PROCESS FOR PRODUCING MINERAL OIL USING SURFACTANTS BASED ON A MIXTURE OF C32 GUERBET-, C34 GUERBET-, C36 GUERBET-CONTAINING ALKYL ALKOXYLATES
    1.
    发明申请
    PROCESS FOR PRODUCING MINERAL OIL USING SURFACTANTS BASED ON A MIXTURE OF C32 GUERBET-, C34 GUERBET-, C36 GUERBET-CONTAINING ALKYL ALKOXYLATES 有权
    使用C32GERBET-,C34 GUERBET-,C36含有烷基烷氧基化物的混合物,使用表面活性剂生产矿物油的方法

    公开(公告)号:US20150353818A1

    公开(公告)日:2015-12-10

    申请号:US14832425

    申请日:2015-08-21

    Applicant: BASF SE*

    CPC classification number: C09K8/86 C09K8/584 E21B43/16

    Abstract: The present invention relates to a process for mineral oil extraction by means of Winsor type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least three ionic surfactants which are different with regard to the alkyl moiety (R1)(R2)—CH—CH2— and are of the general formula (R1)(R2)—CH—CH2—O-(D)n-(B)m-(A)l-XYa−a/bMb+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to surfactant formulations of ionic surfactants of the general formula.

    Abstract translation: 本发明涉及一种通过Winsor III型微乳液淹水进行矿物油提取的方法,其中包含至少三种离子表面活性剂的水性表面活性剂制剂,其对于烷基部分(R 1)(R 2)-CH- CH 2 - 并且具有通式(R1)(R2)-CH-CH2-O-(D)n-(B)m-(A)1-XYa-a / bMb +通过注射钻孔注入矿物油 通过生产钻孔从存款中取出原油。 本发明还涉及通式为离子表面活性剂的表面活性剂制剂。

    NOVEL PROCESS FOR PREPARING CYCLOHEXANE FROM METHYLCYCLOPENTANE AND BENZENE
    2.
    发明申请
    NOVEL PROCESS FOR PREPARING CYCLOHEXANE FROM METHYLCYCLOPENTANE AND BENZENE 审中-公开
    从甲基环戊烷和苯甲腈制备环己烷的新工艺

    公开(公告)号:US20140114100A1

    公开(公告)日:2014-04-24

    申请号:US14053647

    申请日:2013-10-15

    Applicant: BASF SE

    Abstract: The present invention relates to a process for preparing cyclohexane from methylcyclopentane (MCP) and benzene. In the context of the present invention, MCP and benzene are constituents of a hydrocarbon mixture (HM1) additionally comprising dimethylpentanes (DMP), possibly cyclohexane and at least one compound (low boiler) selected from acyclic C5-C6-alkanes and cyclopentane. First of all, benzene is converted in a hydrogenation step to cyclohexane, while MCP is isomerized in the presence of a catalyst, preferably of an acidic ionic liquid, to cyclohexane. The hydrogenation is preceded by a prior removal of the dimethylpentanes (DMP), with initial removal of any cyclohexane present in the hydrocarbon mixture (HM1) together with DMP. This cyclohexane already present can be separated again from DMP in a downstream rectification step and recycled into the process for cyclohexane preparation. Between hydrogenation and isomerization, low boilers are removed and, after the isomerization, the cyclohexane is isolated with return of unisomerized MCP and optionally of low boilers.

    Abstract translation: 本发明涉及从甲基环戊烷(MCP)和苯制备环己烷的方法。 在本发明的上下文中,MCP和苯是另外包含二甲基戊烷(DMP),可能的环己烷和至少一种选自无环C5-C6烷烃和环戊烷的化合物(低沸点)的烃混合物(HM1)的组分。 首先,将苯在氢化步骤中转化为环己烷,而MCP在催化剂,优选酸性离子液体存在下异构化为环己烷。 之前先氢化二甲基戊烷(DMP),然后与DMP一起初始除去烃混合物(HM1)中存在的任何环己烷。 已经存在的环己烷可以在下游精馏步骤中再次从DMP分离并再循环到环己烷制备方法中。 在氢化和异构化之间,除去低锅炉,在异构化之后,环己烷被分离出来,分离出未异构化的MCP和任选的低锅炉。

    PROCESS FOR PREPARING CYCLOHEXANEPOLYCARBOXYLIC ACID DERIVATIVES HAVING A LOW PROPORTION OF BY-PRODUCTS
    3.
    发明申请
    PROCESS FOR PREPARING CYCLOHEXANEPOLYCARBOXYLIC ACID DERIVATIVES HAVING A LOW PROPORTION OF BY-PRODUCTS 有权
    制备具有较低比例的副产物的环己烷羧酸羧酸衍生物的方法

    公开(公告)号:US20140100387A1

    公开(公告)日:2014-04-10

    申请号:US14045178

    申请日:2013-10-03

    Applicant: BASF SE

    CPC classification number: C07C51/36 C07C61/09 C07C67/303 C07C2601/14 C07C69/75

    Abstract: The present invention relates to a process for preparing at least one cyclohexanepolycarboxylic acid or a derivative thereof by bringing at least one corresponding benzenepolycarboxylic acid or a derivative thereof into contact with a hydrogen-comprising gas in the presence of at least one coated catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixes thereof, applied to a support material comprising silicon dioxide, where the pore volume of the support material is from 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is from 280 to 500 m2/g, at least 90% of the pores present have a diameter of from 6 to 12 nm, and from 40 to 70% by weight of the active metal, based on the total amount of the active metal, are present in the catalyst coating up to a penetration depth of 200 μm, wherein the contacting is carried out at a superficial velocity of not more than 50 m/h.

    Abstract translation: 本发明涉及一种制备至少一种环己烷多羧酸或其衍生物的方法,该方法是使至少一种相应的苯多元羧酸或其衍生物与含氢气体在至少一种包含活性物质的涂层催化剂存在下接触 选自钌,铑,钯,铂及其混合物的金属,施加到包含二氧化硅的载体材料上,其中载体材料的孔体积为0.6至1.0ml / g,通过Hg孔隙率法测定, BET表面积为280〜500m2 / g,至少90%的孔具有6〜12nm的直径和40〜70重量%的活性金属,基于 活性金属存在于催化剂涂层中,直到穿透深度为200μm,其中接触以不大于50m / h的表观速度进行。

    Method for hydrogenating aromatic compounds

    公开(公告)号:US10329237B2

    公开(公告)日:2019-06-25

    申请号:US15103652

    申请日:2014-12-10

    Applicant: BASF SE

    Abstract: The present invention relates to a method for hydrogenating aromatic compounds with hydrogen in the presence of a catalyst, in which the catalyst comprises ruthenium on a zirconium oxide support material, and also the use of a catalyst comprising ruthenium on a zirconium oxide support material for hydrogenating aromatic compounds.

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