-
公开(公告)号:US20210376239A1
公开(公告)日:2021-12-02
申请号:US16637365
申请日:2018-08-07
申请人: ARKEMA FRANCE , UNIVERSITE DE BORDEAUX , INSTITUT POLYTECHNIQUE DE BORDEAUX , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
摘要: The invention relates to a composition comprising a blend of fluorinated electroactive polymers and having a dielectric permittivity that exhibits greater stability over the operating temperature range with respect to each polymer employed on its own. The invention also relates to formulations and films produced on the basis of said composition. The invention also relates to a field-effect transistor, at least part of the dielectric layer of which is composed of a blend of fluorinated electroactive polymers.
-
公开(公告)号:US20220098343A1
公开(公告)日:2022-03-31
申请号:US17414444
申请日:2019-12-16
申请人: Arkema France , UNIVERSITE DE BORDEAUX , INSTITUT POLYTECHNIQUE DE BORDEAUX , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人: Georges HADZIIOANNOU , Eric CLOUTET , Cyril BROCHON , Konstantinos KALLITSIS , Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN
IPC分类号: C08F214/22 , C08F8/06 , C08J5/18 , C08L27/16
摘要: A copolymer including units derived from fluoro monomers of formula (I): CX1X2═CX3X4 (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, the H and/or F atoms of the fluoro monomers being partially replaced with photoactive groups of formula —Y—Ar—R in the copolymer; Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, preferably a phenyl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. The fluoro monomers of formula (I) of the copolymer include vinylidene fluoride and trifluoroethylene. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from the copolymer.
-
公开(公告)号:US20200157365A1
公开(公告)日:2020-05-21
申请号:US16633297
申请日:2018-07-17
申请人: ARKEMA FRANCE , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , Universite De Montpellier , ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER
发明人: Thierry LANNUZEL , Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN , Vincent LADMIRAL , Bruno AMEDURI
IPC分类号: C09D11/106 , C08L27/16 , C08K5/06 , C08F214/24 , C08K5/36 , C08L83/08 , C08K5/17 , C08L47/00 , C08K5/00 , C08K5/10 , C08K5/07 , C08K5/521 , C09D11/101
摘要: A process for preparing a crosslinked fluoropolymer film, including the successive steps of: (1) formulating an ink containing: (a) the product of the reaction of triethylamine with at least one fluorinated copolymer obtained by radical copolymerization of monomers including: (i) vinylidene fluoride (VDF), (ii) trifluoroethylene (TrFE), (iii) at least one chlorinated monomer of formula —CXCl═CX1X2 where X, X1 and X2 independently denote H, F or CF3, wherein at most one of X, X1 and X2 denotes CF3; (b) at least one crosslinking agent; (c) at least one photoinitiator; and (d) at least one organic solvent; (2) applying said ink in film form to a substrate; and (3) UV-irradiating said film. Also, the film capable of being obtained according to this process, and also to the uses thereof, in particular in the manufacture of (opto)electronic devices and more particularly in the manufacture of a gate dielectric layer in a field-effect transistor.
-
公开(公告)号:US20200207970A1
公开(公告)日:2020-07-02
申请号:US16622422
申请日:2018-06-13
申请人: Arkema France
IPC分类号: C08L27/16 , C09D11/106 , C09D11/52 , H01L23/29
摘要: A composition including: a PF polymer including units derived from vinylidene fluoride; and a PA polymer including units derived from a (meth)acrylic monomer and units including at least one associative group chosen among imidazolidonyl, triazolyl, triazinyl, bis-ureyl and ureido-pyrimidyl groups; in solution in a solvent. Also, the use of this composition for the production of electronic devices.
-
公开(公告)号:US20200157334A1
公开(公告)日:2020-05-21
申请号:US16631882
申请日:2018-07-16
申请人: Arkema France , UNIVERSITE DE BORDEAUX , INSTITUT POLYTECHNIQUE DE BORDEAUX , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人: Georges HADZIIOANNOU , Eric CLOUTET , Cyril BROCHON , Damien THUAU , Konstantinos KALLITSIS , Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN
IPC分类号: C08L27/16 , C08F214/16 , C08F214/04 , C08F8/30 , C08F214/24 , C08F214/22
摘要: The invention relates to a copolymer comprising units derived from monomers of vinylidene fluoride and/or trifluoroethylene, as well as fluorinated monomers X comprising a double bond and a leaving group selected from among chlorine, bromine and iodine atoms, the leaving groups being partially replaced by azide groups in the copolymer.
-
6.
