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    Zeolite ITQ-30
    2.
    发明授权
    Zeolite ITQ-30 有权
    沸石ITQ-30

    公开(公告)号：US08115001B2

    公开(公告)日：2012-02-14

    申请号：US11597808

    申请日：2005-05-25

    申请人： Avelino Corma Canos ,  María José Díaz Cabañas

    发明人： Avelino Corma Canos ,  María José Díaz Cabañas

    IPC分类号： C07D221/18

    CPC分类号： C01B39/48 ,  B01J29/035 ,  B01J29/70 ,  C01B37/02 ,  C10G11/05 ,  C10G49/08 ,  C10G2300/1092 ,  C10G2300/1096 ,  C10G2400/30

    摘要： The invention relates to a laminar microporous crystalline zeolite material known as ITQ-30 which, as when synthesized, has a chemical composition in the anhydrous state with the following molar relations: x (M1/n XO2):y YO2:SiO2:z R, wherein: x represents a value less than 0.1, which can be equal to zero; y has a value of less than 0.1, which can be equal to zero; z has a value of less than 0.1; M is selected from among H+, NH4+, one or more +n inorganic cations and combinations of same; X represents one or more +3 oxidation state chemical elements; Y represents one or more +4 oxidation state chemical elements; and R represents one or more organic compounds. The invention also relates to the method of preparing said zeolite, involving the use of one or more organic additives in a reaction mixture which is crystallized by means of heating, and to the use thereof in processes for the separation and transformation of organic compounds.

    摘要翻译： 本发明涉及一种称为ITQ-30的层状微孔结晶沸石材料，其当合成时具有以下摩尔关系的无水状态的化学组成：x（M1 / n XO2）：y YO2：SiO2：zR ，其中：x表示小于0.1的值，其可以等于零; y的值小于0.1，可以等于零; z的值小于0.1; M选自H +，NH4 +，一种或多种+ n种无机阳离子及其组合; X表示一种或多种+3氧化态化学元素; Y表示一个或多个+4氧化态化学元素; R表示一种或多种有机化合物。 本发明还涉及制备所述沸石的方法，涉及在通过加热结晶的反应混合物中使用一种或多种有机添加剂，以及其用于分离和转化有机化合物的方法中的用途。

    METHOD FOR EXTRACTING BIOCHEMICAL PRODUCTS OBTAINED FROM A PROCESS OF HYDROTHERMAL CARBONIZATION OF BIOMASS
    5.
    发明申请
    METHOD FOR EXTRACTING BIOCHEMICAL PRODUCTS OBTAINED FROM A PROCESS OF HYDROTHERMAL CARBONIZATION OF BIOMASS 有权
    从生物质热水碳酸化过程中提取生物化学产品的方法

    公开(公告)号：US20140142353A1

    公开(公告)日：2014-05-22

    申请号：US14114818

    申请日：2011-12-22

    申请人： Martin Hitzl ,  Michael Renz ,  Avelino Corma Canos

    发明人： Martin Hitzl ,  Michael Renz ,  Avelino Corma Canos

    IPC分类号： C10G1/00

    CPC分类号： C10G1/002 ,  C10G1/008 ,  C10G1/02 ,  C10G2300/1011 ,  C10L9/086 ,  C10L2290/54 ,  Y02E50/13 ,  Y02P30/20

    摘要： The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pressure. The invention likewise relates to the biochemical product obtainable from said method, as well as to a system for implementing said method.

    摘要翻译： 本发明涉及一种从生物质水热碳化过程中提取生物化学产品的方法，其包括将生物质的水混合物从用于生物质的含水混合物的预热管中提供至具有预定水平浮选的垂直反应器， 其中所述用于提取生物化学产物的方法的特征在于其包括（a）将所述生物质的水混合物加热至或高于所述垂直反应器中的蒸发温度和/或在 预热生物质水混合物的先前阶段，在垂直反应器的预定浮选水平增加流和/或气体的产生，（b）提取先前阶段产生的并积聚在上层的蒸汽和/或气体 垂直反应器的一部分，和（c）在不同的水平下冷却气体和/或冷凝在前一阶段提取的蒸汽 ls的温度和压力。 本发明同样涉及可从所述方法获得的生物化学产品，以及用于实施所述方法的系统。

    PROCESS FOR THE PRODUCTION OF METHYLENE-BRIDGED POLYPHENYL POLYAMINES
    6.
    发明申请
    PROCESS FOR THE PRODUCTION OF METHYLENE-BRIDGED POLYPHENYL POLYAMINES 有权
    制备亚甲基桥联聚苯胺的方法

