公开(公告)号：US20190210010A1

公开(公告)日：2019-07-11

申请号：US16335785

申请日：2017-09-14

Applicant: BASF SE

Inventor： Rolf Pinkos ,  Irene de Wispelaere ,  Michael Schwarz ,  Michael Schreiber ,  Zeljko Kotanjac ,  Michael Nilles

IPC: B01J25/02 ,  B01J35/04 ,  B01J23/72 ,  B01J35/00 ,  B01J35/10 ,  B01J35/06 ,  B01J37/18 ,  B01J37/08 ,  B01J37/02 ,  B01J37/00 ,  C07C29/145 ,  C07C29/17 ,  C07C29/141

CPC classification number: B01J25/02 ,  B01J23/72 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/04 ,  B01J35/06 ,  B01J35/10 ,  B01J37/0018 ,  B01J37/0215 ,  B01J37/06 ,  B01J37/08 ,  B01J37/18 ,  C07C29/141 ,  C07C29/145 ,  C07C29/172 ,  C07C31/12 ,  C07C31/207 ,  C07C33/20

Abstract: A process for hydrogenating a hydrogenatable organic compound in a reactor including a fixed catalyst bed. The fixed catalyst bed includes monolithic shaped catalyst bodies having pores and/or channels. The catalyst bodies include at least one element selected from Ni, Fe, Co, Cu, Cr, Pt, Ag, Au, Pd, Mn, Re, Ru, Rh and Ir. The CO content in the gas phase within the reactor during hydrogenation is within a range from 0.1 to 10,000 ppm by volume. In any section in the normal plane to flow direction through the fixed catalyst bed, at least 90% of the pores and channels have an area of not more than 3 mm2.

公开(公告)号：US20200269227A1

公开(公告)日：2020-08-27

申请号：US16648502

申请日：2018-09-10

Applicant: BASF SE

Inventor： Marie Katrin Schroeter ,  Irene de Wispelaere ,  Michael Schwarz ,  Rolf Pinkos ,  Inna Schwabauer

IPC: B01J37/00 ,  B01J35/04 ,  B01J21/04 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  B01J23/755 ,  C07C29/17 ,  C07C29/141

Abstract: Provided herein is a novel process for producing shaped catalyst bodies in which a mixture having aluminum contents of Al=0 in the range from 80 to 99.8% by weight, based on the mixture used, is used to form a specific intermetallic phase, shaped catalyst bodies obtainable by the process of the invention, a process for producing an active catalyst fixed bed including the shaped catalyst bodies provided herein, the active catalyst fixed beds and also the use of these active catalyst fixed beds for the hydrogenation of organic hydrogenatable compounds or for formate degradation.

公开(公告)号：US20160244387A1

公开(公告)日：2016-08-25

申请号：US15030627

申请日：2014-10-13

Applicant: BASF SE

Inventor： Rolf Pinkos ,  Olga Osetska ,  Irene de Wispelaere ,  Stefan Dudenhoeffer ,  Christina Walczuch

IPC: C07C29/80 ,  B01D3/34 ,  B01D3/14 ,  C07C29/94

CPC classification number: C07C29/80 ,  B01D3/141 ,  B01D3/34 ,  C07C29/88 ,  C07C29/94 ,  C07C31/207

Abstract: Method for preparing 1,4-butanediol having an APHA color index of less than 30 by treating substance mixtures comprising 1,4-butanediol by distillation of the 1,4-butanediol in the presence of complex hydrides.

Abstract translation: 通过在复合氢化物存在下蒸馏1,4-丁二醇，通过处理包含1,4-丁二醇的物质混合物制备APHA颜色指数小于30的1,4-丁二醇的方法。

公开(公告)号：US11173479B2

公开(公告)日：2021-11-16

申请号：US16648502

申请日：2018-09-10

Applicant: BASF SE

Inventor： Marie Katrin Schroeter ,  Irene de Wispelaere ,  Michael Schwarz ,  Rolf Pinkos ,  Inna Schwabauer

IPC: C07C29/141 ,  B01J37/00 ,  B01J21/04 ,  B01J23/755 ,  B01J35/04 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C07C29/17

Abstract: Provided herein is a novel process for producing shaped catalyst bodies in which a mixture having aluminum contents of Al±0 in the range from 80 to 99.8% by weight, based on the mixture used, is used to form a specific intermetallic phase, shaped catalyst bodies obtainable by the process of the invention, a process for producing an active catalyst fixed bed including the shaped catalyst bodies provided herein, the active catalyst fixed beds and also the use of these active catalyst fixed beds for the hydrogenation of organic hydrogenatable compounds or for formate degradation.

公开(公告)号：US20200016583A1

公开(公告)日：2020-01-16

申请号：US16335897

申请日：2017-09-14

Applicant: BASF SE

Inventor： Tobias Maximilian Merkel ,  Michael Schreiber ,  Irene de Wispelaere ,  Rolf Pinkos

IPC: B01J35/04 ,  B01J25/02 ,  B01J23/883 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/06 ,  B01J37/08 ,  B01J37/18 ,  B01J35/02

Abstract: Described herein is a process for providing a catalytically active fixed bed for hydrogenation of organic compounds, in which a fixed bed including monolithic shaped bodies as catalyst supports or consisting of monolithic shaped bodies is introduced into a reactor and the fixed bed is then contacted with at least one catalyst or a precursor thereof. The fixed beds laden with a catalyst that are obtained in this way are especially suitable for the hydrogenation of organic compounds in the presence of CO, wherein the conversion is at least 90%. They are notable in that only a very small proportion, if any, of the catalyst introduced is released into the reaction medium.

公开(公告)号：US09975829B2

公开(公告)日：2018-05-22

申请号：US15030627

申请日：2014-10-13

Applicant: BASF SE

Inventor： Rolf Pinkos ,  Olga Osetska ,  Irene de Wispelaere ,  Stefan Dudenhoeffer ,  Christina Walczuch

IPC: B01D3/34 ,  C07C29/80 ,  C07C29/88 ,  B01D3/14 ,  C07C29/94

CPC classification number: C07C29/80 ,  B01D3/141 ,  B01D3/34 ,  C07C29/88 ,  C07C29/94 ,  C07C31/207

Abstract: Method for preparing 1,4-butanediol having an APHA color index of less than 30 by treating substance mixtures comprising 1,4-butanediol by distillation of the 1,4-butanediol in the presence of complex hydrides.