公开(公告)号:US20240110054A1
公开(公告)日:2024-04-04
申请号:US18267757
申请日:2021-12-15
申请人: ARKEMA FRANCE
IPC分类号: C08L33/12 , B06B1/06 , H10N30/00 , H10N30/098 , H10N30/857
CPC分类号: C08L33/12 , B06B1/0688 , H10N30/098 , H10N30/1061 , H10N30/857 , C08L2203/20
摘要: A composite article including at least one electronic system, integrated onto the surface or in the volume of a thermoplastic matrix. The electronic system includes at least one piezoelectric transducer and means for transmitting an electrical signal. The piezoelectric transducer includes a piezoelectric polymer essentially consisting of, or consisting of, repeating units derived from vinylidene fluoride (VDF) and vinylidene trifluoride (TrFE), the molar proportion of the unit derived from TrFE being from 15% to 50% relative to the total number of moles of the units derived from VDF and TrFE. Also, the use of the electronic system and to the use of the article.
-
公开(公告)号:US20220411550A1
公开(公告)日:2022-12-29
申请号:US17414721
申请日:2019-12-16
申请人: ARKEMA FRANCE , UNIVERSITE DE BORDEAUX , INSTITUT POLYTECHNIQUE DE BORDEAUX , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人: Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN , Georges HADZIIOANNOU , Eric CLOUTET , Cyril BROCHON , Konstantinos KALLITSIS
IPC分类号: C08F214/22 , C08F214/24 , C08F220/18 , G03F7/004 , G03F7/033 , G03F7/30
摘要: A copolymer including fluorinated units of formula (I): —CX1X2—CX3X4— (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and fluorinated units of formula (II): —CX5X6—CX7Z— (II) in which each of the X5, X6 and X7 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and in which Z is a photoactive group of formula —Y—Ar—R, Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from this copolymer.
-
公开(公告)号:US20180312618A1
公开(公告)日:2018-11-01
申请号:US15769275
申请日:2016-10-18
申请人: Arkema France , Centre National de la Recherche Scientifique , Universite de Montpellier , Ecole Nationale Superieure de Chimie de Montpellier
发明人: Thierry T. Lannuzel , Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN , Vincent LADMIRAL , Bruno AMEDURI
IPC分类号: C08F214/22 , C09D127/24 , C09D127/16 , C08F8/22 , C08F8/40 , C09D127/22 , C08F8/30
CPC分类号: C08F214/227 , C08F8/22 , C08F8/30 , C08F8/40 , C08F214/22 , C08F216/1408 , C08F2800/10 , C09D127/16 , C09D127/22 , C09D127/24 , C08F214/247
摘要: “The invention relates to a fluorinated copolymers which are particularly based on vinylidene fluoride (VDF) or trifluoroethylene (TrFE) and particularly functionalized by functional and/or functionizable vinyl ethers. The invention also relates to methods for producing said copolymers, and to the applications thereof.”
-
公开(公告)号:US20230022870A1
公开(公告)日:2023-01-26
申请号:US17784438
申请日:2020-12-11
申请人: Arkema France , UNIVERSITE DE BORDEAUX , INSTITUT POLYTECHNIQUE DE BORDEAUX , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人: Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN , Florian LE GOUPIL , Konstantinos KALLITSIS , Georges HADZIIOANNOU
IPC分类号: C09K5/14
摘要: A polymer including VDF-based units having an electrocaloric effect under the effect of a variable electric field. The polymer includes 0.1 to 10.0 mol % double bonds, which are substantially non-conjugated. Also, a corresponding composition including the polymer, a corresponding film including the polymer, and to various uses of the polymer.
-
公开(公告)号:US20220073663A1
公开(公告)日:2022-03-10
申请号:US17414459
申请日:2019-12-16
申请人: ARKEMA FRANCE , UNIVERSITE DE BORDEAUX , INSTITUT POLYTECHNIQUE DE BORDEAUX , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
发明人: Fabrice DOMINGUES DOS SANTOS , Thibaut SOULESTIN , Georges HADZIIOANNOU , Eric CLOUTET , Cyril BROCHON , Konstantinos KALLITSIS
IPC分类号: C08F214/22 , C09D127/16 , C09D5/24 , H01L51/00 , C09D11/106 , C09D11/52 , H01L41/193
摘要: A copolymer including fluorinated units of formula (I): —CX1X2—CX3X4— (I) in which each of the X1, X2, X3 and X4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and units of formula (III): —CXAXB—CXCZ— (III) in which each of the XA, XB and XC is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and Z being a polarizable group of formula —Y—Ar—R; Y representing an O atom or an S atom or an NH group, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms; and the copolymer having a heat of fusion of greater than or equal to 5 J/g. Also a process, a composition, an ink and a film.
-
-
-
-
-
-
-
-
-