公开(公告)号：US10077322B2

公开(公告)日：2018-09-18

申请号：US15533856

申请日：2015-12-01

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Pietro Baita ,  Tiziano Dall'Occo ,  Maria Di Diego ,  Dario Liguori ,  Lorella Marturano ,  Andreas Maus ,  Gabriele Mei ,  Gerhardus Meier ,  Giampiero Morini ,  Roberta Pica ,  Ulf Schueller

IPC: C08F4/649 ,  C08F4/654 ,  C08F110/02 ,  C08F210/02 ,  C08F2/34

CPC classification number: C08F2/34 ,  C08F4/6493 ,  C08F4/6494 ,  C08F110/02 ,  C08F2410/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/6543 ,  C08F210/02

Abstract: The present disclosure provides a gas-phase polymerization process for preparing polyethylene, wherein halogenated alcohols in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst suppress ethane formation or increase polymerization activity.

公开(公告)号：US09441056B2

公开(公告)日：2016-09-13

申请号：US14653961

申请日：2013-12-10

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Andreas Maus ,  Gerhardus Meier ,  Gianni Collina ,  Diego Brita

IPC: C08F110/02 ,  C08F2/14 ,  C08F2/38 ,  C08F10/02

CPC classification number: C08F110/02 ,  C08F2/14 ,  C08F10/02 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/14

Abstract: The present invention relates to a slurry process for preparing an ethylene polymer having a melt flow ratio F/P, which is the ratio among the melt index value measured according to ASTM 1238 condition “F” and the melt index value measured according to ASTM 1238 condition “P” of equal to or lower than 27, carried out in two or more stages of polymerization at temperatures in the range from 60 to 120° C., in which at least two of the said two or more polymerization stages are carried out under different amounts of molecular weight regulator, said process being carried out in the presence of (A) a solid catalyst component comprising Ti, Mg, halogen, having a porosity (PF), measured by the mercury method and due to pores with radius equal to, or lower than, 1 μm, of at least 0.3 cm3/g and a surface area determined by BET method, of lower than 100 m2/g, and being further characterized by the fact that more than 50% of the titanium atoms are in a valence state lower than 4 and (B) of an organoaluminum compound.

Abstract translation: 本发明涉及一种用于制备熔体流动比F / P的乙烯聚合物的浆料方法，其是根据ASTM 1238条件“F”测量的熔体指数与根据ASTM 1238测量的熔体指数之间的比率 条件“P”等于或低于27，在60至120℃的温度下在两个或更多个聚合阶段进行，其中至少两个所述两个或更多个聚合阶段被执行 在不同量的分子量调节剂下，所述方法在（A）包含通过汞法测量的具有孔隙率（PF）的Ti，Mg，卤素的固体催化剂组分的存在下进行，并且由于具有半径相等的孔 至少为0.3cm 3 / g，BET法测定的表面积低于100m2 / g，进一步的特征在于，超过50％的钛原子为 低于4的价态，（B） 的有机铝化合物。

公开(公告)号：US20150353655A1

公开(公告)日：2015-12-10

申请号：US14653961

申请日：2013-12-10

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Andreas Maus ,  Gerhardus Meier ,  Gianni Collina ,  Diego Brita

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F2/14 ,  C08F10/02 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/14

Abstract: The present invention relates to a slurry process for preparing an ethylene polymer having a melt flow ratio F/P, which is the ratio among the melt index value measured according to ASTM 1238 condition “F” and the melt index value measured according to ASTM 1238 condition “P” of equal to or lower than 27, carried out in two or more stages of polymerization at temperatures in the range from 60 to 120° C., in which at least two of the said two or more polymerization stages are carried out under different amounts of molecular weight regulator, said process being carried out in the presence of (A) a solid catalyst component comprising Ti, Mg, halogen, having a porosity (PF), measured by the mercury method and due to pores with radius equal to, or lower than, 1 μm, of at least 0.3 cm3/g and a surface area determined by BET method, of lower than 100 m2/g, and being further characterized by the fact that more than 50% of the titanium atoms are in a valence state lower than 4 and (B) of an organoaluminum compound.

Abstract translation: 本发明涉及一种用于制备熔体流动比F / P的乙烯聚合物的浆料方法，其是根据ASTM 1238条件“F”测量的熔体指数与根据ASTM 1238测量的熔体指数之间的比率 条件“P”等于或低于27，在60至120℃的温度下在两个或更多个聚合阶段进行，其中至少两个所述两个或更多个聚合阶段被执行 在不同量的分子量调节剂下，所述方法在（A）包含通过汞法测量的具有孔隙率（PF）的Ti，Mg，卤素的固体催化剂组分的存在下进行，并且由于具有半径相等的孔 至少为0.3cm 3 / g，BET法测定的表面积低于100m2 / g，进一步的特征在于，超过50％的钛原子为 在低于4的价态下，（B） 的有机铝化合物。