公开(公告)号：US20140315023A1

公开(公告)日：2014-10-23

申请号：US14357300

申请日：2012-11-13

Applicant: BASF SE ,  EMPA MATERIALS SCIENCE AND TECHNOLOGY

Inventor： Roman Fasel ,  Pascal Ruffieux ,  Klaus Muellen ,  Stephan Blankenburg ,  Jinming Cai ,  Xinliang Feng ,  Carlo Pignedoli ,  Daniele Passerone

IPC: C01B31/04 ,  C01B31/00

CPC classification number: C01B32/184 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/182 ,  C01B2204/06 ,  C01B2204/065 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/896 ,  Y10S977/932 ,  Y10T428/298 ,  Y10T428/2982

Abstract: The present invention relates to a segmented graphene nanoribbon, comprising at least two different graphene segments covalently linked to each other, each graphene segment having a monodisperse segment width, wherein the segment width of at least one of said graphene segments is 4 nm or less and to a method for preparing it by polymerizing at least one polycyclic aromatic monomer compound and/or at least one oligo phenylene aromatic hydrocarbon monomer compound to form at least one polymer and by at least partially cyclodehydrogenating the one or more polymer.

Abstract translation: 本发明涉及一种分段石墨烯纳米棒，其包括彼此共价连接的至少两个不同的石墨烯段，每个石墨烯段具有单分散段宽度，其中至少一个所述石墨烯段的段宽度为4nm或更小， 涉及一种通过聚合至少一种多环芳族单体化合物和/或至少一种低聚亚苯基芳族烃单体化合物以形成至少一种聚合物并通过至少部分地将该一种或多种聚合物环化而制备该方法。

公开(公告)号：US09975777B2

公开(公告)日：2018-05-22

申请号：US14357300

申请日：2012-11-13

Applicant: BASF SE ,  EMPA MATERIALS SCIENCE AND TECHNOLOGY

Inventor： Roman Fasel ,  Pascal Ruffieux ,  Klaus Muellen ,  Stephan Blankenburg ,  Jinming Cai ,  Xinliang Feng ,  Carlo Pignedoli ,  Daniele Passerone

IPC: C01B31/04 ,  C01B31/00 ,  C08G61/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/182 ,  C01B32/184

CPC classification number: C01B32/184 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/182 ,  C01B2204/06 ,  C01B2204/065 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/896 ,  Y10S977/932 ,  Y10T428/298 ,  Y10T428/2982

Abstract: The present invention relates to a segmented graphene nanoribbon, comprising at least two different graphene segments covalently linked to each other, each graphene segment having a monodisperse segment width, wherein the segment width of at least one of said graphene segments is 4 nm or less and to a method for preparing it by polymerizing at least one polycyclic aromatic monomer compound and/or at least one oligo phenylene aromatic hydrocarbon monomer compound to form at least one polymer and by at least partially cyclodehydrogenating the one or more polymer.

公开(公告)号：US20150030968A1

公开(公告)日：2015-01-29

申请号：US14384095

申请日：2013-02-26

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Zhong-Shuai Wu

IPC: H01G11/24 ,  H01M4/96 ,  H01M4/90 ,  H01G11/32 ,  H01G11/56

CPC classification number: H01G11/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/192 ,  H01G11/32 ,  H01G11/36 ,  H01G11/56 ,  H01M4/90 ,  H01M4/96 ,  Y02E60/13

Abstract: The present invention relates to an aerogel based on doped graphene, a method for producing said aerogel and the use of said aerogel, for example, as an electrode or a catalyst. Furthermore, the present invention relates to electrodes, all solid-state supercapacitors (ASSS) or catalysts based on said aerogel. The present invention also relates to doped graphene, which can be obtained as an intermediate in the production of the aerogel based on doped graphene using graphene oxide as starting material.

