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公开(公告)号：US5695689A
公开(公告)日：1997-12-09
申请号：US530628
申请日：1995-09-20
申请人： Pramod Gupta , Hansjurgen Rabe
发明人： Pramod Gupta , Hansjurgen Rabe
IPC分类号： C09K15/08 , C08G18/28 , C08G18/48 , C08K5/00 , C08K5/1545 , C08K5/18 , C08L71/00 , C08L71/02 , C09K15/22
CPC分类号： C08K5/1545 , C08G18/28 , C08K5/005 , C08K5/18
摘要： .alpha.- and/or .beta.-tocopherol (vitamin E), optionally in combination with octylated diphenylamines, is combined with a polyether polyol having a molecular weight of from about 300 to about 10,000 to stabilize that polyether polyol. Polyether polyols which are stabilized in this manner are particularly useful in the production of polyurethanes and polyurethane foams with a reduced tendency toward discoloration.
摘要翻译： 任选与辛基化二苯胺组合的α-和/或β-生育酚（维生素E）与分子量为约300至约10,000的聚醚多元醇组合以稳定该聚醚多元醇。 以这种方式稳定的聚醚多元醇特别可用于生产具有降低的变色趋势的聚氨酯和聚氨酯泡沫体。
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2.发明授权Process for the production of highly elastic foams containing urethane groups from polyethers, modified polyisocyanates and cross-linking agents 失效用于从聚醚，改性多异氰酸酯和交联剂生产含有氨基甲酸酯基的高弹性泡沫的方法
公开(公告)号：US4288566A
公开(公告)日：1981-09-08
申请号：US120250
申请日：1980-02-11
申请人： Hanns P. Muller , Hansjurgen Rabe , Kuno Wagner
发明人： Hanns P. Muller , Hansjurgen Rabe , Kuno Wagner
IPC分类号： C08G18/00 , C08G18/28 , C08G18/32 , C08G18/38 , C08G18/65 , C08G18/66 , C08G18/78 , C08G18/79 , C08G18/14
CPC分类号： C08G18/79 , C08G18/2805 , C08G18/32 , C08G18/3209 , C08G18/3823 , C08G18/6666 , C08G18/78 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： The invention is directed to a process for the production of highly elastic, open-celled foams containing urethane groups by reacting polyether polyols with modified polyisocyanates in the presence of cross-linking agents and water characterized in that the reaction is carried out in the presence of 0.5 to 10 g/100 g of the polyether of a cross-linking mixture corresponding to the general formulaC.sub.n H.sub.2n+2 O.sub.nwherein n=2 to 10,which has a statistical average of at least four hydroxyl groups per molecule.
摘要翻译： 本发明涉及通过在交联剂和水的存在下使聚醚多元醇与改性多异氰酸酯反应来生产含有氨基甲酸酯基团的高弹性，开孔泡沫的方法，其特征在于反应在 0.5至10g / 100g对应于通式C n H 2n + 20n的交联混合物的聚醚，其中n = 2-10，其每分子具有至少四个羟基的统计平均值。
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3.发明授权Process for the production of low-fog flexible polyester polyurethane foams and their use in vehicles 失效生产低雾柔性聚酯聚氨酯泡沫的方法及其在车辆中的应用
公开(公告)号：US5286761A
公开(公告)日：1994-02-15
申请号：US86489
申请日：1993-07-01
申请人： Manfred Naujoks , Klaus Konig , Manfred Schmidt , Hans-Walter Illger , Gunter Baatz , Hansjurgen Rabe
发明人： Manfred Naujoks , Klaus Konig , Manfred Schmidt , Hans-Walter Illger , Gunter Baatz , Hansjurgen Rabe
CPC分类号： C08G63/90 , C08G18/4241 , C08G18/425 , C08G2101/0008 , C08G2101/0033 , C08G2101/0083 , C08G2290/00
摘要： Low-fog flexible polyester polyurethane foams are produced by reactinga) polyisocyanates, withb) polyesters containing at least two hydroxyl groups and having a molecular weight in the range from 400 to 10,000, in the presence ofc) water and/or readily volatile organic compounds as blowing agentswherein prior to reacting, the polyesters have been subjected to continuous distillation over an average holding time of 2 to 600 s, at a temperature of 160.degree. to 250.degree. C., and under a pressure of 0.05 to 10 mbar.The reaction mixture may optionally contain d) compounds containing at least two active hydrogen atoms and having a molecular weight in the range from 32 to 400 as chain-extending and crosslinking agents, and/ore) auxiliaries and additives known per se.These low-fogging polyester polyurethane foams are extremely suitable for use in vehicles, preferably automobiles.
