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1.发明授权公开(公告)号：US07456124B2
公开(公告)日：2008-11-25
申请号：US11843719
申请日：2007-08-23
申请人： Edwin P. Boldingh , Antoine Negiz , James E. Rekoske , Eric J. Baker , Robert B. Larson , Terrence E. Deak , Sergey V. Gurevich
发明人： Edwin P. Boldingh , Antoine Negiz , James E. Rekoske , Eric J. Baker , Robert B. Larson , Terrence E. Deak , Sergey V. Gurevich
IPC分类号： B01J29/06
CPC分类号： B01J29/80 , B01J29/26 , B01J29/48 , B01J37/0009 , B01J37/08 , B01J37/14 , B01J37/18 , B01J37/20 , B01J2229/20 , B01J2229/42 , C07C6/123 , C07C6/126 , C07C2529/18 , C07C2529/26 , C07C2529/80 , Y02P20/52 , C07C15/08
摘要： Transalkylation catalysts containing rhenium and a molecular sieve component comprising an acidic MFI molecular sieve having a Si/Al2 molar ratio of less than about 80 and mordenite provide a transalkylation product with a low content of benzene co-boilers. The invention encompasses sulfided catalyst embodiments and methods of making the catalysts.
摘要翻译： 含有铼的分子筛催化剂和包含Si / Al 2摩尔比小于约80的酸性MFI分子筛和丝光沸石的分子筛组分提供了具有低含量苯共锅炉的烷基转移产物 。 本发明包括硫化催化剂实施方案和制备催化剂的方法。
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公开(公告)号：US20110046427A1
公开(公告)日：2011-02-24
申请号：US12917045
申请日：2010-11-01
IPC分类号： C07C15/08
摘要： A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.
摘要翻译： 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理（如加氢处理，氢化或用粘土和/或分子筛处理）的必要性。
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公开(公告)号：US07847137B2
公开(公告)日：2010-12-07
申请号：US11830424
申请日：2007-07-30
摘要： A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.
摘要翻译： 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理（如加氢处理，氢化或用粘土和/或分子筛处理）的必要性。
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4.发明授权Processes for producing xylenes using isomerization and transalkylation reactions and apparatus therefor 失效使用异构化和烷基转移反应生产二甲苯的方法及其设备公开(公告)号：US07615197B2
公开(公告)日：2009-11-10
申请号：US11945617
申请日：2007-11-27
CPC分类号： B01J8/0457 , B01J8/0453 , B01J8/0492 , B01J2219/00006 , C07C6/126 , C07C15/08
摘要： Processes for making xylene isomer using integrated transalkylation and isomerization reaction zones to enhance xylene recovery and enable reduction in capital costs and energy consumption.
摘要翻译： 使用整合的烷基转移反应区和异构化反应区制备二甲苯异构体的方法，以增强二甲苯回收率，并降低资本成本和能源消耗。
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公开(公告)号：US20090032386A1
公开(公告)日：2009-02-05
申请号：US11830460
申请日：2007-07-30
IPC分类号： B01D3/14
CPC分类号： C10G29/205
摘要： An apparatus for producing a xylene isomer, which integrates the removal of olefins into a reaction zone of the apparatus is disclosed. Apparatus of this invention enable the use of aromatic feedstocks containing olefins and reduce or eliminate the need for feed pretreatment by olefin removal assemblies or zones such as hydrotreating, hydrogenation, and clay and/or molecular sieve treating, thereby reducing capital and operating costs.
摘要翻译： 公开了一种用于生产二甲苯异构体的装置，其将烯烃的除去整合到装置的反应区中。 本发明的装置能够使用含有烯烃的芳族原料，并减少或消除了通过烯烃去除组件或诸如加氢处理，氢化和粘土和/或分子筛处理的区域的进料预处理的需要，从而降低了资金和运行成本。
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公开(公告)号：US08563795B2
公开(公告)日：2013-10-22
申请号：US12689751
申请日：2010-01-19
申请人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Dean E. Rende , James E. Rekoske , David E. Mackowiak , Paul Barger
发明人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Dean E. Rende , James E. Rekoske , David E. Mackowiak , Paul Barger
IPC分类号： C07C2/66
摘要： One exemplary embodiment can be a process using an aromatic methylating agent. Generally, the process includes reacting an effective amount of the aromatic methylating agent having at least one of an alkane, a cycloalkane, an alkane radical, and a cycloalkane radical with one or more aromatic compounds. As such, at least one of the one or more aromatic compounds may be converted to one or more higher methyl substituted aromatic compounds to provide a product having a greater mole ratio of methyl to phenyl than a feed.
