公开(公告)号：US09005428B2

公开(公告)日：2015-04-14

申请号：US13286974

申请日：2011-11-01

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10G1/06 ,  C10G9/30

CPC分类号： C10G9/30 ,  C10G2300/201 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/308 ,  C10G2400/06

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process selectively removes metals, salts, water and nitrogen from the feedstock, while at the same time maximizes the yield of the liquid product, and minimizes coke and gas production. Furthermore, this process reduces the viscosity of the feedstock in order to permit pipeline transport, if desired, of the upgraded feedstock with little or no addition of diluents.

摘要翻译： 本发明涉及使用在裂化和化学升级原料的条件下运行的短停留热解反应器的重质烃原料的升级。 本发明的方法提供了显示出降低的粘度和增加的API重力的部分升级的原料的制备。 该方法选择性地从原料中除去金属，盐，水和氮，同时使液体产物的产量最大化，并使焦炭和气体产量最小化。 此外，该方法降低了原料的粘度，以便如果需要，允许很少或不添加稀释剂的改质原料的管道输送。

公开(公告)号：US20120279825A1

公开(公告)日：2012-11-08

申请号：US13552536

申请日：2012-07-18

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10G9/00

CPC分类号： C10B55/04 ,  C10G9/32 ,  C10G31/06 ,  C10G2300/201 ,  C10G2300/208 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/308

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.

摘要翻译： 本发明涉及使用在裂化和化学升级原料的条件下运行的短停留热解反应器的重质烃原料的升级。 用于升级重质烃原料的方法包括将颗粒状热载体引入向上流动的反应器中，将重质烃原料引入到高于微粒热载体的位置的上游反应器中，使得颗粒状热载体与原料的负载比 为约15:1至约200:1，允许重质烃原料与热载体相互作用，停留时间小于约1秒，以产生产物流，将产物流与颗粒状热载体分离， 再生颗粒状热载体，并从产物流中收集气态和液态产物。

公开(公告)号：US08062503B2

公开(公告)日：2011-11-22

申请号：US11713520

申请日：2007-03-01

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10G1/06

CPC分类号： C10G9/30 ,  C10G2300/201 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/308 ,  C10G2400/06

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process selectively removes metals, salts, water and nitrogen from the feedstock, while at the same time maximizes the yield of the liquid product, and minimizes coke and gas production. Furthermore, this process reduces the viscosity of the feedstock in order to permit pipeline transport, if desired, of the upgraded feedstock with little or no addition of diluents. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream. This invention also pertains to the products produced by the method.

摘要翻译： 本发明涉及使用在裂化和化学升级原料的条件下运行的短停留热解反应器的重质烃原料的升级。 本发明的方法提供了显示出降低的粘度和增加的API重力的部分升级的原料的制备。 该方法选择性地从原料中除去金属，盐，水和氮，同时使液体产物的产量最大化，并使焦炭和气体产量最小化。 此外，该方法降低了原料的粘度，以便如果需要，允许很少或不添加稀释剂的改质原料的管道输送。 用于升级重质烃原料的方法包括将颗粒状热载体引入向上流动的反应器中，将重质烃原料引入到高于微粒热载体的位置的上游反应器中，使得颗粒状热载体与原料的负载比 为约15:1至约200:1，允许重质烃原料与热载体相互作用，停留时间小于约1秒，以产生产物流，将产物流与颗粒状热载体分离， 再生颗粒状热载体，并从产物流中收集气态和液态产物。 本发明还涉及通过该方法生产的产品。

公开(公告)号：US09719021B2

公开(公告)日：2017-08-01

申请号：US13338144

申请日：2011-12-27

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10B55/04 ,  C10G9/32 ,  C10G31/06

CPC分类号： C10B55/04 ,  C10G9/32 ,  C10G31/06 ,  C10G2300/302 ,  C10G2300/4006 ,  C10G2300/4025 ,  C10G2300/4081

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.

