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9 条记录 (耗时 0.017 秒)

    Production of 1-(3-hydroxy-propyl)-1,4-diazepane and 1,4-bis(3,4,5-trimethoxy-benzoyloxy)-propyl-diazepane derivatives thereof
    2.
    发明授权
    Production of 1-(3-hydroxy-propyl)-1,4-diazepane and 1,4-bis(3,4,5-trimethoxy-benzoyloxy)-propyl-diazepane derivatives thereof 失效
    1-（3-羟基 - 丙基）-1,4-二氮杂环庚烷和1,4-双（3,4,5-三甲氧基 - 苯甲酰氧基） - 丙基 - 二氮杂环庚烷衍生物的制备

    公开(公告)号：US4751298A

    公开(公告)日：1988-06-14

    申请号：US693344

    申请日：1985-01-22

    申请人： Axel Kleemann ,  Bernd Lehmann ,  Klaus Deller

    发明人： Axel Kleemann ,  Bernd Lehmann ,  Klaus Deller

    IPC分类号： A61K31/55 ,  B01J27/00 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/24 ,  C07D243/08

    CPC分类号： C07C255/00 ,  C07D243/08

    摘要： There is disclosed a process for the production of 1,4-bis-[3-(3,4,5-trimethoxybenzyloxy)-propyl]-diazepane which consists of first reacting 3-aminopropanol with acrylonitrile and subsequently reacting in aqueous solution with formaldehyde and hydrocyanic acid or with formaldehyde and an alkali cyanide in the presence of alkali hydrogen sulfite to form cyanomethyl-(2-cyano-ethyl)-(3-hydroxy-propyl)-amine; hydrogenating the thus obtained reaction product in the presence of a hydrogenating catalyst and ammonia to 1 (3-hydroxy-propyl)-1,4-diazepane and reacting the latter compound for example with 3-halogen propanol or with allyl alcohol and introducing two 3,4,5-trimethoxy-benzoyl groups into the thus obtained reaction product by esterification.

    摘要翻译： 公开了一种生产1,4-双[3-（3,4,5-三甲氧基苄氧基） - 丙基] - 二氮杂环丁烷的方法，该方法由首先使3-氨基丙醇与丙烯腈反应，随后在水溶液中与甲醛反应 和氢氰酸，或在碱金属亚硫酸盐存在下与甲醛和碱金属氰化物反应，形成氰基甲基 - （2-氰基 - 乙基） - （3-羟基 - 丙基） - 胺; 将由此得到的反应产物在氢化催化剂和氨的存在下氢化成1（3-羟基 - 丙基）-1,4-二氮杂环丁烷，并使后者化合物例如与3-卤素丙醇或烯丙醇反应并引入两个3 ，4,5-三甲氧基苯甲酰基通过酯化转化成如此得到的反应产物。

    Process for the production of 1,2-diols
    3.
    发明授权
    Process for the production of 1,2-diols 失效
    生产1,2-二醇的方法

    公开(公告)号：US4482760A

    公开(公告)日：1984-11-13

    申请号：US552106

    申请日：1983-11-16

    申请人： Axel Kleemann ,  Klaus Deller ,  Karlheinz Drauz ,  Bernd Lehmann

    发明人： Axel Kleemann ,  Klaus Deller ,  Karlheinz Drauz ,  Bernd Lehmann

    IPC分类号： C07C43/13 ,  B01J23/00 ,  B01J31/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/00 ,  C07C31/20 ,  C07C33/26 ,  C07C41/00 ,  C07C67/00 ,  C07D307/42 ,  C07C7/00

    CPC分类号： C07C29/00

    摘要： 1,2-Diols of the formula: ##STR1## where R.sub.1 and R.sub.2 are hydrogen, alkyl of 1 to 10 carbon atoms or such as alkyl substituted by a halogen, a hydroxy group, a phenyl group, a methoxy group, or an ethoxy group, a phenyl group or a furyl group or R.sub.1 and R.sub.2 together form an alkylene group of 2 to 7 carbon atoms are formed by hydrogenating a correspondingly substituted cyanohydrin in an aqueous medium first in the presence of a hydrogenation catalyst and an acid at a temperature between -20.degree. and +25.degree. C. and a hydrogen pressure of less than 10 bar until per mole of cyanohydrin employed there is taken up one mole of hydrogen and then the hydrogenation continued to the end of the absorption of hydrogen in the presence of metallic nickel at a temperature between 30.degree. and 100.degree. C. and a hydrogen pressure between 10 and 150 bar.

    摘要翻译： 具有下式的1,2-二醇：其中R 1和R 2是氢，1至10个碳原子的烷基或被卤素，羟基，苯基，甲氧基， 或乙氧基，苯基或呋喃基或R 1和R 2一起形成2至7个碳原子的亚烷基通过在氢化催化剂和酸存在下首先在水性介质中氢化相应地取代的羟腈而形成 在-20℃至+25℃的温度和小于10巴的氢气压力下，直到每摩尔使用的氰醇为止，吸收1摩尔氢气，然后氢化继续到氢气吸收的最后 金属镍的存在温度在30℃至100℃之间，氢气压力在10至150巴之间。

    Process for the production of aqueous solutions of sodium salts of .alpha.- a
    4.
    发明授权
    Process for the production of aqueous solutions of sodium salts of .alpha.- a 失效
    制备α-氨基羧酸钠盐水溶液的方法

    公开(公告)号：US4436910A

    公开(公告)日：1984-03-13

    申请号：US347477

    申请日：1982-02-10

    申请人： Axel Kleemann ,  Bernd Lehmann ,  Jurgen Martens

    发明人： Axel Kleemann ,  Bernd Lehmann ,  Jurgen Martens

    IPC分类号： C07C227/24 ,  C07C229/00 ,  C07C229/02 ,  C07D207/16 ,  C07D209/20 ,  C07D211/60

    CPC分类号： C07D211/60

    摘要： Aqueous solutions of sodium salts of .alpha.-aminocarboxylic acids practically free of foreign salts are produced by saponifying the corresponding hydantoin at a temperature between 110.degree. C. and 180.degree. C. with a mixture, in each case based on the hydantoin, of 1 equivalent of sodium hydroxide and 2 equivalents of calcium oxide or hydroxide, separating off the precipitated calcium carbonate after the end of the saponification and concentrating the aqueous sodium salt solution remaining to drive off the ammonia contained therein.

