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公开(公告)号:US10030088B2
公开(公告)日:2018-07-24
申请号:US15324281
申请日:2015-06-29
申请人: BASF SE
发明人: Christian Hubert Weidl , Uwe Held , Thomas Mausberg , Silke Annika Köhler , Bernd Schneider , Karolina Hofmann , Linda Winkelmann
IPC分类号: C08F216/14 , C08F2/22 , C08F212/08 , C08F218/08 , C08F220/14 , C08F220/18
摘要: The present invention relates to the use of reactive monomers as plasticizers in copolymers. The invention further relates to copolymers obtainable by using the reactive monomers. The present invention moreover relates to processes for the lowering of the glass transition temperature of copolymers with use of the reactive monomers.
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公开(公告)号:US20170204209A1
公开(公告)日:2017-07-20
申请号:US15324281
申请日:2015-06-29
申请人: BASF SE
发明人: Christian Hubert Weidl , Uwe Held , Thomas Mausberg , Silke Annika Köhler , Bernd Schneider , Karolina Hofmann , Linda Winkelmann
IPC分类号: C08F216/14 , C08F220/14 , C08F218/08 , C08F212/08 , C08F220/18
CPC分类号: C08F216/1416 , C08F212/08 , C08F218/08 , C08F220/14 , C08F220/18 , C08F2216/1425 , C08F2216/1433 , C08F2216/1441 , C08F2220/1825
摘要: The present invention relates to the use of reactive monomers as plasticizers in copolymers. The invention further relates to copolymers obtainable by using the reactive monomers. The present invention moreover relates to processes for the lowering of the glass transition temperature of copolymers with use of the reactive monomers.
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公开(公告)号:US09109054B2
公开(公告)日:2015-08-18
申请号:US14371933
申请日:2013-06-11
申请人: BASF SE
CPC分类号: C08F2/44 , B01F17/0021 , C08F2/24 , C08F2/30
摘要: Process for polymerizing at least one monomer under emulsion polymerization conditions, characterized in that the (co)monomers are selected from vinyl aromatic compounds, ethylenically unsaturated carboxylic acids with 3 to 10 carbon atoms, C1-C10-alkyl esters of ethylenically unsaturated carboxylic acids with 3 to 10 carbon atoms, 1,3-butadiene, and a-olefins bearing in the range of from 10 to 250 carbon atoms per molecule, in pure form or as mixture with isomers, and using a surfactant mixture comprising (A) an alkoxylation product of at least one alkanol (a), characterized in that alkanol (a) has 6 to 12 carbon atoms per molecule and the average number of alkylene oxide units per molecule in alkoxylation product (A) assumes a value in the range of from 35 to 55, the alkylene oxide units are selected from C2-C10-alkylene oxide units and alkanol (a) has an average degree of branching of at least 1; and (B) an alkoxylation product of at least one alkanol (b), characterized in that alkanol (b) has 13 to 19 carbon atoms per molecule and the average number of alkylene oxide units per molecule in alkoxylation product (B) assumes a value in the range of from 35 to 55, the alkylene oxide units are selected from C2-C10-alkylene oxide units, or (C) an alkoxylation product of at least one linear C12-C22-alkyl alcohol (c), characterized in that the average number of alkylene oxide units per molecule in alkoxylation product (C) assumes a value in the range of from 35 to 55, the alkylene oxide units are selected from C2-C10-alkylene oxide units.
