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1.发明授权公开(公告)号：US07799184B2
公开(公告)日：2010-09-21
申请号：US11558295
申请日：2006-11-09
CPC分类号： C22B3/045 , C22B7/006 , C22B11/042 , C22B34/36 , Y02P10/214 , Y02P10/234
摘要： Process for the electrochemical decomposition of precursors in powder form by introducing a powder batch between two electrodes of an electrolysis cell, electrodes being designed to be liquid-permeable, and the electrolyte flowing through the powder batch perpendicularly to the electrode surfaces, and electrolysis cell suitable therefor, which is essentially characterized in that at least one electrode has a structure which consists of a supporting pierced plate (5), an electrode plate (3) provided with perforations, and a filter cloth (4) arranged between the supporting pierced plate (5) and the electrode plate (3), and in that the cathode (6) is shielded from the cell by means of a liquid-permeable separator (7).
摘要翻译： 通过在电解池的两个电极之间引入粉末批料，设计为液体可渗透的电极以及垂直于电极表面流过粉末批料的电解质，以及电解槽适用于电化学分解粉末形式的前体的方法 其特征在于，至少一个电极具有由支撑穿孔板（5），设置有穿孔的电极板（3）和布置在支撑穿孔板（4）之间的滤布 5）和电极板（3），并且阴极（6）通过透液分离器（7）与电池屏蔽。
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2.发明申请公开(公告)号：US20070256931A1
公开(公告)日：2007-11-08
申请号：US11558295
申请日：2006-11-09
IPC分类号： C25B9/00
CPC分类号： C22B3/045 , C22B7/006 , C22B11/042 , C22B34/36 , Y02P10/214 , Y02P10/234
摘要： Process for the electrochemical decomposition of precursors in powder form by introducing a powder batch between two electrodes of an electrolysis cell, electrodes being designed to be liquid-permeable, and the electrolyte flowing through the powder batch perpendicularly to the electrode surfaces, and electrolysis cell suitable therefor, which is essentially characterized in that at least one electrode has a structure which consists of a supporting pierced plate (5), an electrode plate (3) provided with perforations, and a filter cloth (4) arranged between the supporting pierced plate (5) and the electrode plate (3), and in that the cathode (6) is shielded from the cell by means of a liquid-permeable separator (7).
摘要翻译： 通过在电解池的两个电极之间引入粉末批料，设计为液体可渗透的电极以及垂直于电极表面流过粉末批料的电解质，以及电解槽适用于电化学分解粉末形式的前体的方法 其特征在于，至少一个电极具有由支撑穿孔板（5），设置有穿孔的电极板（3）和布置在支撑穿孔板（4）之间的滤布 5）和电极板（3），并且阴极（6）通过透液分离器（7）与电池屏蔽。
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3.发明授权公开(公告)号：US07144493B2
公开(公告)日：2006-12-05
申请号：US10413958
申请日：2003-04-15
CPC分类号： C22B3/045 , C22B7/006 , C22B11/042 , C22B34/36 , Y02P10/214 , Y02P10/234
摘要： Process for the electrochemical decomposition of precursors in powder form by introducing a powder batch between two electrodes of an electrolysis cell, electrodes being designed to be liquid-permeable, and the electrolyte flowing through the powder batch perpendicularly to the electrode surfaces, and electrolysis cell suitable therefor, which is essentially characterized in that at least one electrode has a structure which consists of a supporting pierced plate (5), an electrode plate (3) provided with perforations, and a filter cloth (4) arranged between the supporting pierced plate (5) and the electrode plate (3), and in that the cathode (6) is shielded from the cell by means of a liquid-permeable separator (7).