摘要翻译： a）多异氰酸酯，其具有b）分子量为400至10,000的聚酯，其含有至少两个羟基，并且在制备之后以2至600秒的平均停留时间进行连续蒸馏，以及 在c）水和/或易挥发的有机化合物的存在下，温度为160-250℃，优选180-230℃，压力为0.05-10mbar，优选0.1-3mbar，如 发泡剂和任选地存在d）分子量为32-400的化合物，其含有最少两个活性氢原子作为扩链剂和交联剂，以及任选地在e）本身已知的助剂和添加剂的存在下，以及 用于运输工具（运输），最好是汽车（汽车）。
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4.发明授权Process for the production of modified polyether polyols and their use in processes for the production of polyurethane plastics 失效生产改性聚醚多元醇的方法及其在聚氨酯塑料生产工艺中的应用
公开(公告)号：US4272619A
公开(公告)日：1981-06-09
申请号：US139901
申请日：1980-04-14
申请人： Gerhard Balle , Hansjurgen Rabe , Peter Vehlewald
发明人： Gerhard Balle , Hansjurgen Rabe , Peter Vehlewald
IPC分类号： C08F283/06 , C08G18/63 , C08G18/14
CPC分类号： C08G18/632 , C08F283/06 , C08G18/638
摘要： The present invention relates to a process for the production of modified polyether polyols by the radical polymerization of a mixture of acrylonitrile, styrene, a salt of an .alpha.,.beta.-unsaturated monocarboxylic or polycarboxylic acid containing a primary, secondary or tertiary monoamine or polyamine and optionally copolymerizable compounds with a polyether polyol.
摘要翻译： 本发明涉及通过自由基聚合丙烯腈，苯乙烯，α，β-不饱和一元羧酸或含有伯，仲或叔一胺或多胺的多元羧酸的盐的混合物生产改性聚醚多元醇的方法，以及 任选地可共聚的化合物与聚醚多元醇。
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5.发明授权Apparatus for applying a layer of a liquid foamable reaction mixture to a continuously moving support 失效用于将液体可发泡反应混合物层施加到连续移动的载体上的装置
公开(公告)号：US4165211A
公开(公告)日：1979-08-21
申请号：US812011
申请日：1977-07-01
申请人： Wilfried Ebeling , Volker Onnenberg , Alberto C. Gonzalez-Dorner , Bernd Lehmann , Hansjurgen Rabe , Klaus Schulte
发明人： Wilfried Ebeling , Volker Onnenberg , Alberto C. Gonzalez-Dorner , Bernd Lehmann , Hansjurgen Rabe , Klaus Schulte
CPC分类号： B29C44/461 , D06B19/0094 , Y10S118/04 , Y10S264/13 , Y10S264/84
摘要： The instant invention relates to a process and an apparatus for applying a layer of liquid, foamable reaction mixture to a continuously moving support, such as for the production of foam blocks or foam sandwich panels having a thick foam core.
摘要翻译： 本发明涉及一种用于将液体可发泡反应混合物层施加到连续移动的载体上的方法和装置，例如用于生产具有厚泡沫芯的泡沫块或泡沫夹芯板。
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6.发明授权Process for the production of low-fog flexible polyester polyurethane foams and their use in vehicles 失效生产低雾柔性聚酯聚氨酯泡沫的方法及其在车辆中的应用
公开(公告)号：US5373029A
公开(公告)日：1994-12-13
申请号：US154655
申请日：1993-11-18
申请人： Manfred Naujoks , Klaus Konig , Manfred Schmidt , Hans-Walter Illger , Gunter Baatz , Hansjurgen Rabe
发明人： Manfred Naujoks , Klaus Konig , Manfred Schmidt , Hans-Walter Illger , Gunter Baatz , Hansjurgen Rabe
CPC分类号： C08G63/90 , C08G18/4241 , C08G18/425 , C08G2101/0008 , C08G2101/0033 , C08G2101/0083 , C08G2290/00
摘要： Low-fog flexible polyester polyurethane foams are produced by reactinga) polyisocyanates, withb) polyesters containing at least two hydroxyl groups and having a molecular weight in the range from 400 to 10,000,in the presence ofc) water and/or readily volatile organic compounds as blowing agentswherein prior to reacting, the polyesters have been subjected to continuous distillation over an average holding time of 2 to 600 s, at a temperature of 160.degree. to 250.degree. C., and under a pressure of 0.05 to 10 mbar.The reaction mixture may optionally containd)compounds containing at least two active hydrogen atoms and having a molecular weight in the range from 32 to 400 as chain-extending and crosslinking agents, and/ore) auxiliaries and additives known per se.These low-fogging polyester polyurethane foams are extremely suitable for use in vehicles, preferably automobiles.
