Abstract:
A process for the preparation of an ultra-high molecular weight ethylene homopolymer having a MFR21 of 0.01 g/10 min or less, said process comprising:
(I) prepolymerising at least ethylene at a temperature of 0 to 90° C. in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst; (II) polymerising ethylene at a temperature of 55° C. or less, such as 20 to 55° C., to prepare said UHMW ethylene homopolymer;
wherein the UHMW ethylene homopolymer comprises up to 8 wt. % of said prepolymer.
Abstract:
A process for the preparation of an ultra-high molecular weight ethylene homopolymer having a MFR21 of 0.01 g/10 min or less, said process comprising: (I) prepolymerising at least ethylene at a temperature of 0 to 90° C. in the presence of a heterogeneous Ziegler Natta catalyst to prepare an ethylene prepolymer having an Mw of 40,000 to 600,000 g/mol; and thereafter in the presence of the prepolymer and said catalyst; (II) polymerising ethylene at a temperature of 55° C. or less, such as 20 to 55° C., to prepare said UHMW ethylene homopolymer; wherein the UHMW ethylene homopolymer comprises up to 8 wt. % of said prepolymer.
Abstract:
Procatalyst comprising an inorganic support, a chlorine compound carried on said support, a magnesium compound carried on said support, a titanium compound carried on said support, and a compound comprising two oxygen containing rings, wherein said two rings are linked via a bridge selected from the group consisting of carbon bridge, silicon bridge, ethane-1.2-diyl bridge, ethene-1,2-diyl bridge, alkylaminomethyl bridge and imine bridge.
Abstract:
An ethylene polymer with a density of less than 955 kg/m3 obtained by polymerisation with a single-site catalyst and having a shear thinning index SHI2.7/210 of less than 5 wherein ethylene polymer comprises two components.
Abstract translation:密度小于955kg / m 3的乙烯聚合物通过用单中心催化剂聚合获得,并且具有小于5的剪切稀化指数SHI2.7 / 210,其中乙烯聚合物包含两种组分。
Abstract:
Procatalyst comprising an inorganic support, a chlorine compound carried on said support, a magnesium compound carried on said support, a titanium compound carried on said support, and a compound comprising two oxygen containing rings, wherein said two rings are linked via a bridge selected from the group consisting of carbon bridge, silicon bridge, ethane-1.2-diyl bridge, ethene-1,2-diyl bridge, alkylaminomethyl bridge and imine bridge.