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    Polymeric antioxidants
    6.
    发明授权
    Polymeric antioxidants 失效
    聚合物抗氧化剂

    公开(公告)号：US07595074B2

    公开(公告)日：2009-09-29

    申请号：US10761933

    申请日：2004-01-21

    申请人： Ashok L. Cholli ,  Vijayendra Kumar ,  Ashish Dhawan ,  Jayant Kumar ,  Virinder Singh Parmar ,  Lynne Ann Samuelson ,  Ferdinando F. Bruno

    发明人： Ashok L. Cholli ,  Vijayendra Kumar ,  Ashish Dhawan ,  Jayant Kumar ,  Virinder Singh Parmar ,  Lynne Ann Samuelson ,  Ferdinando F. Bruno

    IPC分类号： A23D7/00

    CPC分类号： A23G3/36 ,  A23G4/06 ,  A23L3/3463 ,  A23L3/349 ,  A23L13/42 ,  C09K15/08 ,  C09K15/10 ,  C09K15/12 ,  C09K15/18 ,  C09K15/20 ,  C10M2207/026 ,  C10M2209/10 ,  C11B5/0035

    摘要： A method of preparing a phenolic polymer comprising: a) protecting at least one hydroxyl group of a substituted or unsubstituted phenol represented by Structural Formula (XXIX), wherein: R11, R12, R13, R14 and R15 are independently —H, —OH, —NH, —SH, a substituted or unsubstituted alkyl or aryl group, a substituted or unsubstituted alkoxycarbonyl or aryloxycarbonyl group, a substituted or unsubstituted alkoxy group or a saturated or unsaturated carboxylic acid group; or R11, R12, R13, R14 or R15, in conjunction with an adjacent R11, R12, R13, R14 or R15, forms a substituted or unsubstituted alkylene dioxy group; provided that at least one of R11, R12, R13, R14 or R15 is a tert-butyl group 1-ethenyl-2-carboxylic acid or ester thereof, a substituted or unsubstituted alkylene dioxy group or a substituted or unsubstituted n-alkoxycarbonyl group, at least one of R11, R12, R13, R14 or R15 is a hydroxyl group, and at least one of R11, R12, R13, R14 and R15 is —H; with a protecting group, wherein thereby obtaining one or more protected hydroxyl groups; and b) polymerizing the substituted or unsubstituted phenol, thereby obtaining the phenolic polymer.

    摘要翻译： 一种制备酚醛聚合物的方法，包括：a）保护由结构式（XXIX）表示的取代或未取代的酚的至少一个羟基，其中：R 11，R 12，R 13，R 14和R 15独立地为-H，-OH， -NH，-SH，取代或未取代的烷基或芳基，取代或未取代的烷氧基羰基或芳氧基羰基，取代或未取代的烷氧基或饱和或不饱和羧酸基团; 或R11，R12，R13，R14或R15与相邻的R11，R12，R13，R14或R15结合形成取代或未取代的亚烷基二氧基; 条件是R11，R12，R13，R14或R15中的至少一个是叔丁基1-乙烯基-2-羧酸或其酯，取代或未取代的亚烷基二氧基或取代或未取代的正烷氧基羰基， R 11，R 12，R 13，R 14或R 15中的至少一个为羟基，R 11，R 12，R 13，R 14和R 15中的至少一个为-H; 与保护基，其中由此获得一个或多个被保护的羟基; 和b）使取代或未取代的苯酚聚合，由此得到酚类聚合物。