Solid catalyst component for olefin polymerization catalysts
    1.
    发明授权
    Solid catalyst component for olefin polymerization catalysts 失效
    烯烃聚合催化剂的固体催化剂组分

    公开(公告)号:US4847227A

    公开(公告)日:1989-07-11

    申请号:US105586

    申请日:1987-10-08

    CPC分类号: C08F10/00

    摘要: A solid catalyst component for olefin polymerization catalysts prepared by suspending diethoxymagnesium (a) in an aromatic hydrocarbon (b) which is liquid at normal temperature and bringing the suspension into a first contact with titanium tetrachloride (c) to form a product and bringing it into a second contact with tianium tetrachloride (c) in such manner that a diester (d) of an aromatic dicarboxylic acid and calcium chloride (e) are allowed to coexist at any stage of the above suspending and/or contacts, the calcium chloride (e) being used in an amount of 1-2 grams per gram of the diethoxymagnesium (a). This solid catalyst component exhibits, when applied to the polymerization of olefins, a surprisingly enhanced polymerization activity per titanium atom and a high stereospecific performance and scarcely necessitates any deashing treatment, thus affording a great economical advantage.

    摘要翻译: 一种用于烯烃聚合催化剂的固体催化剂组分,其通过将二乙氧基镁(a)悬浮在常温下为液体的芳族烃(b)中并使悬浮液与四氯化钛(c)首次接触形成产物并使其进入 与四氯化钛(c)的第二次接触,使得芳族二羧酸和氯化钙(e)的二酯(d)在上述悬浮和/或接触的任何阶段共存,氯化钙(e )的用量为每克二乙氧基镁(a)1-2克。 当用于烯烃聚合时,该固体催化剂组分表现出惊人的增加的每个钛原子的聚合活性和高立体特异性性能,并且几乎不需要任何脱屑处理,从而提供了巨大的经济优势。

    Solid catalyst component for olefin polymerization catalysts
    2.
    发明授权
    Solid catalyst component for olefin polymerization catalysts 失效
    用于烯烃聚合催化剂的固体催化剂组分

    公开(公告)号:US4839321A

    公开(公告)日:1989-06-13

    申请号:US141523

    申请日:1988-01-07

    CPC分类号: C08F10/00

    摘要: A solid catalyst component for olefin polymerization catalysts prepared by subjecting diethoxymagnesium (a), calcium chloride (b) and a silicon compound (c) of the general formula: Si(OR).sub.4 (wherein R is an alkyl or aryl group) together to a contact treatment in the presence of an organic solvent (d), suspending the treated composition in an aromatic hydrocarbon (e) which is liquid at normal temperature and bringing the suspension into a first contact with titanium tetrachloride (f) to form a product and bringing it to a second contact with titanium tetrachloride (f) in such manner that a diester (g) of an aromatic dicarboxylic acid is allowed to coexist at any stage of the above suspending and/or contacts with the exception of the contact treatment, the calcium chloride (b) being used in an amount of 1-2 g per gram of the diethoxymagnesium (a). This solid catalyst component exhibits, when applied to the polymerization of olefins, a surprisingly enhanced polymerization activity per titanium atom and a high stereospecific performance and scarcely necessitates any deashing treatment, thus affording a great economical advantage.

    摘要翻译: 将通式为Si(OR)4(其中R为烷基或芳基)的二乙氧基镁(a),氯化钙(b)和硅化合物(c))(其中R为烷基或芳基)一起制备的烯烃聚合催化剂固体催化剂组分 在有机溶剂(d)的存在下进行接触处理,将经处理的组合物悬浮在常温下为液态的芳烃(e)中,并使悬浮液与四氯化钛(f)进行第一次接触以形成产物, 使其与四氯化钛(f)进行第二次接触,使得除了接触处理之外,在上述悬浮和/或接触的任何阶段允许芳族二羧酸的二酯(g)共存, 氯化钙(b)的用量为每克二乙氧基镁(a)1-2克。 当用于烯烃聚合时,该固体催化剂组分表现出惊人的增加的每个钛原子的聚合活性和高立体特异性性能,并且几乎不需要任何脱屑处理,从而提供了巨大的经济优势。

    Catalyst for polymerization of olefins
    3.
    发明授权
    Catalyst for polymerization of olefins 失效
    烯烃聚合催化剂

    公开(公告)号:US4829037A

    公开(公告)日:1989-05-09

    申请号:US150650

    申请日:1988-01-05

    IPC分类号: C08F4/64 C08F10/00

    CPC分类号: C08F10/00 Y10S526/903

    摘要: A catalyst for the polymerization of olefins which exhibits a high catalytic activity and is capable of producing a stereoregular polymer in a high yield. The catalyst includes a catalyst component for the polymerization of olefins prepared by subjecting a solid composition obtained by a process comprising contacting dialkoxymagnesium, diester of aromatic dicarboxylic acid, aromatic hydrocarbon and titanium halide to a heat treatment in the presence or absence of a solvent; a silicon compound; and an organic aluminum compound.

    摘要翻译: PCT No.PCT / JP87 / 00278 Sec。 371日期1988年1月5日第 102(e)日期1988年1月5日PCT提交1987年5月6日PCT公布。 第WO87 / 06945号公报 日期:1987年11月19日。用于烯烃聚合的催化剂,其表现出高催化活性并且能够以高产率制备立体有规聚合物。 催化剂包括用于烯烃聚合的催化剂组分,其通过使含有二烷氧基镁,芳族二羧酸二酯,芳族烃和卤化钛的方法得到的固体组合物在溶剂存在或不存在下进行热处理而制备。 硅化合物; 和有机铝化合物。