摘要翻译： 通过在电解池的两个电极之间引入粉末批料，设计为液体可渗透的电极以及垂直于电极表面流过粉末批料的电解质，以及电解槽适用于电化学分解粉末形式的前体的方法 其特征在于，至少一个电极具有由支撑穿孔板（5），设置有穿孔的电极板（3）和布置在支撑穿孔板（4）之间的滤布 5）和电极板（3），并且阴极（6）通过透液分离器（7）与电池屏蔽。
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公开(公告)号：US20080110767A1
公开(公告)日：2008-05-15
申请号：US11741347
申请日：2007-06-21
申请人： Viktor Stoller , Armin Olbrich , Juliane Meese-Marktscheffel , Wolfgang Mathy , Michael Erb , Georg Nietfeld , Gerhard Gille
发明人： Viktor Stoller , Armin Olbrich , Juliane Meese-Marktscheffel , Wolfgang Mathy , Michael Erb , Georg Nietfeld , Gerhard Gille
IPC分类号： B23H3/00
CPC分类号： C22B3/045 , C22B7/007 , C22B11/046 , Y02P10/214 , Y02P10/234
摘要： A process for recovery of valuable metals from superalloys by electrochemical decomposition is described, both electrodes being formed by the superalloy and the polarity of the electrolysis current being reversed with a frequency of from 0.005 to 5 Hz.
摘要翻译： 描述了通过电化学分解从超级合金中回收有价值金属的方法，两个电极由超级合金形成，并且电解电流的极性以0.005至5Hz的频率反转。
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公开(公告)号：US06936090B2
公开(公告)日：2005-08-30
申请号：US10288908
申请日：2002-11-06
CPC分类号： C01G47/003 , C22B3/24 , C22B11/048 , Y02P10/214 , Y02P10/234
摘要： A process for elution of rhenium adsorbed on strongly basic ion-exchange resins by means of highly concentrated aqueous hydrochloric acid solution is described, in which the ion-exchange resin is treated with aqueous solution containing an oxidizing agent.
摘要翻译： 描述了通过高浓度盐酸水溶液洗脱强碱性离子交换树脂上的铼的方法，其中用含有氧化剂的水溶液处理离子交换树脂。
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公开(公告)号：US07048843B2
公开(公告)日：2006-05-23
申请号：US10311396
申请日：2001-06-06
申请人： Armin Olbrich , Astrid Görge , Frank Schrumpf , Juliane Meese-Marktscheffel , Viktor Stoller , Gerhard Gille , Josef Schmoll , Michael Kruft , Dirk Naumann
发明人： Armin Olbrich , Astrid Görge , Frank Schrumpf , Juliane Meese-Marktscheffel , Viktor Stoller , Gerhard Gille , Josef Schmoll , Michael Kruft , Dirk Naumann
CPC分类号： C25B1/00
摘要： The invention relates to a method for producing metal hydroxides or alkaline metal carbonates by anode dissolution of the corresponding metals and precipitation of the hydroxides or alkaline carbonates in an aqueous medium. The anode dissolution of the metal components is carried out in the anode compartment of a three-compartment electrolytic cell. An aqueous auxiliary salt solution is fed to an intermediate compartment that is disposed between the anode compartment and the cathode compartment and that is separated therefrom by a porous membrane. An at least not alkaline metal salt solution is continuously taken from the anode compartment while an alkaline auxiliary salt solution is continuously taken from the cathode compartment. The at least not alkaline metal salt solution and the alkaline auxiliary salt solution are combined outside the electrolytic cell for the purpose of precipitating metal hydroxides or alkaline metal carbonates.
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公开(公告)号：US06752918B1
公开(公告)日：2004-06-22
申请号：US10009543
申请日：2001-11-05
申请人： Armin Olbrich , Viktor Stoller , Juliane Meese-Marktscheffel , Frank Schrumpf , Josef Schmoll , Gerhard Gille
发明人： Armin Olbrich , Viktor Stoller , Juliane Meese-Marktscheffel , Frank Schrumpf , Josef Schmoll , Gerhard Gille
IPC分类号： C25B100
CPC分类号： C25B1/00
摘要： A process is described for the production of spherical nickel hydroxide by anodic dissolution of a nickel electrode and precipitation of nickel hydroxide in a completely intermixed electrolysis cell, wherein an electrolysis brine is used which has a content of 20 to 50 g/l of chloride ions and 1 to 7 g/l of ammonia with a pH value of 9.5 to 11.5 and a temperature of 45 to 60° C.