摘要翻译： 一个示例性实施方案可以是使用芳族甲基化剂的方法。 通常，该方法包括将有效量的具有烷烃，环烷烃，烷烃基和环烷烃基团中的至少一种的芳族甲基化试剂与一种或多种芳族化合物反应。 因此，一种或多种芳族化合物中的至少一种可以转化为一种或多种高级甲基取代的芳族化合物，以提供具有比进料更大的甲基与苯基的摩尔比的产物。
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公开(公告)号：US20110178356A1
公开(公告)日：2011-07-21
申请号：US12689560
申请日：2010-01-19
申请人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Dean E. Rende , James E. Rekoske , David E. Mackowiak , Paul Barger
发明人： Antoine Negiz , Edwin P. Boldingh , Gregory J. Gajda , Dean E. Rende , James E. Rekoske , David E. Mackowiak , Paul Barger
IPC分类号： C07C5/52
CPC分类号： C07C2/76 , C10G29/205 , C10G2300/104 , C10G2300/1044 , C10G2300/1081 , C10G2300/1096 , C10G2400/02 , C10G2400/30 , C07C15/06 , C07C15/08 , C07C15/073 , C07C15/02
摘要： One exemplary embodiment can be a process for increasing a mole ratio of methyl to phenyl of one or more aromatic compounds in a feed. The process can include reacting an effective amount of one or more aromatic compounds and an effective amount of one or more aromatic methylating agents to form a product having a mole ratio of methyl to phenyl of at least about 0.1:1 greater than the feed.
摘要翻译： 一个示例性实施方案可以是提高进料中一种或多种芳族化合物的甲基与苯基的摩尔比的方法。 该方法可以包括使有效量的一种或多种芳族化合物和有效量的一种或多种芳族甲基化剂反应以形成比进料大至少约0.1:1的甲基与苯基的摩尔比的产物。
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公开(公告)号：US07566810B2
公开(公告)日：2009-07-28
申请号：US11843718
申请日：2007-08-23
申请人： Edwin P. Boldingh , Antoine Negiz , James E. Rekoske , Eric J. Baker , Robert B. Larson , Terrence E. Deak , Sergey V. Gurevich
发明人： Edwin P. Boldingh , Antoine Negiz , James E. Rekoske , Eric J. Baker , Robert B. Larson , Terrence E. Deak , Sergey V. Gurevich
IPC分类号： C07C6/12
CPC分类号： B01J29/80 , B01J29/26 , B01J29/48 , B01J37/0009 , B01J37/08 , B01J37/14 , B01J37/18 , B01J37/20 , B01J2229/20 , B01J2229/42 , C07C6/123 , C07C6/126 , C07C2529/18 , C07C2529/26 , C07C2529/80 , Y02P20/52 , C07C15/08
摘要： Processes for making xylene employ catalysts containing rhenium and a molecular sieve component comprising an acidic MFI molecular sieve having a Si/Al2 molar ratio of less than about 80 and mordenite to provide a transalkylation product with a low content of benzene co-boilers. The invention encompasses the use of sulfided catalyst embodiments in xylene production processes.
摘要翻译： 制备二甲苯的方法使用含有铼的催化剂和包含Si / Al 2摩尔比小于约80的酸性MFI分子筛和丝光沸石的分子筛组分，以提供具有低含量苯共沸器的烷基转移产物。 本发明包括在二甲苯生产方法中使用硫化催化剂实施方案。
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公开(公告)号：US20090036724A1
公开(公告)日：2009-02-05
申请号：US11830424
申请日：2007-07-30
IPC分类号： C07C15/08
摘要： A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.
摘要翻译： 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理（如加氢处理，氢化或用粘土和/或分子筛处理）的必要性。
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公开(公告)号：US08044253B2
公开(公告)日：2011-10-25
申请号：US12917045
申请日：2010-11-01
摘要： A process for aromatic transalkylation and olefin reduction of a feed stream is disclosed. Transalkylation conditions provide a product having increased xylene concentration and reduced olefin concentration relative to the feed. The process may be used in a xylene production facility to minimize or avoid the necessity of feedstock pretreatment such as hydrotreating, hydrogenation, or treating with clay and/or molecular sieves.
摘要翻译： 公开了一种进料流的芳族烷基转移和烯烃还原方法。 烷基转移条件提供了相对于进料的二甲苯浓度增加和烯烃浓度降低的产物。 该方法可用于二甲苯生产设备中以最小化或避免原料预处理（如加氢处理，氢化或用粘土和/或分子筛处理）的必要性。
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