SUPPORTED NOBLE METAL CATALYST AND PROCESS FOR PREPARING THE SAME IN SITU
    10.
    发明申请
    SUPPORTED NOBLE METAL CATALYST AND PROCESS FOR PREPARING THE SAME IN SITU 有权
    支持的金属催化剂及其制备方法

    公开(公告)号:US20130143731A1

    公开(公告)日:2013-06-06

    申请号:US13700427

    申请日:2010-05-27

    Abstract: A supported noble metal catalyst and a process for preparing the same in situ are provided. Hexamethylenetetramine, a soluble divalent metal salt solution, a Al2O3 carrier and a soluble noble metal salt solution, are mixed and crystallized, in which the hexamethylenetetramine acts as both a precipitating agent for producing hydrotalcite and a reducing agent for the noble metal precursor, and a supported catalyst Me-LDHs-Al2O3 containing an elementary substance of a noble metal is prepared by a one-step reaction. During the growth of the hydrotalcite, Al3+ on the surface layer of the Al2O3 carrier is directly used as the trivalent metal ion to form the slab structure of the hydrotalcite, and the hydrotalcite is grown in situ on the surface of the alumina carrier. The noble metal element particle in the catalyst has a particle size of 10 to 60 nm, and has an even and stable dispersion on or between slabs of the hydrotalcite. The calcination and reduction processes in the traditional production method are no longer required, and the reduced noble metal catalyst is obtained by a single step of a crystallization process, while the utilization ratio of the noble metal is high.

    Abstract translation: 提供负载型贵金属催化剂及其原位制备方法。 将六亚甲基四胺,可溶性二价金属盐溶液,Al 2 O 3载体和可溶性贵金属盐溶液混合并结晶,其中六亚甲基四胺既用作制备水滑石的沉淀剂和贵金属前体的还原剂, 通过一步反应制备含有贵金属的基本物质的载体催化剂Me-LDHs-Al 2 O 3。 在水滑石生长过程中,Al2O3载体的表层上的Al3 +直接用作三价金属离子,形成水滑石的板状结构,水滑石在氧化铝载体的表面原位生长。 催化剂中的贵金属元素粒子的粒径为10〜60nm,并且在水滑石板之间或之间均匀且稳定地分散。 不再需要传统生产方法中的煅烧和还原过程,而贵金属的利用率高时,通过结晶过程的一个步骤获得还原的贵金属催化剂。

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