公开(公告)号：US11560446B2

公开(公告)日：2023-01-24

申请号：US16473340

申请日：2017-12-27

Applicant: BASF SE

Inventor： Joseph Ogonowski ,  Chulhoon Jang ,  Achara Bowornprasirtkul

IPC: C08G18/48 ,  C08G18/10 ,  C08G18/08 ,  C08G18/76 ,  C08J9/00 ,  C08J9/12 ,  C08J9/14 ,  C08J9/20

Abstract: A polyurethane foam article comprises the reaction product of an isocyanate component and isocyanate-reactive composition in the presence of a blowing agent. The isocyanate component includes an isocyanate prepolymer comprising the reaction product of a first polyether polyol and a methylene diphenyl diisocyanate. The isocyanate-reactive composition comprises a second polyether polyol having secondary terminal hydroxyl groups and an amine-initiated catalytic polyether polyol having primary hydroxyl groups. A method of making the polyurethane foam article comprises the steps of reacting the first polyether polyol and methylene diphenyl diisocyanate to form the isocyanate prepolymer and reacting the isocyanate prepolymer with the isocyanate-reactive composition in the presence of the blowing agent to form the polyurethane foam article.

公开(公告)号：US09598605B2

公开(公告)日：2017-03-21

申请号：US14449497

申请日：2014-08-01

Applicant: BASF SE

Inventor： Joseph Ogonowski

IPC: C09D175/08 ,  B05B1/02 ,  B05B7/00 ,  B05B7/16 ,  B05B7/26 ,  B05C5/02 ,  B05B1/04 ,  B05B1/06 ,  B29B7/32 ,  B29B7/74 ,  B29B7/80 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G18/50 ,  C08J9/14 ,  C08G101/00

CPC classification number: C09D175/08 ,  B05B1/02 ,  B05B1/042 ,  B05B1/06 ,  B05B7/0031 ,  B05B7/0075 ,  B05B7/1693 ,  B05B7/26 ,  B05C5/02 ,  B29B7/325 ,  B29B7/7404 ,  B29B7/805 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/4883 ,  C08G18/5033 ,  C08G2101/0025 ,  C08G2150/50 ,  C08G2150/60 ,  C08J9/14 ,  C08J2201/022 ,  C08J2375/04

Abstract: A method minimizes emissions while spraying a mixture of a resin composition and a polyisocyanate onto a surface. The resin composition has a hydroxyl content of at least 400 mg KOH/g and includes a blowing agent that is a liquid under pressure, a first polyol, at least one additional polyol other than the first polyol, and optionally a catalyst, surfactant, and water. The mixture is sprayed onto the surface to form a polyurethane foam having a closed cell content of at least 90 percent. The mixture is also sprayed through a spray nozzle at a spray angle corresponding to a control spray angle of from 15 to 125 degrees measured at a pressure of from 10 to 40 psi using water as a standard. The step of spraying produces less than 50 parts of the polyisocyanate per one billion parts of air according to OSHA Method 47.

公开(公告)号：US09592516B2

公开(公告)日：2017-03-14

申请号：US13729540

申请日：2012-12-28

Applicant: BASF SE

Inventor： Todd William Wishneski ,  Joseph Ogonowski ,  Mario Jean-Rejouis ,  Marcus Hunter

IPC: B05B7/00 ,  B05B7/16 ,  B05B1/04 ,  B05B1/06 ,  B29B7/32 ,  B29B7/74 ,  C08G18/48 ,  C08G18/50 ,  C08G18/40 ,  C08G18/42 ,  C08G101/00 ,  B05D1/34 ,  B05D1/02

CPC classification number: B05B1/04 ,  B05B1/042 ,  B05B1/06 ,  B05D1/02 ,  B05D1/34 ,  B05D2503/00 ,  B29B7/325 ,  B29B7/7404 ,  B29B7/7433 ,  B29B7/7447 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/4883 ,  C08G18/5033 ,  C08G2101/0025 ,  C08G2150/50 ,  C08G2150/60

Abstract: A polyurethane spraying system minimizes emissions of a polyisocyanate while spraying a mixture of a polyisocyanate and a resin composition onto a surface. The system includes a first reactant supply tank including the resin composition. The system also includes a second reactant supply tank including the polyisocyanate. The system further includes a non-gaseous pump that is coupled with the first and second reactant supply tanks, a mixing apparatus that is coupled with the first and second reactant supply tanks for mixing the resin composition and the polyisocyanate prior to spraying, and a particular spray nozzle that is coupled with the mixing apparatus. The polyurethane spraying system produces less than 50 parts of the polyisocyanate per one billion parts of air according to the NIOSH 5521 Impingement Method while spraying the mixture onto the surface.

Abstract translation: 聚氨酯喷涂系统使多异氰酸酯的排放最小化，同时将多异氰酸酯和树脂组合物的混合物喷涂到表面上。 该系统包括包含树脂组合物的第一反应物供应罐。 该系统还包括包含多异氰酸酯的第二反应物供应罐。 该系统还包括与第一和第二反应物供应罐联接的非气体泵，与第一和第二反应物供应罐联接以在喷雾之前混合树脂组合物和多异氰酸酯的混合设备，以及特定的 与混合装置连接的喷嘴。 聚氨酯喷涂系统根据NIOSH 5521冲击法在每十亿份空气中产生少于50份的多异氰酸酯，同时将混合物喷洒在表面上。