PROPYLENE POLYOL CONVERSION TO OLEFIN MONOMER

    公开(公告)号:US20240182388A1

    公开(公告)日:2024-06-06

    申请号:US18526332

    申请日:2023-12-01

    CPC classification number: C07C29/172 C07C2527/051

    Abstract: Processes for conversion of propylene polyol feed into useful petrochemical products, including olefin monomers, are described. Such processes comprise: adding a feed stream comprising one or more propylene polyols to a dehydration cleavage reaction zone in the presence of a dehydration cleavage catalyst and reacting at a pressure and temperature sufficient to form a product stream comprising propionaldehyde, a dioxolane component, and a dioxane component; and adding the product stream and hydrogen to a dehydration reaction zone in the presence of a hydrogenation catalyst to form and reacting at a pressure and temperature sufficient to form a second product stream comprising a propanol component. The second product can be added to a dehydration reaction zone in the presence of a dehydration catalyst and reacted at a pressure and temperature sufficient to form a third product stream comprising propylene.

    Styrene-assisted depolymerization of polyolefins

    公开(公告)号:US12173124B2

    公开(公告)日:2024-12-24

    申请号:US17450234

    申请日:2021-10-07

    Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.

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