ETHYLENE-OCTENE COPOLYMERS WITH IMPROVED PROPERTY PROFILE

    公开(公告)号:US20230312789A1

    公开(公告)日:2023-10-05

    申请号:US18022595

    申请日:2021-09-27

    Applicant: Borealis AG

    Abstract: Ethylene-1-octene copolymer characterized by a density in the range of 850 kg/m3 to 930 kg/m3 measured according to ISO 1183-187, a melt flow rate MFR2 (190° C., 2.16 kg) in the range of from 0.3 g/10 min to 100 g/10 min measured according to ISO 1133, a MFR10/MFR2 of from 5.0 to 15.0, a Mw/Mn of from 2.0 to 5.0, 1.0 to below 20 vinyl unsaturation units/100,000 C atoms, more than 5.0 to 35 vinylidene unsaturation units/100,000 C atoms, more than 5.0 to 30 vinylene unsaturation units/100,000 C atoms, more than 15.0 to 60 trisubstituted unsaturation units/100,000 C atoms, 26 to 150 total unsaturation units/100,000 C atoms, wherein the total unsaturation units/100,000 C atoms is the sum of vinyl unsaturation units/100,000 C atoms, vinylidene unsaturation units/100,000 C atoms, vinylene unsaturation units/100,000 C atoms and trisubstituted unsaturation units/100,000 C atoms, an unsaturation degree for unsaturation types e) to h) according to formula (I) wherein a vinyl unsaturation degree is in the range of from 5.0 to 15.0%, a vinylene unsaturation degree is in the range of from 20.0 to 30.0%, and wherein the sum of the vinyl unsaturation degree and vinylidene unsaturation degree is at least 30.0% and up to 50.0%.









    unsaturation
    Type


    degree



    (
    %
    )


    =





    unsaturation
    Type


    units
    /
    100

    ,

    000


    C


    atoms




    total


    unsaturation


    units
    /
    100

    ,

    000


    C


    atoms



    *
    100





    (
    I
    )

    A PROCESS FOR EXTRACTING POLYMERS FROM WASTE MATERIAL

    公开(公告)号:US20240209176A1

    公开(公告)日:2024-06-27

    申请号:US18285731

    申请日:2022-04-13

    Applicant: Borealis AG

    CPC classification number: C08J11/20 C08J2300/30

    Abstract: The present invention relates to a process for extracting polymers, preferably polyolefins, from polymer-containing waste material comprising the steps of: providing polymer-containing waste material comprising polyolefin material; contacting the polymer-containing waste material with a non-polar solvent (8) comprising at least one hydrocarbon, optionally halogenated hydrocarbon, having from 4 to 10 carbon atoms, to form a composition (C); heating the composition (C) at a dissolution temperature (T) in the range of 135 to 200° C. and a pressure (P) in the range of 0.1 to 5 MPa for a period of from 5 min to 5 h (M), to obtain a solution comprising the solvent (S) and the polyolefin material dissolved in the solvent (S), and an undissolved material (U); separating the undissolved material (U) from the solution; separating the polyolefin material from the solution, and optionally separating the solvent (S) from the solution.

    UPGRADED RECYCLED POLYOLEFIN
    7.
    发明申请

    公开(公告)号:US20220372264A1

    公开(公告)日:2022-11-24

    申请号:US17772407

    申请日:2020-03-02

    Applicant: BOREALIS AG

    Abstract: A polyolefin composition obtainable by blending a) 96.0 to 99.7 wt.-% of a blend (A), being a recycled material comprising A-1) 30 to 70 wt.-% isotactic polypropylene homopolymer, A-2) 20 to 50 wt.-% polyethylene and ethylene containing copolymers, A-3) 0.5 to 4.0 wt.-% polyamide-6,various optional components, A-11) 1 ppm to 100 ppm of limonene, and A-12) 1 ppm to 200 ppm total fatty acid content with a maleic anhydride-grafted SEBS block copolymer, characterized by its melt volume rate and maleic anhydride content.

    Polymer composition
    8.
    发明授权

    公开(公告)号:US12202964B2

    公开(公告)日:2025-01-21

    申请号:US17424943

    申请日:2020-01-27

    Applicant: BOREALIS AG

    Abstract: The present invention relates to a polymer composition comprising (A) from 60 to 90 wt % of a non-elastomeric polyethylene; (B) from 9.0 to 38 wt % of an elastomer; wherein onto component (A) or components (A) and (B) an acid grafting agent (C) has been grafted in an amount of from 0.01 to 3.0 wt %, all based on the total weight of the polymer composition, and wherein the polymer composition has two distinct peaks and a valley between said peaks in the GPC curve and a Z value, determined from the areas below the two peaks of the GPC curve, of at least −0.3, wherein the Z-value is determined according to formula (I) Z=s/Abs(B−A) (I) wherein Abs(B−A) is the absolute value of (B−A); A=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS15 signal, from log M of 5.1 to log M value where the LS signal is minimum log M (Min), in the log M range between 5.1 and 6; B=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS 15 signal, from log M(Min) to the point where the LS signal is crossed again; and s is the slope between the two peaks of the GPC curve, defined at log M of 5.1 and 6, wherein the GPC curve is defined as the concentration normalized LS 15 signal along the molecular weight of conventional GPC, obtained from the GPC-VISC-LS analysis, a multi-layer structure such as a coated metal pipe, comprising one layer comprising said polymer composition and the use of said polymer composition as adhesive polymer composition and for the production of a multi-layer structure.

    POLYMER COMPOSITION
    10.
    发明申请

    公开(公告)号:US20220098401A1

    公开(公告)日:2022-03-31

    申请号:US17424943

    申请日:2020-01-27

    Applicant: BOREALIS AG

    Abstract: The present invention relates to a polymer composition comprising (A) from 60 to 90 wt % of a non-elastomeric polyethylene; (B) from 9.0 to 38 wt % of an elastomer; wherein onto component (A) or components (A) and (B) an acid grafting agent (C) has been grafted in an amount of from 0.01 to 3.0 wt %, all based on the total weight of the polymer composition, and wherein the polymer composition has two distinct peaks and a valley between said peaks in the GPC curve and a Z value, determined from the areas below the two peaks of the GPC curve, of at least −0.3, wherein the Z-value is determined according to formula (I) Z=s/Abs(B−A) (I) wherein Abs(B−A) is the absolute value of (B−A); A=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS15 signal, from log M of 5.1 to log M value where the LS signal is minimum log M (Min), in the log M range between 5.1 and 6; B=the area, between the tangent parallel to the MW axis going through log M (Min) and the LS 15 signal, from log M(Min) to the point where the LS signal is crossed again; and s is the slope between the two peaks of the GPC curve, defined at log M of 5.1 and 6, wherein the GPC curve is defined as the concentration normalized LS 15 signal along the molecular weight of conventional GPC, obtained from the GPC-VISC-LS analysis, a multi-layer structure such as a coated metal pipe, comprising one layer comprising said polymer composition and the use of said polymer composition as adhesive polymer composition and for the production of a multi-layer structure.

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