Abstract translation: 本发明涉及一种基于掺杂石墨烯的气凝胶，一种制备所述气凝胶的方法和所述气凝胶的使用，例如电极或催化剂。 此外，本发明涉及电极，所有固态超级电容器（ASSS）或基于所述气凝胶的催化剂。 本发明还涉及掺杂石墨烯，其可以在使用氧化石墨烯作为起始材料的基于掺杂石墨烯的气凝胶生产中作为中间体获得。

公开(公告)号：US20140353554A1

公开(公告)日：2014-12-04

申请号：US14367041

申请日：2012-12-17

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Akimitsu Narita ,  Xinliang Feng ,  Klaus Muellen

IPC: C01B31/04 ,  C08F138/00 ,  H01B1/04 ,  C07C49/683

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C07C49/683 ,  C08F2/00 ,  C08F138/00 ,  C08G61/10 ,  C08G2261/1412 ,  C08G2261/312 ,  C08G2261/364 ,  C08G2261/46 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  H01B1/04 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

Abstract: An oligophenylene monomer of general formula (I) wherein R1 and R2 are independently of each other H, halogene, —OH, —NH2, —CN, —NO2 or a linear or branched, saturated or unsaturated C1-C40 hydrocarbon residue, which can be substituted 1- to 5-fold with halogene (F, Cl, Br, I), —OH, —NH2, —CN and/or —NO2, and wherein one or more CH2-groups can be replaced by —O— or —S—, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; and m represents 0, 1 or 2.

Abstract translation: 通式（I）的低聚苯乙烯单体，其中R 1和R 2彼此独立地为H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以 用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 基团可以被-O-或 -S-或任选取代的芳基，烷基芳基或烷氧基芳基; m表示0,1或2。

公开(公告)号：US20140301935A1

公开(公告)日：2014-10-09

申请号：US14354329

申请日：2012-10-24

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Sorin Ivanovici ,  Matthias Georg Schwab ,  Xinliang Feng ,  Klaus Muellen

IPC: C01B31/04 ,  C08G61/10 ,  C07C17/30 ,  C07C25/18

CPC classification number: C07C25/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07C17/093 ,  C07C17/263 ,  C07C17/30 ,  C07C17/361 ,  C07C2603/42 ,  C07C2603/54 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/412 ,  Y10S977/734 ,  Y10S977/842 ,  C07C25/22 ,  C07C25/24

Abstract: Oligophenylene monomers for the synthesis of polymeric precursors for the preparation of graphene nanoribbons, the polymeric precursors, and methods for preparing them, as well as methods for preparing the graphene nanoribbons from the polymeric precursors and the monomers are provided.

Abstract translation: 提供用于合成制备石墨烯纳米带的聚合物前体的亚乙基单体，聚合物前体及其制备方法，以及从聚合物前体和单体制备石墨烯纳米带的方法。

公开(公告)号：US09550678B2

公开(公告)日：2017-01-24

申请号：US14367041

申请日：2012-12-17

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e. V.

Inventor： Matthias Georg Schwab ,  Akimitsu Narita ,  Xinliang Feng ,  Klaus Muellen

IPC: C01B31/04 ,  C07C49/683 ,  C08F138/00 ,  H01B1/04 ,  C08F2/00 ,  B82Y30/00 ,  B82Y40/00 ,  C08G61/10 ,  C08L65/00

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C07C49/683 ,  C08F2/00 ,  C08F138/00 ,  C08G61/10 ,  C08G2261/1412 ,  C08G2261/312 ,  C08G2261/364 ,  C08G2261/46 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  H01B1/04 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

Abstract: An oligophenylene monomer of general formula (I) wherein R1 and R2 are independently of each other H, halogene, —OH, —NH2, —CN, —NO2 or a linear or branched, saturated or unsaturated C1-C40 hydrocarbon residue, which can be substituted 1-to 5-fold with halogene (F, Cl, Br, I), —OH, —NH2, —CN and/or —NO2, and wherein one or more CH2-groups can be replaced by —O— or —S—, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; and m represents 0, 1 or 2.