公开(公告)号：US09127208B2

公开(公告)日：2015-09-08

申请号：US12295916

申请日：2007-04-02

申请人： David Boulard ,  Robert G. Graham ,  Barry Freel

发明人： David Boulard ,  Robert G. Graham ,  Barry Freel

IPC分类号： C07D305/00 ,  C10B53/02 ,  A61K36/00 ,  A61K36/13 ,  C10B49/22 ,  C10C5/00 ,  C07D305/14

CPC分类号： C07D305/14 ,  A61K36/00 ,  A61K36/13 ,  C10B49/22 ,  C10B53/02 ,  C10C5/00 ,  Y02E50/14

摘要： The present invention is related to a thermal extract of a plant material and methods of extraction thereof. The method of producing a thermal extract from a plant starting material by means of a thermal extraction of the starting material wherein the improvement consists in requiring smaller amounts of costly and/or toxic organic solvents for the extraction and partitioning steps.

摘要翻译： 本发明涉及植物材料的热提取物及其提取方法。 通过原料的热提取从植物原料生产热提取物的方法，其中改进在于需要较少量的昂贵和/或有毒的有机溶剂用于萃取和分配步骤。

公开(公告)号：US20120125815A1

公开(公告)日：2012-05-24

申请号：US13338144

申请日：2011-12-27

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10G55/00 ,  C10G55/08

CPC分类号： C10B55/04 ,  C10G9/32 ,  C10G31/06 ,  C10G2300/302 ,  C10G2300/4006 ,  C10G2300/4025 ,  C10G2300/4081

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.

公开(公告)号：US20090298927A1

公开(公告)日：2009-12-03

申请号：US12295916

申请日：2007-04-02

申请人： David Boulard ,  Robert G. Graham ,  Barry Freel

发明人： David Boulard ,  Robert G. Graham ,  Barry Freel

IPC分类号： A61K31/337 ,  C07D305/14 ,  C07D311/04 ,  C07D473/04 ,  C07C45/78

CPC分类号： C07D305/14 ,  A61K36/00 ,  A61K36/13 ,  C10B49/22 ,  C10B53/02 ,  C10C5/00 ,  Y02E50/14

摘要： The present invention is related to a thermal extract of a plant material and methods of extraction thereof. The method of producing a thermal extract from a plant starting material by means of a thermal extraction of the starting material wherein the improvement consists in requiring smaller amounts of costly and/or toxic organic solvents for the extraction and partitioning steps.

摘要翻译： 本发明涉及植物材料的热提取物及其提取方法。 通过原料的热提取从植物原料生产热提取物的方法，其中改进在于需要较少量的昂贵和/或有毒的有机溶剂用于萃取和分配步骤。

公开(公告)号：US06844420B1

公开(公告)日：2005-01-18

申请号：US10048184

申请日：2000-07-28

申请人： Barry Freel ,  Robert G. Graham ,  Régi Giroux

发明人： Barry Freel ,  Robert G. Graham ,  Régi Giroux

IPC分类号： C08G16/02 ,  C08H8/00 ,  C08L61/06 ,  C08L61/24 ,  C08L97/02 ,  C09J161/06 ,  C09J161/24 ,  C10B53/02 ,  C10C5/00 ,  C08H5/04

CPC分类号： C08L61/24 ,  C08G16/0293 ,  C08H8/00 ,  C08L61/06 ,  C08L97/02 ,  C09J161/06 ,  C09J161/24 ,  C10B53/02 ,  C10C5/00 ,  Y02E50/14 ,  Y02P20/133 ,  C08L2666/02