摘要翻译: 在乳液聚合条件下聚合至少一种单体的方法,其特征在于(共)单体选自乙烯基芳族化合物,具有3-10个碳原子的烯属不饱和羧酸,烯属不饱和羧酸的C 1 -C 10烷基酯与 3至10个碳原子,1,3-丁二烯和每分子具有10至250个碳原子的α-烯烃,以纯形式或与异构体混合,并使用表面活性剂混合物,其包含(A)烷氧基化 至少一种链烷醇(a)的产物,其特征在于链烷醇(a)每分子具有6至12个碳原子,并且烷氧基化产物(A)中每分子的平均氧化烯单位数假定为35 至55,烯化氧单元选自C 2 -C 10 - 氧化烯单元,链烷醇(a)的平均支化度至少为1; 和(B)至少一种链烷醇(b)的烷氧基化产物,其特征在于链烷醇(b)每分子具有13至19个碳原子,并且烷氧基化产物(B)中每分子的平均氧化烯单元数呈现值 在35至55的范围内,烯化氧单元选自C 2 -C 10 - 氧化烯单元,或(C)至少一种直链C 12 -C 22烷基醇(c)的烷氧基化产物,其特征在于, 烷氧基化产物(C)中每分子的平均氧化烯单元数为35至55的范围,烯化氧单元选自C 2 -C 10 - 氧化烯单元。
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公开(公告)号:US20140378636A1
公开(公告)日:2014-12-25
申请号:US14371933
申请日:2013-06-11
申请人: BASF SE
CPC分类号: C08F2/44 , B01F17/0021 , C08F2/24 , C08F2/30
摘要: Process for polymerizing at least one monomer under emulsion polymerization conditions, characterized in that the (co)monomers are selected from vinyl aromatic compounds, ethylenically unsaturated carboxylic acids with 3 to 10 carbon atoms, C1-C10-alkyl esters of ethylenically unsaturated carboxylic acids with 3 to 10 carbon atoms, 1,3-butadiene, and a-olefins bearing in the range of from 10 to 250 carbon atoms per molecule, in pure form or as mixture with isomers, and using a surfactant mixture comprising (A) an alkoxylation product of at least one alkanol (a), characterized in that alkanol (a) has 6 to 12 carbon atoms per molecule and the average number of alkylene oxide units per molecule in alkoxylation product (A) assumes a value in the range of from 35 to 55, the alkylene oxide units are selected from C2-C10-alkylene oxide units and alkanol (a) has an average degree of branching of at least 1; and (B) an alkoxylation product of at least one alkanol (b), characterized in that alkanol (b) has 13 to 19 carbon atoms per molecule and the average number of alkylene oxide units per molecule in alkoxylation product (B) assumes a value in the range of from 35 to 55, the alkylene oxide units are selected from C2-C10-alkylene oxide units, or (C) an alkoxylation product of at least one linear C12-C22-alkyl alcohol (c), characterized in that the average number of alkylene oxide units per molecule in alkoxylation product (C) assumes a value in the range of from 35 to 55, the alkylene oxide units are selected from C2-C10-alkylene oxide units.
摘要翻译: 在乳液聚合条件下聚合至少一种单体的方法,其特征在于(共)单体选自乙烯基芳族化合物,具有3-10个碳原子的烯属不饱和羧酸,烯属不饱和羧酸的C 1 -C 10烷基酯与 3至10个碳原子,1,3-丁二烯和每分子具有10至250个碳原子的α-烯烃,以纯形式或与异构体混合,并使用表面活性剂混合物,其包含(A)烷氧基化 至少一种链烷醇(a)的产物,其特征在于链烷醇(a)每分子具有6至12个碳原子,烷氧基化产物(A)中每分子的平均氧化烯单元数目为35 至55,烯化氧单元选自C 2 -C 10 - 氧化烯单元,链烷醇(a)的平均支化度至少为1; 和(B)至少一种链烷醇(b)的烷氧基化产物,其特征在于链烷醇(b)每分子具有13至19个碳原子,并且烷氧基化产物(B)中每分子的平均氧化烯单元数呈现值 在35至55的范围内,烯化氧单元选自C 2 -C 10 - 氧化烯单元,或(C)至少一种直链C 12 -C 22烷基醇(c)的烷氧基化产物,其特征在于, 烷氧基化产物(C)中每分子的平均氧化烯单元数为35至55的范围,烯化氧单元选自C 2 -C 10 - 氧化烯单元。
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公开(公告)号:US20230203209A1
公开(公告)日:2023-06-29
申请号:US17928338
申请日:2021-06-02
申请人: BASF SE
发明人: Christian Hubert Weidl , Markus Roesch , Juergen Tropsch , Sebastian Mirtschin , Alexandra Wiedemann , Hans-Christian Raths , Bernd Schneider
IPC分类号: C08F2/26 , C08F220/18 , C08K5/1545 , C11D1/83
CPC分类号: C08F2/26 , C08F220/1804 , C08K5/1545 , C11D1/83
摘要: The presently claimed invention relates to the use of at least one compound of general formula (I) as an emulsifier or a stabilizer. The presently claimed invention further relates to the use of at least one compound of general formula (I) as an emulsifier or stabilizer in a polymerization reaction, preferably an emulsion polymerization. The presently claimed invention also relates to a method of emulsifying and/or stabilizing or dispersing liquids or solids in emulsion polymerization using at least one compound of general formula (I). Further, the presently claimed invention relates to a cleaning composition comprising at least one compound of general formula (I) and at least one additive.