摘要翻译： 通过使a）多异氰酸酯与b）含有至少两个羟基并且分子量为400至10,000的聚酯在c）水和/或易挥发的存在下反应来制备低雾柔性聚酯聚氨酯泡沫 有机化合物作为发泡剂，其中在反应之前，聚酯在平均保持时间为2至600秒，160至250℃的温度和0.05至10毫巴的压力下进行连续蒸馏 。 反应混合物可以任选地含有d）含有至少两个活性氢原子并且分子量范围为32-400的化合物作为扩链和交联剂，和/或e）本身已知的助剂和添加剂。 这些低雾聚酯聚氨酯泡沫非常适用于车辆，优选汽车。
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7.发明授权Process for applying a layer of a liquid foamable reaction mixture to a continuously moving shaping support 失效将液体可发泡反应混合物层施加到连续移动的整形支撑件的方法
公开(公告)号：US4216181A
公开(公告)日：1980-08-05
申请号：US32090
申请日：1979-04-23
申请人： Wilfried Ebeling , Volker Onnenberg , Alberto C. Gonzalez-Dorner , Bernd Lehmann , Hansjurgen Rabe , Klaus Schulte
发明人： Wilfried Ebeling , Volker Onnenberg , Alberto C. Gonzalez-Dorner , Bernd Lehmann , Hansjurgen Rabe , Klaus Schulte
CPC分类号： B29C44/461 , D06B19/0094 , Y10S118/04 , Y10S264/13 , Y10S264/84
摘要： A method for the continuous production of foam blocks or foam sandwich panels involving the application of the liquid foamable reaction mixture to the continuously moving shaping support in a manner which avoids large gas inclusions in the final product produced. The liquid foamable reaction mixture is preliminarily distributed by the use of a particular distributor channel means in a traverse direction to the continuously moving shaping support, permitted to flow in the form of a descending film exposed to the atmosphere to an intermediate storage means and then conveyed to said continuously moving shaping support. The distributor channel means may also be pivoted to control the outflow of the mixture.
摘要翻译： 一种用于连续生产泡沫块或泡沫夹芯板的方法，其涉及将液体可发泡反应混合物以避免产生的最终产品中的大气体夹杂物的方式施加到连续移动的成型载体上。 液体可发泡反应混合物通过使用特定的分配器通道装置预先分布在沿连续运动的成形支撑件的横向方向上，允许以暴露于大气的下降膜的形式流动到中间储存装置，然后传送 到所述连续移动的成形支撑件。 分配器通道装置也可以枢转以控制混合物的流出。
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8.发明授权Use of 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid for stabilizing polyether polyols 失效3,5-二叔丁基-4-羟基苯基丙酸用于稳定聚醚多元醇的用途
公开(公告)号：US5006599A
公开(公告)日：1991-04-09
申请号：US450894
申请日：1989-12-14
CPC分类号： C08K5/13
摘要： The present invention relates to a method for stabilizing a polyether polyol having a molecular weight of from about 300 to about 10,000 comprising adding 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid as an antioxidant stabilizer, optionally in combination with other antioxidants, to said polyether polyol. This invention further relates to polyols stabilized by the method of this invention and to stabilized polyurethanes prepared from such stabilized polyols.
摘要翻译： 本发明涉及稳定分子量为约300至约10,000的聚醚多元醇的方法，包括加入3,5-二叔丁基-4-羟基苯基丙酸作为抗氧化剂稳定剂，任选地与其它抗氧化剂 至所述聚醚多元醇。 本发明还涉及通过本发明的方法稳定的多元醇和由这种稳定的多元醇制备的稳定的聚氨酯。
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