    摘要翻译： 通过在110℃和180℃之间的温度下将相应的乙内酰脲在一种混合物中（基于乙内酰脲）相当于1当量的水溶液皂化相应的乙内酰脲来生产实际上不含外来盐的α-氨基羧酸的钠盐水溶液 的氢氧化钠和2当量的氧化钙或氢氧化物，在皂化结束后分离析出的碳酸钙，并浓缩剩余的钠盐水溶液以驱除其中所含的氨。

    Process for the production of .beta.-hydroxy-.alpha.-aminocarboxylic acids
    5.
    发明授权
    Process for the production of .beta.-hydroxy-.alpha.-aminocarboxylic acids 失效
    生产β-羟基-α-氨基羧酸的方法

    公开(公告)号：US4486600A

    公开(公告)日：1984-12-04

    申请号：US552102

    申请日：1983-11-16

    申请人： Axel Kleemann ,  Bernd Lehmann ,  Klaus Deller

    发明人： Axel Kleemann ,  Bernd Lehmann ,  Klaus Deller

    IPC分类号： C07C227/26 ,  C07C229/22 ,  C07C101/30

    CPC分类号： C07C255/00

    摘要： .beta.-hydroxy-.alpha.-aminocarboxylic acids of the formula: ##STR1## where R.sub.1 and R.sub.2 are hydrogen or an alkyl group having 1 to 10 carbon atoms are produced by hydrogenating the correspondingly substituted cyanohydrin in a water containing medium first in the presence of a hydrogenation catalyst and an acid at a temperature between -10.degree. and +40.degree. C. and a hydrogen pressure of less than 10 bar, until per mole of cyanohydrogen employed one mole of hydrogen is taken up and then employing the solution obtained as starting material for a Strecker or Bucherer synthesis of an amino acid.

    摘要翻译： 其中R 1和R 2是氢或具有1至10个碳原子的烷基的下式的β-羟基-α-氨基羧酸是通过在含水介质中氢化相应的取代的氰醇来制备的 在-10℃至+ 40℃的温度和小于10巴的氢气压力下存在氢化催化剂和酸，直到每摩尔氰基氢使用1摩尔氢，然后使用所得溶液 作为Strecker或Bucherer合成氨基酸的起始材料。

    Foams for removing pollutants and/or heavy metals from flowable media
    6.
    发明授权
    Foams for removing pollutants and/or heavy metals from flowable media 有权
    用于从可流动介质中去除污染物和/或重金属的泡沫

    公开(公告)号：US07267776B2

    公开(公告)日：2007-09-11

    申请号：US11121858

    申请日：2005-05-04

    申请人： Bernd Wurth ,  Bernd Lehmann ,  Klaus-Dieter Novak ,  Hendrik Kathrein ,  Andreas Schlegel

    发明人： Bernd Wurth ,  Bernd Lehmann ,  Klaus-Dieter Novak ,  Hendrik Kathrein ,  Andreas Schlegel

    IPC分类号： C02F1/42

    CPC分类号： C02F1/288 ,  B01J20/0229 ,  B01J20/06 ,  B01J20/261 ,  B01J20/262 ,  B01J20/28004 ,  B01J20/28045 ,  B01J20/28097 ,  B01J20/321 ,  B01J20/3212 ,  B01J20/3236 ,  C02F1/281 ,  C02F2101/103 ,  C02F2101/105 ,  C02F2101/20 ,  Y10S210/912

    摘要： The present invention relates to a method of using foam to remove pollutants and/or heavy metals from a flowable media. The method may include providing a foam that may include cavities wherein the cavities may include an adsorbent composition of iron oxyhydroxy granules. The iron oxyhydroxy granules may have a BET surface area of >100 m2/g and a mean particle size of 0.1 mm-2 mm. The method may further include passing a flowable media containing pollutants and/or heavy metals through the foam wherein the pollutants and heavy metals may be removed from the flowable media by the iron oxyhydroxy granules. A method of manufacturing the foam is also disclosed. The method may include introducing an adsorbent composition into a liquid reaction composite to form a mixture and adding an isocyanate reaction component to the mixture to form the foam.

    摘要翻译： 本发明涉及使用泡沫从可流动介质中除去污染物和/或重金属的方法。 该方法可以包括提供可以包括空腔的泡沫，其中空腔可以包括铁羟基羟基颗粒的吸附剂组合物。 铁羟基羟基颗粒可以具有> 100m 2 / g的BET表面积和0.1mm-2mm的平均粒度。 该方法可以进一步包括使含有污染物和/或重金属的可流动介质通过泡沫，其中污染物和重金属可由铁羟基羟基颗粒从可流动介质中除去。 还公开了制造泡沫的方法。 该方法可以包括将吸附剂组合物引入到液体反应复合物中以形成混合物并将异氰酸酯反应组分加入到混合物中以形成泡沫。