摘要： This invention is directed to a method of preparing a natural resin by liquefying wood, bark, forest residues, wood industry residues, or other biomass using rapid destructive distillation (fast pyrolysis). Fast pyrolysis produces both vapors and char from biomass, and following removal of the char from the product vapors, a liquid pitch product is recovered and processed by distillation, evaporation, or a combination thereof, in order to obtain a natural resin which may be in either liquid or solid form. The natural resin comprises a total phenolic content from about 30% to about 80% (w/w), and is a highly-reactive ligninic compound that has been found to be suitable for use within resin formulations without requiring any further extraction or fractionation procedures. Resins comprising up to 60% natural resin have been prepared and tested in board production and found to exhibit similar properties associated with commercially available resins. The natural resin may substitute for phenol, or for both phenol and formaldehyde within phenol-containing resins. Similarly, the natural resin can replace a substantial part of the components within urea-containing resins.

摘要翻译： 本发明涉及通过使用快速破坏性蒸馏（快速热解）液化木材，树皮，森林残留物，木材工业残余物或其它生物质来制备天然树脂的方法。 快速热解从生物质中产生蒸气和焦炭，并且在从产物蒸气中除去焦炭之后，通过蒸馏，蒸发或其组合回收和处理液体沥青产物，以获得可以在 液体或固体形式。 天然树脂包括约30％至约80％（w / w）的总酚含量，并且是已被发现适用于树脂制剂中的高反应性木质素化合物，而不需要任何进一步的提取或分馏程序 。 包含高达60％天然树脂的树脂已经在板生产中制备和测试，发现与市售树脂相关的性能呈现出相似的性质。 天然树脂可以代替苯酚，也可以在酚醛树脂中代替苯酚和甲醛。 类似地，天然树脂可以代替含脲树脂中的大部分组分。

公开(公告)号：US20120111766A1

公开(公告)日：2012-05-10

申请号：US13286974

申请日：2011-11-01

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10G55/04

CPC分类号： C10G9/30 ,  C10G2300/201 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/308 ,  C10G2400/06

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process selectively removes metals, salts, water and nitrogen from the feedstock, while at the same time maximizes the yield of the liquid product, and minimizes coke and gas production. Furthermore, this process reduces the viscosity of the feedstock in order to permit pipeline transport, if desired, of the upgraded feedstock with little or no addition of diluents.

摘要翻译： 本发明涉及使用在裂化和化学升级原料的条件下运行的短停留热解反应器的重质烃原料的升级。 本发明的方法提供了显示出降低的粘度和增加的API重力的部分升级的原料的制备。 该方法选择性地从原料中除去金属，盐，水和氮，同时使液体产物的产量最大化，并使焦炭和气体产量最小化。 此外，该方法降低了原料的粘度，以便如果需要，允许很少或不添加稀释剂的改质原料的管道输送。

公开(公告)号：US08105482B1

公开(公告)日：2012-01-31

申请号：US09958261

申请日：2000-04-07

申请人： Barry Freel ,  Robert G. Graham

发明人： Barry Freel ,  Robert G. Graham

IPC分类号： C10G9/28

CPC分类号： C10B55/04 ,  C10G9/32 ,  C10G31/06 ,  C10G2300/302 ,  C10G2300/4006 ,  C10G2300/4025 ,  C10G2300/4081

摘要： The present invention is directed to the upgrading of heavy hydrocarbon feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process reduces the viscosity of the feedstock in order to permit pipeline transport of the upgraded feedstock with little or no addition of diluents. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier, allowing the heavy hydrocarbon feedstock to interact with the heat carrier to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.

摘要翻译： 本发明涉及重质烃原料的升级。 本发明的方法提供了显示出降低的粘度和增加的API重力的部分升级的原料的制备。 该方法降低了原料的粘度，以便允许管道输送少量或不添加稀释剂的升级原料。 用于升级重质烃原料的方法包括将颗粒状热载体引入上流反应器中，将重质烃原料引入到高于微粒热载体的位置的上游反应器中，允许重烃原料与热载体 以产生产物流，将产物流与颗粒状热载体分离，再生颗粒状热载体，以及从产物流收集气态和液态产物。