摘要翻译： 描述了通过镍电极的阳极溶解和氢氧化镍在完全混合的电解池中沉淀来制造球形氢氧化镍的方法，其中使用电解盐水，其含量为20至50g / l氯离子 和1至7g / l氨，pH值为9.5至11.5，温度为45至60℃。
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公开(公告)号：US07217366B2
公开(公告)日：2007-05-15
申请号：US10935563
申请日：2004-09-07
CPC分类号： C01G39/00 , C22B3/42 , C22B34/34 , Y02P10/234
摘要： A process for reducing the content of alkali metal impurities (e.g., potassium) in ammonium metallate solutions is described. The process involves subjecting a feed solution containing ammonium metallate and alkali metal impurities to membrane filtration. The membrane filtration results in the formation of a retentate having a reduced level alkali metal relative to the feed solution, and a permeate containing substantially the balance of alkali metal. The permeate may also be further treated, to remove alkali metal there from, by passage through a cation exchange column, thereby forming a cation exchange treated permeate that may be combined with the retentate of the membrane filtration step.
摘要翻译： 描述了一种降低金属铵盐溶液中碱金属杂质（例如钾）含量的方法。 该方法包括使含有金属铵盐和碱金属杂质的进料溶液进行膜过滤。 膜过滤导致相对于进料溶液形成具有降低的碱金属含量的渗余物，和形成基本上余量的碱金属的渗透物。 也可以进一步处理渗透物，以通过阳离子交换柱除去碱金属，从而形成阳离子交换处理的渗透物，其可与膜过滤步骤的渗余物组合。
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公开(公告)号：US07563431B2
公开(公告)日：2009-07-21
申请号：US10488441
申请日：2002-06-24
申请人： Armin Olbrich , Juliane Meese-Marktscheffel , Viktor Stoller , Michael Erb , Sven Albrecht , Gerhard Gille , Gerd Maikowske , Frank Schrumpf , Josef Schmoll , Matthias Jahn
发明人： Armin Olbrich , Juliane Meese-Marktscheffel , Viktor Stoller , Michael Erb , Sven Albrecht , Gerhard Gille , Gerd Maikowske , Frank Schrumpf , Josef Schmoll , Matthias Jahn
IPC分类号： C01B13/00
CPC分类号： H01M4/366 , C01G53/04 , C01P2002/60 , C01P2004/61 , C01P2006/20 , C01P2006/40 , C01P2006/60 , H01M4/32 , H01M4/52 , H01M10/345
摘要： A process for preparing nickel hydroxide by alkaline precipitation from nickel salt solutions in the presence of complexing agents, in which the precipitation is carried out at at least two different locations in the same mother liquor with different precipitation kinetics at the different locations and the mother liquor is mixed prior to agglomeration of the precipitated primary crystals, is described.
摘要翻译： 一种在络合剂存在下，由镍盐溶液碱沉淀制备氢氧化镍的方法，其中沉淀是在不同位置的不同沉淀动力学的同一母液中的至少两个不同位置进行的，母液 在沉淀的一次晶体凝聚之前进行混合。
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公开(公告)号：US20050072735A1
公开(公告)日：2005-04-07
申请号：US10935563
申请日：2004-09-07
IPC分类号： B01D61/14 , B01J39/04 , C01G1/00 , C01G39/00 , C01G39/02 , C22B3/00 , C22B34/30 , C22B34/34 , B01D61/00
CPC分类号： C01G39/00 , C22B3/42 , C22B34/34 , Y02P10/234
摘要： A process for reducing the content of alkali metal impurities (e.g., potassium) in ammonium metallate solutions is described. The process involves subjecting a feed solution containing ammonium metallate and alkali metal impurities to membrane filtration. The membrane filtration results in the formation of a retentate having a reduced level alkali metal relative to the feed solution, and a permeate containing substantially the balance of alkali metal. The permeate may also be further treated, to remove alkali metal there from, by passage through a cation exchange column, thereby forming a cation exchange treated permeate that may be combined with the retentate of the membrane filtration step.
摘要翻译： 描述了一种降低金属铵盐溶液中碱金属杂质（例如钾）含量的方法。 该方法包括使含有金属铵盐和碱金属杂质的进料溶液进行膜过滤。 膜过滤导致相对于进料溶液形成具有降低的碱金属含量的渗余物，和形成基本上余量的碱金属的渗透物。 也可以进一步处理渗透物，以通过阳离子交换柱除去碱金属，从而形成阳离子交换处理的渗透物，其可与膜过滤步骤的渗余物组合。
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