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公开(公告)号:US11986798B2
公开(公告)日:2024-05-21
申请号:US17043764
申请日:2019-04-01
Applicant: BASF SE
Inventor: Christophe Bauduin , Thomas Daniel
CPC classification number: B01J20/267 , A61L15/18 , A61L15/24 , A61L15/54 , A61L15/60 , B01J20/08 , B01J20/3021 , B01J20/3085 , C08F220/06 , C08F2800/10 , C08F2810/20
Abstract: A highly permeable superabsorbent is prepared by a process comprising
polymerizing an aqueous monomer solution comprising
a) at least one ethylenically unsaturated monomer which bears acid groups and is optionally at least partly in salt form,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomers copolymerizable with the monomers mentioned under a), and
e) optionally one or more water-soluble polymers;
drying the resulting polymer,
optionally grinding the dried polymer and sieving the ground polymer,
optionally surface postcrosslinking the dried and optionally ground and sieved polymer,
wherein, after drying, grinding or sieving, and, if surface postcrosslinking is conducted, during or after this surface postcrosslinking, x-ray-amorphous aluminum hydroxide powder is added.-
公开(公告)号:US09585798B2
公开(公告)日:2017-03-07
申请号:US14753511
申请日:2015-06-29
Applicant: BASF SE
Inventor: Christophe Bauduin
IPC: A61F13/15 , A61F13/532 , A61F13/53 , A61L15/42 , A61L15/60 , A61F13/511 , A61F13/514 , A61F13/539 , A61L15/22 , A61L15/24 , A61L15/26 , A61L15/28 , A61L15/58 , A61F13/531
CPC classification number: A61F13/5323 , A61F13/511 , A61F13/51401 , A61F13/53 , A61F13/531 , A61F13/539 , A61F2013/530007 , A61F2013/530131 , A61F2013/530481 , A61F2013/530802 , A61F2013/53941 , A61L15/22 , A61L15/24 , A61L15/26 , A61L15/28 , A61L15/42 , A61L15/425 , A61L15/58 , A61L15/60 , Y10T442/699
Abstract: The present invention relates to improved water-absorbing storage layers for use in hygiene articles, the water-absorbing storage layers being essentially free of cellulose fibers.
Abstract translation: 本发明涉及用于卫生制品的改进的吸水层,吸水层基本上不含纤维素纤维。
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公开(公告)号:US20140324005A1
公开(公告)日:2014-10-30
申请号:US14353320
申请日:2012-10-24
Applicant: BOSTIK INC. , BASF SE
Inventor: Christophe Bauduin , Jean-Francois Chartrel , Thomas Daniel , Julien Liger , Renate Wuestefeld
IPC: A61F13/539 , A61F13/15
CPC classification number: A61F13/15699 , A61F13/15658 , A61F13/15707 , A61F13/15747 , A61F13/532 , A61F13/5323 , A61F13/538 , A61F13/539 , A61F2013/530481 , A61F2013/530547 , A61F2013/530562 , A61F2013/53908 , A61F2013/53925 , A61F2013/53933 , A61F2013/5395 , A61F2013/53958 , Y10T156/10 , Y10T156/1049
Abstract: The present invention is directed to a liquid-absorbing article comprising: a first sheet layer presenting an array of absorbent receiving pockets; masses of superabsorbent material, which masses are placed in said absorbent receiving pockets; a second sheet layer placed on top of the first layer; bonding beads placed between the respective pockets.
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公开(公告)号:US20140276511A1
公开(公告)日:2014-09-18
申请号:US14353342
申请日:2012-10-24
Applicant: BOSTIK INC. , BASF SE
Inventor: Christophe Bauduin , Jean-Francois Chartrel , Thomas Daniel , Julien Liger , Renate Wuestefeld
IPC: A61F13/539 , A61F13/15 , A61F13/538
CPC classification number: A61F13/15699 , A61F13/15658 , A61F13/15707 , A61F13/15747 , A61F13/532 , A61F13/5323 , A61F13/538 , A61F13/539 , A61F2013/530481 , A61F2013/530547 , A61F2013/530562 , A61F2013/53908 , A61F2013/53925 , A61F2013/53933 , A61F2013/5395 , A61F2013/53958 , Y10T156/10 , Y10T156/1049
Abstract: The present invention is directed to a liquid-absorbing article comprising: a first sheet layer presenting an array of absorbent receiving pockets; masses of superabsorbent material, which masses are placed in said absorbent receiving pockets; a second sheet layer placed on top of the first layer; bonding beads placed between the respective pockets.
Abstract translation: 本发明涉及一种液体吸收制品,其包括:呈现吸收容纳袋阵列的第一片层; 大块超吸收材料,其中的质量被放置在所述吸收剂容纳口中; 放置在第一层的顶部上的第二片层; 粘合珠放置在相应的口袋之间。
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公开(公告)号:US11846645B2
公开(公告)日:2023-12-19
申请号:US17616705
申请日:2020-06-24
Applicant: BASF SE
Inventor: Thomas Daniel , Markus Toennessen , Christophe Bauduin
CPC classification number: G01N5/02 , G01N15/08 , G01N2015/0866
Abstract: In a method of measuring parameters of superabsorbents, the absorption capacity of superabsorbents is determined under pressure, by reducing the pressure applied to a sample of the superabsorbent stepwise and determining the absorption capacity at each pressure. In addition, the rise in absorption capacity after a reduction in pressure is measured as a function of time and this is used to calculate the swelling constant k or the characteristic swelling time τ. Swelling constant or characteristic swelling time or the magnitude of the difference in absorption capacity at two different pressures are used to determine further parameters of the superabsorbent.
