Process for the production of shaped articles particularly dental prostheses
    4.
    发明授权
    Process for the production of shaped articles particularly dental prostheses 失效
    形成形状特别是牙齿前体的方法

    公开(公告)号:US3649608A

    公开(公告)日:1972-03-14

    申请号:US3649608D

    申请日:1969-07-23

    Applicant: BAYER AG

    CPC classification number: A61K6/083 C08F265/06 C08F2/02

    Abstract: A PROCES FOR USE IN THE PRODUCTION OF DENTAL PROSTHESES, WHEREIN 25-27 PARTS BY WEIGHT OF A LIQUID CONSISTING PREDOMINANTLY OF MONOMERIC METHYL METHACRYLATE AND 73-75 PARTS BY WEIGHT OF A POLYMERPOWDER ARE MIXED TOGETHER. THE USE OF A POLYMER POWDER COMPRISING 85-60 PARTS OF A POLYMER OF METHACRYLIC ACID AND 40-15 PARTS OF AN ACRYLIC ACID ESTER/METHYL METHACRYLATE OR METHACRYLIC ACID ESTER/METHYL METHACRYLATE COPOLYMER, WHERE THE ESTER CONTENT IN THE COPOLYMER, THE MOLECULAR WEIGHT OF THE POLYMER AND COPOLYMER ARE REQUIRED TO BE WITHIN SPECIFIED RANGES RESULTS IN A RAPID START OF PROCESSING AND A PROCESSING TIME OF AT LEAST AN HOUR.

    Process for the production of acrylonitrile polymers by polymerizing on the presence of an aromatic sulfonamide
    6.
    发明授权
    Process for the production of acrylonitrile polymers by polymerizing on the presence of an aromatic sulfonamide 失效
    通过聚合在芳族磺酰胺存在下生产丙烯腈聚合物的方法

    公开(公告)号:US3441533A

    公开(公告)日:1969-04-29

    申请号:US3441533D

    申请日:1967-03-20

    Applicant: BAYER AG

    CPC classification number: C08F20/44 C08F2/36

    Abstract: A solution of an acrylonitrile polymer is produced by polymerizing acrylonitrile in an organic solvent for polyacrylonitrile, at a temperature of from + 10 DEG to - 68 DEG C. in the presence of 0.1 m.mol. to 0.1 mol., per mol of monomer, of an alkali metal salt of an aromatic sulphonamide of the formula wherein M represents Li, Na, K, Rb or Cs, Ar represents an aryl radical and R1 represents a hydrogen atom or an alkyl radical. Specified salts are those of benzene sulphonamide, benzene -N-methyl sulphonamide, p-toluene N-isopropyl or N-methyl sulphonamide and benzene N-hexyl sulphonamide and suitable solvents are dimethyl formamide and dimethyl sulphoxide. In examples solutions of polyacrylonitrile in dimethyl formamide are produced using as catalyst potassium or sodium p-toluene N-methyl sulphonamide. The catalyst is deactivated with HCl or HCO2H.

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