Abstract translation: 通式（I）的低聚苯乙烯单体，其中R 1和R 2彼此独立地为H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以 用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 基团可以被-O-或 -S-或任选取代的芳基，烷基芳基或烷氧基芳基; m表示0,1或2。

公开(公告)号：US09434619B2

公开(公告)日：2016-09-06

申请号：US14354430

申请日：2012-10-24

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Lukas Doessel

IPC: C01B31/02 ,  C01B31/04 ,  B82Y40/00 ,  C07C17/30 ,  C07C25/18 ,  C08G61/10 ,  B82Y30/00

CPC classification number: C08G61/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07C15/14 ,  C07C17/30 ,  C07C25/18 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  C08G2261/412 ,  H01L51/0045 ,  H01L51/0558 ,  H01L51/102

Abstract: Provided are graphene nanoribbon precursors comprising repeated units of the general formula (I) in which R1, R2 are each H, halogen, —OH, —NH2, —CN, —NO2 or a hydrocarbyl radical which has 1 to 40 carbon atoms and may be linear or branched, saturated or unsaturated and mono- or poly-substituted by halogen (F, Cl, Br, I), —OH, —NH2, —CN, and/or —NO2, where one or more CH2 groups may also be replaced by —O—, —S—, —C(O)O—, —O—C(O)—, —C(O)—, —NH— or —NR—, in which R is an optionally substituted C1C40-hydrocarbyl radical, or an optionally substituted aryl, alkylaryl or alkoxyaryl radical.

公开(公告)号：US10329378B2

公开(公告)日：2019-06-25

申请号：US15118796

申请日：2015-02-09

Applicant: BASF SE ,  EMPA-Eidgenoessische Materialpruefungs- und Forschungsanstalt ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Bo Yang ,  Tim Dumslaff ,  Roman Fasel ,  Pascal Ruffieux ,  Jia Liu ,  Jinming Cai ,  Carlos Sanchez-Sanchez ,  Junzhi Liu

IPC: C07C25/22 ,  C08G61/10 ,  C07C15/20 ,  C01B32/184

Abstract: Provided are graphene nanoribbons with controlled zig-zag edge and cove edge configuration and methods for preparing such graphene nanoribbons. The nanoribbons are selected from the following formulae.

公开(公告)号：US09676755B2

公开(公告)日：2017-06-13

申请号：US14402560

申请日：2013-05-13

Applicant: BASF SE ,  EMPA—EIDGENOESSISCHE MATERIALPRUEFUNGS- UND FORSCHUNGSANSTALT ,  MAX-PLANCK-GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN E.V.

Inventor： Roman Fasel ,  Pascal Ruffieux ,  Klaus Muellen ,  Jinming Cai ,  Xinliang Feng ,  Reinhard Berger

IPC: C07D403/10 ,  C01B31/04 ,  C07D215/18 ,  C07D237/26 ,  C07D239/72 ,  C07D209/56 ,  B82Y30/00 ,  B82Y40/00

CPC classification number: C07D403/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07D209/56 ,  C07D215/18 ,  C07D237/26 ,  C07D239/72

Abstract: The present invention relates to a graphene nanoribbon, comprising a repeating unit which comprises at least one modification, wherein the modification is selected from a heteroatomic substitution, a vacancy, a sp3 hybridization, a Stone-Wales defect, an inverse Stone-Wales defect, a hexagonal sp2 hybridized carbon network ring size modification, and any combination thereof.

公开(公告)号：US20150333124A1

公开(公告)日：2015-11-19

申请号：US14652514

申请日：2013-12-02

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V.

Inventor： Tobias Hintermann ,  Klaus Muellen ,  Xinliang Feng ,  Yuan-Zhi Tan

IPC: H01L29/16 ,  H01B1/04 ,  C07C17/02

CPC classification number: H01L29/1606 ,  C01B32/192 ,  C01B32/194 ,  C07C17/02 ,  H01B1/04

Abstract: The present invention relates to a process for edge-halogenation of a graphene material; wherein the graphene material, which is selected from graphene, a graphene nanoribbon, a graphene molecule, or a mixture thereof, is reacted with a halogen-donor compound in the presence of a Lewis acid, so as to obtain an edge-halogenated graphene material.

Abstract translation: 本发明涉及石墨烯材料的边缘卤化方法; 其中选自石墨烯，石墨烯纳米棒，石墨烯分子或其混合物中的石墨烯材料在路易斯酸存在下与卤素给体化合物反应，以获得边缘卤化石墨烯材料 。