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公开(公告)号:US11491463B2
公开(公告)日:2022-11-08
申请号:US16958793
申请日:2019-01-02
Applicant: BASF SE
Inventor: Stephan Bauer , Katrin Baumann , Markus Toennessen , Christophe Bauduin , Markus Christian Biel , Thomas Daniel
Abstract: Superabsorbent mixtures M comprising at least 70% by weight of superabsorbent A having a liquid absorption of 20 g/g (T20) of less than 300 s and/or a volumetric liquid absorption under pressure 0.3 psi (2.07 kPa) (VAUL) with a τ value of less than 400 s, and at least 5% by weight of superabsorbent B having a centrifuge retention capacity (CRC) of at least 30 g/g.
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公开(公告)号:US20200060897A1
公开(公告)日:2020-02-27
申请号:US16482045
申请日:2018-02-12
Applicant: BASF SE
Inventor: Thomas Daniel , Christophe Bauduin , Katrin Baumann , Katarzyna Dobrosielska-Oura
IPC: A61F13/537 , A61L15/60
Abstract: A fluid-absorbent article includes an upper liquid-pervious layer (A), a lower liquid-impervious layer (B), a fluid-absorbent core (C) between (A) and (B) including at least 60% by weight of non-surface postcrosslinked fluid-absorbent polymer particles and not more than 40% by weight of fibrous material, based on the sum of non-surface postcrosslinked fluid-absorbent polymer particles and fibrous material. An acquisition-distribution layer (D) between (A) and (C) includes at least 90% by weight of synthetic fibers and not more than 10% by weight of cellulose based fibers, based on the sum of synthetic fibers and cellulose based fibers. The basis weight of the acquisition-distribution layer (D) is at least 70 gsm. The fluid-absorbent polymer particles have a saline flow conductivity (SFC) of less than 5×10−7 cm3s/g and an AUHL of less than 15 g/g. Preferably the acquisition-distribution layer (D) is a non-woven web including a three dimensional network of fibers.
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公开(公告)号:US12196660B2
公开(公告)日:2025-01-14
申请号:US16968225
申请日:2019-02-18
Applicant: BASF SE
Inventor: Markus Toennessen , Marc Haefner , Karsten Kraemer , Christophe Bauduin , Thomas Daniel
IPC: G01N15/08
Abstract: A method of measuring indices in superabsorbents, by initially charging excess aqueous solution or dispersion, swelling the superabsorbent in the initially charged aqueous solution or dispersion while stirring, dissolving or dispersing a component A in the aqueous solution or dispersion, measuring the enrichment of component A in the aqueous solution or dispersion during the swelling of the superabsorbent, using the enrichment of component A in the aqueous solution or dispersion to measure the time-dependent swelling characteristics and using these to determine the swelling constant k or the characteristic swell time τ, the index being dependent on the permeability of the superabsorbent, and ascertaining the index by means of a correlation measured beforehand between swelling constant k and index or characteristic swell time τ and index.
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公开(公告)号:US11332550B2
公开(公告)日:2022-05-17
申请号:US16488659
申请日:2018-02-26
Applicant: BASF SE
Inventor: Stephan Bauer , Markus Toennessen , Christophe Bauduin , Katrin Baumann , Marco Krüger , Andreas Daiss , Markus Muehl
Abstract: An apparatus for production of pulverulent polymers having a reactor for droplet polymerization with an apparatus for dropletization of a monomer solution for the preparation of the polymer. The apparatus for dropletization has holes through which the monomer solution is introduced, an addition point for a gas above the apparatus for dropletization, at least one gas withdrawal point at the periphery of the reactor and a fluidized bed, wherein at least one of the following is fulfilled: an apparatus for increasing turbulence in the gas flow is disposed in the region of the apparatus for dropletization of the monomer solution, an apparatus for increasing turbulence in the gas flow is disposed in the region of the addition point for the gas, the addition point for gas is configured such that elevated turbulence is generated. A process for producing pulverulent polymers, in which an increase in flow turbulence in the gas flow in the region of the apparatus for dropletization also is disclosed.
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公开(公告)号:US11142614B2
公开(公告)日:2021-10-12
申请号:US16217740
申请日:2018-12-12
Applicant: BASF SE
Inventor: Thomas Daniel , Norbert Herfert , Stephan Bauer , Katrin Baumann , Birgit Reinhard , Jürgen Freiberg , Christophe Bauduin , Katarzyna Dobrosielska-Oura , Michael A. Mitchell
IPC: C08J3/24 , C08J9/00 , A61L15/22 , A61L15/42 , A61L15/60 , B01J20/26 , B01J20/28 , C08F6/00 , C08F220/06 , C08F222/10
Abstract: The present invention relates to a process for producing surface-postcrosslinked water-absorbent polymer particles by coating of water-absorbent polymer particles having a content of residual monomers in the range from 0.03 to 15% by weight with at least one surface-postcrosslinker and thermal surface-postcrosslinking at temperatures in the range from 100 to 180° C.
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