingredient, in the aqueous carrier, for dissolving both the hydrophilic polymer as well as the multivalent metal ion-containing bond-forming agent. The relative amounts of hydrophilic polymer and multivalent metal ion-containing bond-forming agent, in the aqueous carrier, are effective for forming an alkali-soluble polymeric coating on a substrate, upon evaporation of the volatile, aqueous carrier therefrom.

摘要翻译： 公开了一种碱溶性涂料配方。 这种涂料制剂包含挥发性水性载体; 水溶性载体中的碱溶性亲水聚合物; 在水性载体中也是碱溶性多价金属离子的键合形成剂; 和水性载体中的有效量的挥发性碱成分，用于溶解亲水性聚合物以及多价金属离子的键合形成剂。 在水性载体中，亲水性聚合物和多价金属离子的结合剂形成剂的相对量，在挥发性水性载体从其上蒸发后，可有效地在基材上形成碱溶性聚合物涂层。

公开(公告)号：US07619033B2

公开(公告)日：2009-11-17

申请号：US11229413

申请日：2005-09-16

申请人： Glenn C. Calhoun ,  Rodney M. Weston

发明人： Glenn C. Calhoun ,  Rodney M. Weston

IPC分类号： C09D5/02

CPC分类号： C08F2/10 ,  C08F2/06 ,  C08F220/14 ,  C08F220/18 ,  C08F220/34 ,  Y10T442/20 ,  Y10T442/60 ,  Y10T442/69

摘要： A method of making an ion triggerable cationic polymer by solution copolymerizing one or more vinyl-functional cationic monomers, one or more water insoluble or hydrophobic vinyl monomers with alkyl side chains up to 4 carbons long, and, optionally, a minor amount of one or more vinyl monomers with linear or branched alkyl groups longer than 4 carbons, alkyl hydroxy, polyoxyalkylene, or other functional groups. The solution polymerization is accomplished by free radical polymerization in a mixture of an organic solvent such as acetone and water. After polymerization is complete, the organic solvent is preferably removed by a continuous process. The continuous process is preferably performed using a plate evaporator system.

摘要翻译： 一种通过使一种或多种乙烯基官能阳离子单体，一种或多种水不溶性或疏水性乙烯基单体与最多4个碳原子的烷基侧链和任选地少量一个或多个乙烯基官能阳离子单体共聚而制备离子可触发阳离子聚合物的方法， 更多具有长于4个碳的直链或支链烷基的乙烯基单体，烷基羟基，聚氧化烯或其它官能团。 溶液聚合通过在有机溶剂如丙酮和水的混合物中的自由基聚合来完成。 聚合完成后，优选通过连续方法除去有机溶剂。 连续方法优选使用板式蒸发器系统进行。

公开(公告)号：US06355727B1

公开(公告)日：2002-03-12

申请号：US09347035

申请日：1999-07-02

申请人： Kevin M. Andrist ,  John E. Blasko ,  Glenn C. Calhoun ,  Frederick C. Hansen ,  Dean R. Hellwig ,  Kurt A. Hessenius ,  Steven M. Hurley ,  D. Sunil Jayasuriya ,  Matthew G. Lee ,  Stephen J. Maccani ,  H. Thomas Mills, Jr. ,  Gregory R. Peterson ,  Paul E. Sandvick ,  Dennis M. Wilson ,  John P. Wiruth

发明人： Kevin M. Andrist ,  John E. Blasko ,  Glenn C. Calhoun ,  Frederick C. Hansen ,  Dean R. Hellwig ,  Kurt A. Hessenius ,  Steven M. Hurley ,  D. Sunil Jayasuriya ,  Matthew G. Lee ,  Stephen J. Maccani ,  H. Thomas Mills, Jr. ,  Gregory R. Peterson ,  Paul E. Sandvick ,  Dennis M. Wilson ,  John P. Wiruth

IPC分类号： C08F2004

CPC分类号： B01F17/0085 ,  B01F17/0028 ,  B01F17/005 ,  C08F2/02 ,  C08F20/04 ,  C08F22/06 ,  C08F220/06 ,  C08F220/18 ,  C09G1/16 ,  D21H17/28 ,  D21H17/37 ,  D21H21/16

摘要： A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes including maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product. A polymeric surfactant includes at least one ethylenically unsaturated acid-functional monomer which has been radically incorporated into the polymeric surfactant and at least one ester of the incorporated ethylenically unsaturated acid-functional monomer which has a linear or branched chain alkyl group with greater than 11 carbon atoms. The molar critical micelle concentration of the polymeric surfactant is less than 1.0×10−2 moles/liter. Aqueous 2 percent neutralized solutions of certain polymeric surfactants have a surface tension of less than 45 mN/m at 30° C. and exhibit a decrease in surface tension of at least 5 mN/m as the temperature warms from 30° C. to 50° C.

摘要翻译： 连续本体聚合和酯化方法包括将至少一种烯属不饱和酸官能单体和至少一种具有大于11个碳原子的直链或支链链烷醇连续地加入到反应区中。 该方法包括保持通过反应区的流速足以提供小于60分钟的平均停留时间，并保持反应区中的温度足以产生聚合产物，该聚合物与至少一些烷醇作为 聚合的烯键式不饱和酸官能单体。 聚合物产品用于各种工艺中以生产水性组合物，包括乳液和分散体，例如油乳剂，蜡分散体，颜料分散体，表面活性剂和含有聚合产物的涂料。 聚合物表面活性剂包括至少一种烯键式不饱和酸官能单体，其已经自由地掺入聚合物表面活性剂和至少一种具有直链或支链烷基与大于11个碳的烯键式不饱和酸官能单体的酯 原子 聚合物表面活性剂的摩尔临界胶束浓度小于1.0×10 -2摩尔/升。 某些聚合物表面活性剂的2％中和水溶液的表面张力在30℃时的表面张力小于45mN / m，并且随着温度从30℃升至50℃，表面张力降低至少5mN / m C。