    公开(公告)号：US20110282099A1

    公开(公告)日：2011-11-17

    申请号：US13133410

    申请日：2009-11-26

    申请人： Christopher John Mitchell ,  Avelino Corma Canos ,  Robert Henry Carr ,  Pablo Botella Asuncion

    发明人： Christopher John Mitchell ,  Avelino Corma Canos ,  Robert Henry Carr ,  Pablo Botella Asuncion

    IPC分类号： C07C211/51

    CPC分类号： C07C209/60 ,  C07C209/78 ,  C07C211/50

    摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps ofa) condensing aniline and formaldehyde, providing a condensate, the molar ratio of aniline to formaldehyde being chosen in the range of 2 to 3.5;b) reacting, in a first catalytic reaction step, at a reaction temperature within the range of about 30° C. to about 100° C., said condensate over a solid catalyst being chosen from the group consisting of clays, silicates, silica-aluminas and ion exchange resins, whereby an intermediate mixture is provided, the intermediate mixture comprising amino benzyl amines;c) converting, in a subsequent catalytic reaction step, at a temperature within the range of about 70° C. to about 250° C., the reaction temperature in said subsequent catalytic reaction step is higher than the reaction temperature in said first catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst being chosen from the group consisting of zeolites, delaminated zeolites and ordered mesoporous materials, thereby providing said methylene-bridged polyphenyl polyamines.

    摘要翻译： 根据本发明的由苯胺和甲醛提供亚甲基桥接的聚苯胺的方法包括以下步骤：a）使苯胺和甲醛缩合，提供缩合物，苯胺与甲醛的摩尔比选择在2至3.5的范围内; b）在第一催化反应步骤中，在约30℃至约100℃范围内的反应温度下使所述缩合物在固体催化剂上选自粘土，硅酸盐，二氧化硅 - 氧化铝和离子交换树脂，由此提供中间体混合物，所述中间体混合物包含氨基苄基胺; c）在随后的催化反应步骤中，在约70℃至约250℃的温度范围内转化，所述后续催化反应步骤中的反应温度高于所述第一催化反应中的反应温度 在随后的固体催化剂存在下将所述中间体混合物形成亚甲基桥连的聚苯胺，所述固体催化剂选自沸石，分层沸石和有序介孔材料，从而提供所述亚甲基桥连的聚苯基多胺。

    MICROPOROUS CRYSTALLINE MATERIAL OF ZEOLITIC NATURE, ZEOLITE ITQ-39, METHOD OF PREPARATION AND USES
    8.
    发明申请
    MICROPOROUS CRYSTALLINE MATERIAL OF ZEOLITIC NATURE, ZEOLITE ITQ-39, METHOD OF PREPARATION AND USES 有权
    ZEOLITE ITQ-39微波晶体材料，ZEOLITE ITQ-39，制备和使用方法

    公开(公告)号：US20090312177A1

    公开(公告)日：2009-12-17

    申请号：US12525506

    申请日：2008-01-31

    申请人： Avelino Corma Canos ,  Manuel Moliner Marin ,  Fernando Rey Garcia ,  Jorge Gonzalez Gonzalez

    发明人： Avelino Corma Canos ,  Manuel Moliner Marin ,  Fernando Rey Garcia ,  Jorge Gonzalez Gonzalez

    IPC分类号： B01J29/87 ,  B01J29/04 ,  B01J29/072 ,  B01J29/06

    CPC分类号： B01J29/70 ,  B01J20/18 ,  C01B39/48

    摘要： Described herein are zeolite microporous crystalline materials comprising, in the heated state and in the absence of defects in its crystalline framework manifested by the presence of silanols, the empirical formula: x(M1/nXO2):yYO2:SiO2, wherein M is selected from H+, an inorganic cation of charge +n, and mixtures thereof, X is at least one chemical element having an oxidation state of +3, Y is at least one second chemical element other than Si having an oxidation state +4, x has a value between 0 and about 0.3, y has a value between 0 and about 0.1, and wherein the synthesized material has an X-ray diffraction pattern having at least values of angle 2θ (degrees) and relative intensities (I/I0) described. Process of making the microporous crystalline materials are also disclosed.

    摘要翻译： 本文描述的是沸石微孔结晶材料，其包括在加热状态下，在不存在由硅烷醇存在的结晶框架中缺陷的情况下，经验式：x（M1 / nXO2）：yYO2：SiO2，其中M选自 H +，电荷无机阳离子+ n及其混合物，X是氧化态为+3的至少一种化学元素，Y是具有氧化态+4以外的除了Si以外的至少一种第二化学元素，x具有 值在0和约0.3之间，y具有在0和约0.1之间的值，并且其中合成材料具有至少具有所述角度2θ（度）和相对强度（I / I0）的X射线衍射图。 还公开了制备微孔结晶材料的方法。