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公开(公告)号:US20210070958A1
公开(公告)日:2021-03-11
申请号:US17015506
申请日:2020-09-09
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Diego Brita , Sheri E. Davis , Volker Fraaije , Simona Guidotti , Dario Liguori , Sandor Nagy , David L. Ramage , Shahram Mihan , Christopher D. Smith , Daniel F. White , Xueyong Yang
Abstract: A method of depolymerizing plastics using a halloysite catalyst is described herein. The method reduces the energy required for the depolymerization process while achieving improved depolymerization results.
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公开(公告)号:US20150329657A1
公开(公告)日:2015-11-19
申请号:US14651878
申请日:2013-11-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Lenka Richter-Lukesova , Shahram Mihan , Sandor Nagy
IPC: C08F210/14
CPC classification number: C08F210/14 , B01J31/18 , B01J31/181 , B01J31/1815 , B01J2531/0238 , B01J2531/0241 , B01J2531/0258 , B01J2531/48 , B01J2531/842 , C08F2410/04 , Y02P20/52 , C08F210/16 , C08F2500/04 , C08F2500/07 , C08F4/7042 , C08F4/64072
Abstract: A catalyst system obtainable by contacting: A) a metal complex of formula (I) B) an iron complex of the general formula (II) C) an alumoxane or a compound capable of forming an alkyl cation with complexes of formula (I) and (II); Wherein the variables are described in the description
Abstract translation: 一种催化剂体系,其可通过以下方式获得:A)式(I)的金属配合物B)通式(II)的铁络合物C)铝氧烷或能够形成烷基阳离子的化合物与式(I)和 (二); 变量在描述中描述
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公开(公告)号:US20240327715A1
公开(公告)日:2024-10-03
申请号:US18708524
申请日:2022-11-15
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Diego Brita , Simona Guidotti , Dario Liguori , Francesco Menichelli , Sandor Nagy , Noel C. Hallinan
CPC classification number: C10B53/07 , B01J21/08 , B01J23/30 , C08J11/16 , C10B57/06 , C08J2323/06 , C08J2423/12
Abstract: A process for depolymerizing plastic waste including the steps of: a) providing a melt plastic waste feedstock made from or containing recycled polypropylene and polyethylene; and b) subjecting the melt product obtained in (a) to a temperature ranging from 280° C. to 600° C., thereby obtaining a depolymerization product; wherein the melt product, the depolymerization product, or both are contacted with a catalyst made from or containing a supported heteropolyacid, having a transition metal portion containing transition metals selected from the group consisting of W, Mo, and V and a non-metal portion containing non-metal elements selected from the group consisting of Si, P, and As.
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公开(公告)号:US20240182388A1
公开(公告)日:2024-06-06
申请号:US18526332
申请日:2023-12-01
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , David S. Mannel , Natalia Nagy , Amy D. Rose , George R. Horvat , Larry W. Arndt , David W. Leyshon , Xueyong Yang , Barbara Kimmich
IPC: C07C29/17
CPC classification number: C07C29/172 , C07C2527/051
Abstract: Processes for conversion of propylene polyol feed into useful petrochemical products, including olefin monomers, are described. Such processes comprise: adding a feed stream comprising one or more propylene polyols to a dehydration cleavage reaction zone in the presence of a dehydration cleavage catalyst and reacting at a pressure and temperature sufficient to form a product stream comprising propionaldehyde, a dioxolane component, and a dioxane component; and adding the product stream and hydrogen to a dehydration reaction zone in the presence of a hydrogenation catalyst to form and reacting at a pressure and temperature sufficient to form a second product stream comprising a propanol component. The second product can be added to a dehydration reaction zone in the presence of a dehydration catalyst and reacted at a pressure and temperature sufficient to form a third product stream comprising propylene.
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公开(公告)号:US11872545B2
公开(公告)日:2024-01-16
申请号:US17541474
申请日:2021-12-03
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , Daniel F. White , Christopher D. Smith , David L. Ramage , Diego Brita , Noel C. Hallinan
CPC classification number: B01J29/7007 , B01J27/16 , B01J29/084 , B01J29/40 , C08J11/16 , C08J2323/06 , C08J2323/12
Abstract: Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The compositions are a composite of at least one zeolite catalyst with one or more co-catalyst(s) that is a solid inorganic material. These composite catalysts, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of non-polyolefin polymers that may be present. This results in a shorter residence time in the depolymerization unit and more efficient process.
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公开(公告)号:US12173124B2
公开(公告)日:2024-12-24
申请号:US17450234
申请日:2021-10-07
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , Daniel F. White , Christopher D. Smith , David L Ramage
IPC: C08J11/20
Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.
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公开(公告)号:US20240228405A9
公开(公告)日:2024-07-11
申请号:US18493300
申请日:2023-10-24
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , Christopher D. Smith , Daniel F. White , Diego Brita , Simona Guidotti , Dario Liguori , Francesco Menichelli , Paolo Ruzzi
CPC classification number: C07C4/22 , B01J21/16 , B01J21/18 , B01J23/02 , B01J29/40 , B01J29/7007 , C07C2529/40
Abstract: Catalytic compositions and processes for depolymerizing polyolefin-based feed into useful petrochemical products are described. The compositions are a composite of a zeolite catalyst component and a co-catalyst comprising an activated clay component and/or a solid base component. These catalyst systems, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of impurities that may be present in the polyolefin-based feed. This results in a shorter residence time in the depolymerization unit and more efficient process.
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公开(公告)号:US20240132425A1
公开(公告)日:2024-04-25
申请号:US18493300
申请日:2023-10-23
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , Christopher D. Smith , Daniel F. White , Diego Brita , Simona Guidotti , Dario Liguori , Francesco Menichelli , Paolo Ruzzi
CPC classification number: C07C4/22 , B01J21/16 , B01J21/18 , B01J23/02 , B01J29/40 , B01J29/7007 , C07C2529/40
Abstract: Catalytic compositions and processes for depolymerizing polyolefin-based feed into useful petrochemical products are described. The compositions are a composite of a zeolite catalyst component and a co-catalyst comprising an activated clay component and/or a solid base component. These catalyst systems, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of impurities that may be present in the polyolefin-based feed. This results in a shorter residence time in the depolymerization unit and more efficient process.
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公开(公告)号:US20220135760A1
公开(公告)日:2022-05-05
申请号:US17514015
申请日:2021-10-29
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , Daniel F. White , Christopher D. Smith , Xueyong Yang , David L. Ramage
IPC: C08J11/16
Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using supported metal oxides and heat are described. The supported metal oxides improve the depolymerization reaction by decreasing the half time for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.
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公开(公告)号:US20210061972A1
公开(公告)日:2021-03-04
申请号:US17001832
申请日:2020-08-25
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Sandor Nagy , Christopher D. Smith , Xueyong Yang , Daniel F. White , Sheri E. Davis , Shahram Mihan , Volker Fraaije
IPC: C08J11/16 , B01J27/125 , C10G1/10
Abstract: A method of depolymerizing plastics using a fluorinated alumina catalyst is described herein. The method reduces the energy required for the depolymerization process while achieving improved depolymerization results.
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