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公开(公告)号:US09228106B2
公开(公告)日:2016-01-05
申请号:US14147013
申请日:2014-01-03
申请人: BASF SE
发明人: Szilard Csihony , Ivette Garcia Castro , Heike Pfistner , Eva Wagner , Pia Baum , Christian Hubert Weidl
IPC分类号: C09D191/06 , C09D123/08
CPC分类号: C09D123/08 , C09D191/06
摘要: An aqueous paint formulation having an aqueous basecoat and an aqueous dispersion having an at least partially neutralized ethylene copolymer wax, wherein the ethylene copolymer wax contains as comonomers in copolymerized form (A) 12-40 wt % of an ethylenically unsaturated carboxylic acid of formula (I), (B) 60-88 wt % of ethylene, and (C) 0-10 wt % of a further comonomer; or the ethylene copolymer was contains as comonomers in copolymerized form (A′) 5-50 wt % of a comonomer of formula (II), (B′) 50-95 wt % of ethylene, and (C′) 0-20 wt % of a further comonomer; wherein the ethylene copolymer wax comprising the comonomers (A), (B), and optionally (C) has a molecular weight Mw of 10000 to 150000 g/mol, and the ethylene copolymer wax comprising the comonomers (A′), (B′), and optionally (C′) has a molecular weight Mw of 5000 to 40000 g/mol.
摘要翻译: 一种具有底漆水溶液和含有至少部分中和的乙烯共聚物蜡的水性分散体的水性涂料配方,其中乙烯共聚物蜡含有共聚形式的共聚单体(A)12-40重量%的式(I)的烯键式不饱和羧酸 I),(B)60-88重量%的乙烯和(C)0-10重量%的另外的共聚单体; 或乙烯共聚物作为共聚单体(A')含有5-50重量%的式(II)共聚单体,(B')50-95重量%乙烯和(C')0-20重量%的共聚单体 %的另外的共聚单体; 其中包含共聚单体(A),(B)和任选的(C)的乙烯共聚物蜡的分子量Mw为10000至150000g / mol,并且包含共聚单体(A'),(B' ),任选地(C')的分子量Mw为5000〜40000g / mol。
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公开(公告)号:US20140116294A1
公开(公告)日:2014-05-01
申请号:US14147013
申请日:2014-01-03
申请人: BASF SE
发明人: Szilard CSIHONY , Ivette Garcia Castro , Heike Pfistner , Eva Wagner , Pia Baum , Christian Hubert Weidl
IPC分类号: C09D123/08
CPC分类号: C09D123/08 , C09D191/06
摘要: An aqueous paint formulation having an aqueous basecoat and an aqueous dispersion having an at least partially neutralized ethylene copolymer wax, wherein the ethylene copolymer wax contains as comonomers in copolymerized form (A) 12-40 wt % of an ethylenically unsaturated carboxylic acid of formula (I), (B) 60-88 wt % of ethylene, and (C) 0-10 wt % of a further comonomer; or the ethylene copolymer was contains as comonomers in copolymerized form (A′) 5-50 wt % of a comonomer of formula (II), (B′) 50-95 wt % of ethylene, and (C′) 0-20 wt % of a further comonomer; wherein the ethylene copolymer wax comprising the comonomers (A), (B), and optionally (C) has a molecular weight Mw of 10000 to 150000 g/mol, and the ethylene copolymer wax comprising the comonomers (A′), (B′), and optionally (C′) has a molecular weight Mw of 5000 to 40000 g/mol.
摘要翻译: 一种具有底漆水溶液和含有至少部分中和的乙烯共聚物蜡的水性分散体的水性涂料配方,其中乙烯共聚物蜡含有共聚形式的共聚单体(A)12-40重量%的式(I)的烯属不饱和羧酸 I),(B)60-88重量%的乙烯和(C)0-10重量%的另外的共聚单体; 或乙烯共聚物作为共聚单体(A')含有5-50重量%的式(II)共聚单体,(B')50-95重量%乙烯和(C')0-20重量%的共聚单体 %的另外的共聚单体; 其中包含共聚单体(A),(B)和任选的(C)的乙烯共聚物蜡的分子量Mw为10000至150000g / mol,并且包含共聚单体(A'),(B' ),任选地(C')的分子量Mw为5000〜40000g / mol。
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